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This study aimed to synthesize distrontium cerate (2SrO·CeO2: S2Ce) and evaluate its properties as an alternative component of the endodontic cement. S2Ce cement was prepared through calcination of strontium hydroxide and cerium carbonate. Subsequently, the crystal phase was confirmed using X-ray diffraction. S2Ce cement exhibited a rapid setting time (121 min) and achieved a high compressive strength (72.1 MPa) at 1 d after mixing, comparable to the compressive strength of a commercial mineral trioxide aggregate (MTA) cement (ProRoot MTA) after 28 d post mixing. However, the compressive strength decreased after 28 d of storage when the W/P ratio was 0.30–0.40 (p < 0.05). Ion dissolution test of the S2Ce cement showed that strontium ions were released after immersion in water (5.27 mg/mL after 1 d), whereas cerium dissolution was not detected. S2Ce exhibited approximately three times higher radiopacity (9.0 mm aluminum thickness equivalent) compared to the commercial MTA (p < 0.05). These findings suggest that S2Ce is a possible component for hydraulic endodontic cement that demonstrates a rapid setting and high radiopacity.

The influence of alloying elements on the cohesive strength of metal heat-resistant alloys (HRAs) is analyzed. Special parameters are introduced to characterize the individual contribution of each alloying element. These are the partial molar cohesion energy of the matrix (χ) and the cohesive strength of the grain boundaries (η) and can be calculated by computer modeling based on the density functional theory. The calculating results of the parameters χ and η in nickel HRAs with mono– and polycrystalline structures alloyed with refractory metals are presented. The calculated data are used to select the chemical composition and develop new nickel (Ni) HRAs with superior creep-rupture properties. It is assumed that a similar approach can be used to search for alloying elements that will contribute to increasing the cohesive strength of additive objects. The resistance of coherent γ-γ′ and lamellar (raft) structures in nickel HRAs to the process of diffusion coarsening during operation is analyzed.

Tensile strength of concrete is the basic property when estimating the cracking resistance of the structure and when analysing fracture processes in concrete. The most common way of testing tensile strength is the Brazilian method. It has been noticed that the shape and size of specimens influence the tensile splitting strength. The experiments were performed to investigate the impact of cylinder’s length on tensile concrete strength received in the Brazilian method. During the experiment the tensile concrete strength was tested on two different sizes cylindrical specimens: 150 mm × 150 mm and 150 mm × 300 mm. Experiments were performed in two stages, with two types of maximum aggregate size: 16 mm and 22 mm. The software “Statistica” was used to perform the broad scale statistical analysis. When comparing test results for shorter and longer specimens, the increase of tensile splitting strength tested on shorter cylinders was observed (approximately 5%). However, when performing deeper statistical analysis, it has been found that the length effect was not sensitive to the strength of the cement matrix and the type of aggregate but was influenced by the aggregate size. Further experiments are needed in order to perform a multi-parameter statistical analysis of scale effect when testing the splitting tensile strength of concrete.

Consistent and proper use of respiratory protective devices (RPD) is one of the essential actions that can be taken to reduce the risk of exposure to airborne hazards, i.e., biological and nonbiological aerosols, vapours, and gases. Proper fit of the facepiece and comfort properties of RPDs play a crucial role in effective protection and acceptance of RPDs by workers. The objective of the present paper was to develop viscoelastic polyurethane foams for use in RPD seals characterised by proper elasticity, allowing for the enhancement of the device fit to the face and the capability of removing moisture from the skin in order to improve the comfort of RPD use. Moreover, it was pivotal to ensure the non-flammability of the foams, as well as a simultaneous reduction in their cytotoxicity. The obtained foams were characterised using scanning electron microscopy, infrared spectroscopy, thermogravimetry, and differential scanning calorimetry. Measurements also involved gel fraction, apparent density, compression set, rebound resilience, wettability, flammability, and cytotoxicity. The results are discussed in the context of the impact of modifications to the foam formulation (i.e., flame-retardant type and content) on the desired foam properties. The test results set directions for future works aimed to develop viscoelastic polyurethane foams that could be applied in the design of respiratory protective devices.

