Search

Your search keyword '"Mercè Martin-Sabi"' showing total 2 results
Start Over Author "Mercè Martin-Sabi" Topic crystallography
2 results on '"Mercè Martin-Sabi"'

1. ChemInform Abstract: Rearrangement of {α-P2W15} to {PW6} Moieties During the Assembly of Transition-Metal-Linked Polyoxometalate Clusters

Author

Jamie M. Cameron, Mercè Martin-Sabi, Ross S. Winter, Leroy Cronin, Claire Lydon, and De-Liang Long

Subjects
Crystallography, Electrospray, Transition metal, Chemistry, Polyoxometalate, Solution analysis, General Medicine, Mass spectrometry, Lacunary function, Block (periodic table)
Abstract

We report the formation of two polyoxotungstates of the general formula [M6(PW6O26)(α-P2W15O56)2(H2O)2]23− (M = CoII or MnII), which contain {PW6} fragments generated from the [P2W15O56]12− precursor, which demonstrates for the first time the transformation of a Dawson lacunae into a Keggin lacunary building block. Solution analysis of the clusters has been conducted via electrospray ionisation mass spectrometry.

Published
2016
Full Text
View/download PDF

2. Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

Author

Leroy Cronin, Jamie M. Cameron, Claire Lydon, Mercè Martin-Sabi, Ross S. Winter, and De-Liang Long

Subjects
Electrospray, 010405 organic chemistry, Chemistry, Inorganic chemistry, Metals and Alloys, Solution analysis, General Chemistry, 010402 general chemistry, Mass spectrometry, Block (periodic table), 01 natural sciences, Catalysis, 3. Good health, 0104 chemical sciences, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Crystallography, Transition metal, Polyoxometalate, Materials Chemistry, Ceramics and Composites, Lacunary function
Abstract

We report the formation of two polyoxotungstates of the general formula [M6(PW6O26)(α-P2W15O56)2(H2O)2](23-) (M = Co(II) or Mn(II)), which contain {PW6} fragments generated from the [P2W15O56](12-) precursor, which demonstrates for the first time the transformation of a Dawson lacunae into a Keggin lacunary building block. Solution analysis of the clusters has been conducted via electrospray ionisation mass spectrometry.

Published
2015

Catalog

Books, media, physical & digital resources
See catalog results