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Start Over Author "Benjamin Dassonneville" Topic cyclohexane
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1. Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride

Author

Esfandiar Rafii, Benjamin Dassonneville, and Andreas Heumann

Subjects
Cyclohexane, Ligand, Stereochemistry, Metals and Alloys, chemistry.chemical_element, General Chemistry, Highly selective, Medicinal chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, chemistry.chemical_compound, chemistry, Diamine, Materials Chemistry, Ceramics and Composites, Palladium
Abstract

In non-racemic (1R,2R)-(1,2-dialkyl)-1,2-diaminocyclohexane palladium dichloride complexes the C2 symmetry of the diamine ligand is broken, resulting in selective R,S-coordination.

Published
2007

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