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One method for computationally determining phase boundaries is to explicitly simulate a direct coexistence between the two phases of interest. Although this approach works very well for fluid–fluid coexistences, it is often considered to be less useful for fluid–crystal transitions, as additional care must be taken to prevent the simulation boundaries from imposing unwanted strains on the crystal phase. Here, we present a simple adaptation to the direct coexistence method that nonetheless allows us to obtain highly accurate predictions of fluid–crystal coexistence conditions, assuming that a fluid–crystal interface can be readily simulated. We test our approach on hard spheres, the screened Coulomb potential, and a 2D patchy-particle model. In all cases, we find excellent agreement between the direct coexistence approach and (much more cumbersome) free-energy calculation methods. Moreover, the method is sufficiently accurate to resolve the (tiny) free-energy difference between the face-centered cubic and hexagonally close-packed crystal of hard spheres in the thermodynamic limit. The simplicity of this method also ensures that it can be trivially implemented in essentially any simulation method or package. Hence, this approach provides an excellent alternative to free-energy based methods for the precise determination of phase boundaries. [ABSTRACT FROM AUTHOR]

The interplay between crystal nucleation and the structure of the metastable fluid has been a topic of significant debate over recent years. In particular, it has been suggested that even in simple model systems such as hard or charged colloids, crystal nucleation might be foreshadowed by significant fluctuations in local structure around the location where the nucleus first arises. We investigate this using computer simulations of spontaneous nucleation events in both hard and charged colloidal systems. To detect local structural variations, we use both standard and unsupervised machine learning methods capable of finding hidden structures in the metastable fluid phase. We track numerous nucleation events for the face-centered cubic and body-centered cubic crystals on a local level and demonstrate that all signs of crystallinity emerge simultaneously from the very start of the nucleation process. We thus conclude that we observe no precursor for the crystal nucleation of hard and charged colloids. [ABSTRACT FROM AUTHOR]

We study the nucleation of nearly hard charged colloidal particles. We use Monte Carlo simulations in combination with free-energy calculations to accurately predict the phase diagrams of these particles and map them via the freezing density to hard spheres, then we use umbrella sampling to explore the nucleation process. Surprisingly, we find that even very small amounts of charge repulsion can have a significant effect on the phase behavior. Specifically, we find that phase boundaries and nucleation barriers are mostly dependent on the Debye screening length and that even screening lengths as small as 2% of the particle diameter are sufficient to show marked differences in both. This work demonstrates clearly that even mildly charged colloids are not effectively hard spheres. [ABSTRACT FROM AUTHOR]

Charged colloidal particles—on both the nano and micron scales—have been instrumental in enhancing our understanding of both atomic and colloidal crystals. These systems can be straightforwardly realized in the lab and tuned to self-assemble into body-centered-cubic (BCC) and face-centered-cubic (FCC) crystals. While these crystals will always exhibit a finite number of point defects, including vacancies and interstitials—which can dramatically impact their material properties—their existence is usually ignored in scientific studies. Here, we use computer simulations and free-energy calculations to characterize vacancies and interstitials in FCC and BCC crystals of point-Yukawa particles. We show that, in the BCC phase, defects are surprisingly more common than in the FCC phase, and the interstitials manifest as so-called crowdions: an exotic one-dimensional defect proposed to exist in atomic BCC crystals. Our results open the door to directly observe these elusive defects in the lab. [ABSTRACT FROM AUTHOR]