1. Investigation on crystal structure, magnetic and near-infrared absorption properties of a novel heteroleptic nickel-bis-1,2-dithiolene compound.
- Author
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Chen, Xuan-Rong, Xue, Chen, Liu, Shao-Xian, Cai, Bin, Wang, Jun, Tao, Jian-Qing, Xue, Yun-Shan, Huang, Xing-Cai, Ren, Xiao-Ming, and Liu, Jian-Lan
- Subjects
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NICKEL compounds , *CRYSTAL structure , *ABSORPTION spectra , *MAGNETIC properties of metals , *DITHIOLENES , *ION pairs - Abstract
A new heteroleptic nickel-bis-1,2-dithiolene ion-pair complex, (4-ClBz-1-APy)[Ni(dmit)(mnt)] ( 1 ) (where 4-ClBz-1-APy + = p-chloro-benzyliden-1-aminopyridinium; dmit 2− = 2-thioxo-1, 3-dithiole-4, 5-dithiolate; mnt 2− = maleonitriledithiolate) was synthesized and characterized structurally. The IR spectra, thermal analysis, magnetic and near-IR absorption properties have been investigated for 1 . Complex 1 crystallized in monoclinic system with space group P 2 1 . The anions and cations form the mixed stacked columns separated by the cation columns. The anion stacks are irregular, in which two neighboring heteroleptic [Ni(dmit)(mnt)] − anions are separated by one 4-ClBz-1-APy + cation. The neighboring anions are connected via lateral-to-lateral S…S contacts of dmit 2− ligands and short H…N, H…S and C…S contacts are observed between the cations and the anions. Magnetic susceptibility measurement shows that the magnetic data follows the S = 1 / 2 Heisenberg alternating linear-chain model in the temperature range 40–300 K and Curie-Weiss law below 40 K for 1 . Salts 1 exhibits a intense near-IR absorption in the region of 900–1400 nm, and this near-IR absorption feature makes it to be a promising optical material. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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