Skin is a hierarchical and multi-cellular organ exposed to the external environment with a key protective and regulatory role. Wounds caused by disease and trauma can lead to a loss of function, which can be debilitating and even cause death. Accelerating the natural skin healing process and minimizing the risk of infection is a clinical challenge. Electrospinning is a key technology in the development of wound dressings and skin substitutes as it enables extracellular matrix-mimicking fibrous structures and delivery of bioactive materials. Honey is a promising biomaterial for use in skin tissue engineering applications and has antimicrobial properties and potential tissue regenerative properties. This preliminary study investigates a solution electrospun composite nanofibrous mesh based on polycaprolactone and a medical grade honey, SurgihoneyRO. The processing conditions were optimized and assessed by scanning electron microscopy to fabricate meshes with uniform fiber diameters and minimal presence of beads. The chemistry of the composite meshes was examined using Fourier transform infrared spectroscopy and X-ray photon spectroscopy showing incorporation of honey into the polymer matrix. Meshes incorporating honey had lower mechanical properties due to lower polymer content but were more hydrophilic, resulting in an increase in swelling and an accelerated degradation profile. The biocompatibility of the meshes was assessed using human dermal fibroblasts and adipose-derived stem cells, which showed comparable or higher cell metabolic activity and viability for SurgihoneyRO-containing meshes compared to polycaprolactone only meshes. The meshes showed no antibacterial properties in a disk diffusion test due to a lack of hydrogen peroxide production and release. The developed polycaprolactone-honey nanofibrous meshes have potential for use in skin applications. Published version The authors wish to acknowledge the funding provided by the Republic of Turkey’s Ministry of National Education, the United Kingdom’s Engineering and Physical Sciences Research Council (EPSRC) Doctoral Prize Fellowship (EP/R513131/1), and the EPSRC and Medical Research Council (MRC) Centre for Doctoral Training in Regenerative Medicine (EP/L014904/1).

This paper aims to study the feasibility of low cement content foamed concrete using waste lime mud (LM) and fly ash (FA) as mineral additives. The LM/FA ratio was first optimized based on the compressive strength. Isothermal calorimetry test, ESEM, and XRD were used to investigate the role of LM during hydration. Afterward, the optimized LM/FA ratio (1/5) was used to design foamed concrete with various wet densities (600, 700, 800 and 900 kg/m3) and LM–FA dosages (0%, 50%, 60%, 70% and 80%). Flowability measurements and mechanical measurements including compressive strength, flexural strength, splitting strength, elastic modulus, and California bearing ratio were conducted. The results show that the foamed concretes have excellent workability and stability with flowability within 170 and 190 mm. The high alkalinity of LM accelerated the hydration of FA, thereby increasing the early strength. The significant power functions were fitted for the relationships between flexural/splitting and compressive strength with all correlation coefficients (R2) larger with 0.95. The mechanical properties of the foamed concrete increased with the density increasing or LM–FA dosage decreasing. The compressive strength, tensile strength, CBR of all prepared foamed concretes were higher than the minimum requirements of 0.8 and 0.15 MPa and 8%, respectively in the standard.

Lead-free Na1/2Bi1/2TiO3-BaTiO3 (NBT-BT) has gained revived interest due to its exceptionally good high power properties in comparison to commercial lead-based piezoelectrics. Recently, Zn-modified NBT-BT-based materials as solid solution and composites have been reported to exhibit enhanced depolarization temperatures and a high mechanical quality factor. In this work, the pyroelectric properties of Zn-doped NBT-6mole%BT and NBT-9mole%BT ceramics are investigated. The doped compositions of NBT-6BT and NBT-9BT feature a relatively stable pyroelectric property in a wide temperature range of ~37 K (300–330 K) and 80 K (300–380 K), respectively. A threefold increase in detector figure of merit is noted for 0.01 mole Zn-doped NBT-6mole% BT at room temperature in comparison to undoped NBT-6mole%BT and this increase is higher than those of major lead-free materials. A broad range of the temperature-independent behavior for the figures of merit was noted (303–380 K) for Zn-doped NBT-6mole% BT, which is 30 K higher than the undoped material. The large pyroelectric figures of merit and good temperature stability renders Zn-doped NBT-BT an ideal candidate for pyroelectric detector and energy harvesting applications.

