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BaHfO (BHO) has been proposed as a new cap layer material for YBaCuO (YBCO) coated conductors. Highly c-axis oriented BHO cap layer has been deposited on ion-beam assisted deposition-MgO buffered Hastelloy tapes by direct-current-magnetron sputtering method. The epi-growth of BHO films combined with its properties is investigated in details. The degenerated cubic crystal structure of BHO film is confirmed by Raman spectrum analysis. XRD θ-2θ scan, φ-scan and ω-scan reveal an excellent c-axis alignment with good in-plane and out-of-plane textures for BHO cap layers. SEM and AFM investigations show BHO cap layer a dense and crack-free morphology. Subsequently pure c-axis orientation YBCO film was epitaxial grown on such BHO cap layer successfully, shown BaHfO a potential cap layer material for coated conductors. [ABSTRACT FROM AUTHOR]

The influence of various gas flow conditions on the nucleation and growth rate of YBa 2 Cu 3 O 7-δ (YBCO) coated conductors in the high-temperature heat treatment stage of low fluorine chemical solution deposition (LF–MOD) process have been investigated, including the gas flow rate and gas flow direction. The results indicated that film-growth rate is faster while a -axis oriented phase coexisted with c -axis in the films at the higher gas flow rate. And YBCO ( 00 l) grains grew slowly while a -axis oriented phase also nucleated easily on the end of the long films along gas flow direction. It could be caused by large quantities of HF gas accumulating from the chemical reaction for converting YBCO phase. Hence, the crystal mechanism of various LF–MOD methods can be supposed as still “BaF 2 ” process as the TFA-MOD method, and orientation nucleation and growth rate of YBCO films can be artificial control by adjusting the gas flow conditions. [ABSTRACT FROM AUTHOR]

Abstract: We report the synthesis of barium phosphate (BP) nano-flake and its adsorption behavior to methyl blue (MB) in aqueous solution. The as-obtained BP nano-flake revealed pure rhombohedral crystal structure. The adsorption capacity of MB onto BP reached 1500mgg−1. The adsorption equilibrium results fitted well with the Freundlich isotherm model. The adsorption process took less than 30min to reach equilibrium. The adsorption kinetics was elucidated by the pseudo-second-order kinetic equation. It followed 2-stage and 3-stage intra-particle diffusion models for the low and high concentration of dye solutions, respectively. The adsorption of MB using the BP nano-flake was highly selective, compared with the adsorption of other dyes. The interactions between MB and BP were mainly the ionic interaction and hydrogen bonds, which were confirmed by the X-ray photoelectron spectroscopic results and the density functional theory calculations. The BP nano-flake revealed less than 5% decrease in adsorption amount when it was recycled and reused five times. The present work shows that the BP nano-flake is promising for practical applications in MB removal from aqueous solutions. [Copyright &y& Elsevier]