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We have measured the inelastic neutron scattering spectra for a powder sample and three differently oriented single crystals of K[sub 2]C[sub 2]O[sub 4]·H[sub 2]O on the TFXA spectrometer at the ISIS facility. The crystal structure consists of oxalate ions hydrogen-bonded by the water molecules into infinite linear chains, which are held together by electrostatic interactions with the K[sup +] ions. The H[sub 2]O molecules are isolated from each other. The vibrations can then be separated into internal and external vibrations. The single crystals were cut and oriented so as to separate the rocking, twisting and wagging modes as much as possible. The rocking mode appears at 656 cm[sup -1] (overtone at 1278cm[sup -1]). A band at 746cm[sup -1] with strong overtones at 1448 and 2099 cm[sup -1] is assigned to the overlapping twisting and wagging modes. The translational modes are found at 97, 210 and 215 cm[sup -1]. [ABSTRACT FROM AUTHOR]