Biomedical alloys are essential parts of modern biomedical applications. However, they cannot satisfy the increasing requirements for large-scale production owing to the degradation of metals. Physical surface modification could be an effective way to enhance their biofunctionality. The main goal of this review is to emphasize the importance of the physical surface modification of biomedical alloys. In this review, we compare the properties of several common biomedical alloys, including stainless steel, Co–Cr, and Ti alloys. Then, we introduce the principle and applications of some popular physical surface modifications, such as thermal spraying, glow discharge plasma, ion implantation, ultrasonic nanocrystal surface modification, and physical vapor deposition. The importance of physical surface modifications in improving the biofunctionality of biomedical alloys is revealed. Future studies could focus on the development of novel coating materials and the integration of various approaches.

A spontaneous oscillation between the expansion and contraction of a nitrobenzene pendant droplet containing di-(2-ethylhexyl)phosphoric acid (DEHPA) was observed in an aqueous phase under alkaline conditions. We described this phenomenon as the spontaneous oscillation of the oil–water interfacial tension. The oscillation characteristics such as the induction period and the interfacial-tension oscillation frequency were investigated under different temperatures and aqueous phase polarities. The effects of the interfacial tension of the biphasic pendant-droplet, the surface excess of the surfactant molecules, and the amount of nitrobenzene elution from the droplet to the aqueous phase on the oscillation characteristics were investigated. Consequently, the periodic expansion–contraction oscillation mechanism was explained through the adsorption–desorption cycle of DEHPA with respect to the aggregate formation of the inverted micelle of DEHPA. This study was based on a simple vibration phenomenon of interfacial tension, and is extremely important for clarifying the predominant factors that cause fluctuations in the free interface energy, which has been ambiguous.

This paper presents an effectiveness analysis of the grinding process with the use of a new multi-layer abrasive tool. The designed abrasive tool consists of external layers with a conventional structure, whose task is to decrease the grinding wheel load and ensure high grinding volumetric efficiency. The inner layer of the grinding wheel contains a 30% addition of abrasive aggregates. The task of the inner layer is to provide lower roughness of the machined surface. The aim of the research presented in this paper was to evaluate the topography of the designed abrasive tool and to analyze the middle layer properties influencing the machined surface roughness. The differentiation of the active surface features of the abrasive tool was determined for the conventional layer and the layer with the addition of abrasive aggregates. The machining potential of the layers was also determined using the Shos parameter. The surface topography of Ti-6Al-4V alloys ground with the use of a multi-layer wheel and a conventional grinding wheel was analyzed. With the application of the bootstrap hypothesis, the set of roughness parameters differentiating the topography of ground surfaces was determined.

Amyotrophic lateral sclerosis (ALS) is characterized by the degeneration and death of motor neurons. This neurodegenerative disease leads to muscle atrophy, paralysis, and death due to respiratory failure. MicroRNAs (miRNAs) are small non-coding ribonucleic acids (RNAs) with a length of 19 to 25 nucleotides, participating in the regulation of gene expression. Different studies have demonstrated that miRNAs deregulation is critical for the onset of a considerable number of neurodegenerative diseases, including ALS. Some studies have underlined how miRNAs are deregulated in ALS patients and for this reason, design therapies are used to correct the aberrant expression of miRNAs. With this rationale, delivery systems can be designed to target specific miRNAs. Specifically, these systems can be derived from viral vectors (viral systems) or synthetic or natural materials, including exosomes, lipids, and polymers. Between many materials used for non-viral vectors production, the two-dimensional graphene and its derivatives represent a good alternative for efficiently delivering nucleic acids. The large surface-to-volume ratio and ability to penetrate cell membranes are among the advantages of graphene. This review focuses on the specific pathogenesis of miRNAs in ALS and on graphene delivery systems designed for gene delivery to create a primer for future studies in the field.

Low-frequency noise investigation is a highly sensitive and very informative method for characterization of white nitride-based light-emitting diodes (LEDs) as well as for the evaluation of their degradation. We present a review of quality and reliability investigations of high-power (1 W and 3 W) white light-emitting diodes during long-term aging at the maximum permissible forward current at room temperature. The research was centered on the investigation of blue InGaN and AlInGaN quantum wells (QWs) LEDs covered by a YAG:Ce3+ phosphor layer for white light emission. The current-voltage, light output power, and low-frequency noise characteristics were measured. A broadband silicon photodetector and two-color (blue and red) selective silicon photodetectors were used for the LED output power detection, which makes it possible to separate physical processes related to the initial blue light radiation and the phosphor luminescence. Particular attention was paid to the measurement and interpretation of the simultaneous cross-correlation coefficient between electrical and optical fluctuations. The presented method enables to determine which part of fluctuations originates in the quantum well layer of the LED. The technique using the two-color selective photodetector enables investigation of changes in the noise properties of the main blue light source and the phosphor layer during the long-term aging.

The discharge of oily wastewater and oil spills at sea are the current difficulties in water pollution control. This problem often leads to terrible disasters. Therefore, the effective realization of oil-water separation is a very challenging problem. Superhydrophobic sponge is a promising oil-absorbing material. In this article, we reported a superhydrophobic sponge with nano-Fe3O4 for oil-water separation. The addition of nano-Fe3O4 allows the sponge to be recycled under the action of magnetic force. The sponge has the advantages of low cost, simple preparation and efficient oil-water separation. This kind of sponge is very worthy of promotion for the treatment of oily wastewater and marine oil spill accidents.

The article aims to present the modified structural composition of the sub-ballast layers of the railway substructure, in which a part of the natural materials for the establishment of sub-ballast or protective layers of crushed aggregate is replaced by thermal insulation and reinforcing material (layer of composite foamed concrete and extruded polystyrene board). In this purpose, the experimental field test was constructed and the bearing capacity of the modified sub-ballast layers’ structure and temperature parameters were analyzed. A significant increase in the original static modulus of deformation on the surface of composite foamed concrete was obtained (3.5 times and 18 times for weaker and strengthen subsoil, respectively). Based on real temperature measurement, it was determined the high consistency of the results of numerical analyses and experimental test (0.002 m for the maximum freezing depth of the railway line layers and maximum ±0.5 °C for temperature in the railway track substructure–subsoil system). Based on results of numerical analyses, modified railway substructure with built-in thermal insulating extruded materials (foamed concrete and extruded polystyrene) were considered. A nomogram for the implementation of the design of thicknesses of individual structural layers of a modified railway sub-ballast layers dependent on climate load, and a mathematical model suitable for the design of thicknesses of structural sub-ballast layers of railway line were created.

This work investigates two austenitic stainless steels, Sanicro 25 which is a candidate for high temperature heavy section components of future power plants and Esshete 1250 which is used as a reference material. The alloys were subjected to out-of-phase (OP) thermomechanical fatigue (TMF) testing under strain-control in the temperature range of 100 ∘C to 650 ∘C. Both unaged and aged (650 ∘C, 3000 h) TMF specimens were tested to simulate service degradation resulting from long-term usage. The scanning electron microscopy methods electron backscatter diffraction (EBSD) and energy dispersive spectroscopy (EDS) were used to analyse and discuss active failure and deformation mechanisms. The Sanicro 25 results show that the aged specimens suffered increased plastic straining and shorter TMF-life compared to the unaged specimens. The difference in TMF-life of the two test conditions was attributed to an accelerated microstructural evolution that provided decreased the effectiveness for impeding dislocation motion. Ageing did not affect the OP-TMF life of the reference material, Esshete 1250. However, the structural stability and its resistance for cyclic deformation was greatly reduced due to coarsening and cracking of the strengthening niobium carbide precipitates. Sanicro 25 showed the higher structural stability during OP-TMF testing compare with the reference material.

4H-SiC based p-n junction UV photo-detectors were irradiated with 600 keV He+ in the fluence range of 5 × 1011 ÷ 5 × 1014 ion/cm2 in order to investigate their radiation hardness. The effects of irradiation on the electro-optical performance were monitored in dark condition and in the UV (200 ÷ 400 nm) range, as well as in the visible region confirming the typical visible blindness of unirradiated and irradiated SiC photo-sensors. A decrease of UV optical responsivity occurred after irradiation and two fluence regimes were identified. At low fluence (13 ions/cm2), a considerable reduction of optical responsivity (of about 50%) was measured despite the absence of relevant dark current changes. The presence of irradiation induced point defects and then the reduction of photo-generated charge lifetime are responsible for a reduction of the charge collection efficiency and then of the relevant optical response reduction: point defects act as recombination centers for the photo-generated charges, which recombine during the drift/diffusion toward the electrodes. At higher irradiation fluence, the optical responsivity is strongly reduced due to the formation of complex defects. The threshold between low and high fluence is about 100 kGy, confirming the radiation hardness of SiC photo-sensors.

In this paper, we investigated the interaction of nanosecond pulsed-periodic infrared (IR) laser radiation at a 50 and 500 Hz repetition rate with aerosol platinum (Pt) and silver (Ag) nanoparticles agglomerates obtained in a spark discharge. Results showed the complete transformation of Pt dendrite-like agglomerates with sizes of 300 nm into individual spherical nanoparticles directly in a gas flow under 1053 nm laser pulses with energy density 3.5 mJ/cm2. Notably, the critical energy density required for this process depended on the size distribution and extinction of agglomerates nanoparticles. Based on the extinction cross-section spectra results, Ag nanoparticles exhibit a weaker extinction in the IR region in contrast to Pt, so they were not completely modified even under the pulses with energy density up to 12.7 mJ/cm2. The obtained results for Ag and Pt laser sintering were compared with corresponding modification of gold (Au) nanoparticles studied in our previous work. Here we considered the sintering mechanisms for Ag, Pt and Au nanoparticles agglomerates in the aerosol phase and proposed the model of their laser sintering based on one-stage for Pt agglomerates and two-stage shrinkage processes for Au and Ag agglomerates.

Nickel-based super alloys are popular for applications in the energy and aerospace industries due to their excellent corrosion and high-temperature resistance. Direct metal deposition (DMD) of nickel alloys has reached technology readiness for several applications, especially for the repair of turbomachinery components. However, issues related to part quality and defect formation during the DMD process still persist. Laser remelting can effectively prevent and repair defects during metal additive manufacturing (AM); however, very few studies have focused on numerical modeling and experimental process parameter optimization in this context. Therefore, the aim of this study is to investigate the effect of determining the remelting process parameters via numerical simulation and experimental analyses in order to optimize an industrial process chain for part repair by DMD. A heat conduction model analyzed 360 different process conditions, and the predicted melt geometry was compared with observations from a fluid flow model and experimental single tracks for selected reference conditions. Subsequently, the remelting process was applied to a demonstrator repair case. The results show that the models can well predict the melt pool shape and that the optimized remelting process increases the bonding quality between base and DMD materials. Therefore, DMD part fabrication and repair processes can benefit from the remelting step developed here., Materials, 15 (1), ISSN:1996-1944

In this study, the results obtained by 19 laboratories participating in 2 editions of the interlaboratory comparison (ILC) determining 2 properties of ceramic tiles adhesives (CTAs), i.e., initial tensile adhesion strength and tensile adhesion strength after water immersion following EN 12004, were analyzed. The results show that participating laboratories maintain a constant quality of their work. The use of z-score analysis, under ISO 13528, allows for classifying 89.5% to 100% of laboratories as satisfactory, depending on the measurement’s kind and edition. The remaining laboratories are classified as questionable. The investigation of the predominant mode of failure of the CTA’s samples tested in the two editions shows significant differences. From the perspective of laboratories, the goal of the ILC has been achieved. From the standpoint of a manufacturer who evaluates a product’s properties when placing it on the market, the results indicate the necessity of a particular treatment of the product evaluation process because the variability of the obtained results is significant. It increases the possibility of the product failing to meet the assessment criteria verified by the construction market supervision authorities. The manufacturer must consider all possible variations in the risk analysis, including the ILC results, to improve the assessment process of CTAs.

The aim of this paper is to promote the use of mine clay washing residues for the preparation of alkali activated materials (AAMs). In particular, the influence of the calcination temperature of the clayey by-product on the geopolymerization process was investigated in terms of chemical stability and durability in water. The halloysitic clay, a mining by-product, has been used after calcination and mixed with an alkaline solution to form alkali activated binders. Attention was focused on the influence of the clay’s calcination treatment (450–500–600 °C) on the geopolymers’ microstructure of samples, remaining in the lower limit indicated by the literature for kaolinite or illite calcination. The mixtures of clay and alkali activators (NaOH 8M and Na-silicate) were cured at room temperature for 28 days. The influence of solid to liquid ratio in the mix formulation was also tested in terms of chemical stability measuring the pH and the ionic conductivity of the eluate after 24-h immersion time in water. The results reported values of ionic conductivity higher for samples made with untreated clay or with low temperature of calcination (≥756 mS/m) compared with values of samples made with calcined clay (292 mS/m). This result suggests that without a proper calcination of the as-received clay it was not possible to obtain 25 °C-consolidated AAMs with good chemical stability and dense microstructure. The measures of integrity test, pH, and ionic conductivity in water confirmed that the best sample is made with calcined clay at 600 °C, being similar (53% higher ionic conductivity of the eluate) or equal (integrity test and pH) to values recorded for the metakaolin-based geopolymer considered the reference material. These results were reflected in term of reticulation and morphology of samples through the analysis with scanning electron microscope (SEM) and X-ray diffraction (XRD), which show a dense and homogeneous microstructure predominantly amorphous with minor amounts of quartz, halloysite, and illite crystalline phases. Special attention was dedicated to this by-product to promote its use, given that kaolinite (and metakaolin), as primary mineral product, has a strong impact on the environment. The results obtained led us to consider this halloysite clay very interesting as an aluminosilicate precursor, and extensively deepening its properties and reactivity for the alkaline activation. In fact, the heart of this work is to study the possibility of reusing this by-product of an industrial process to obtain more sustainable high-performance binders.

Germanene, with a wrinkled atomic layer structure and high specific surface area, showed high potential as an electrode material for supercapacitors. According to the first-principles calculation based on Density Functional Theory, the quantum capacitance of germanene could be significantly improved by introducing doping/co-doping, vacancy defects and multilayered structures. The quantum capacitance obtained enhancement as a result of the generation of localized states near the Dirac point and/or the movement of the Fermi level induced by doping and/or defects. In addition, it was found that the quantum capacitance enhanced monotonically with the increase of the defect concentration.

Palladium satisfies most of the requirements for an effective hydrogen storage material with two major drawbacks: it has a relatively low gravimetric hydrogen density and is prohibitively expensive for large scale applications. Pd-based alloys should be considered as possible alternatives to a pure Pd. The question is how much one can dilute the Pd concentration in a variety of candidate materials while preserving the hydrogen absorption capability. We demonstrate that the resistivity measurements of thin film alloy samples can be used for a qualitative high-throughput screening and study of the hydrogen absorbing properties over the entire range of palladium concentrations. Contrary to palladium-rich alloys where additional hydrogen scattering indicates a degree of hydrogen content, the diluted alloy films respond by a decrease in resistance due to their thickness expansion. Evidence of significant hydrogen absorption was found in thin CoPd films diluted to just 20% of Pd.

In this paper, a parallel homogenization model for recycled concrete was proposed. A new type of finite element method, the base force element method, based on the complementary energy principle and the parallel homogenization model, is used to conduct meso-level damage research on recycled concrete. The stress–strain softening curve and failure mechanism of the recycled concrete under uniaxial tensile load are analyzed using the nonlinear damage analysis program of the base force element method based on the parallel homogenization model. The tensile strength and destructive mechanisms of recycled concrete materials are studied using this parallel homogenization model. The calculation results are compared with the results of the experiments and meso-level random aggregate model analysis methods. The research results show that this parallel homogenization analysis method can be used to analyze the nonlinear damage analysis of recycled concrete materials. The tensile strength, stress–strain softening curve, and crack propagation process of recycled concrete materials can be obtained using the present method.

Dowel-type fasteners are one of the most used type of connections in timber joints. Its design follows the equations included in the Eurocode 5. The problem with these equations is that they do not adequately contemplate the resistive capacity increase of these joints, when using configurations which provoke the so-called rope effect. This effect appears when using threaded surface dowels instead of flat surface dowels, expansion kits or nut-washer fixings at the end of the dowel. The standards consider this increase through a constant value, which is a poor approximation, because it is clearly variable, depending on the joint displacement and because is much bigger, especially when using nut-washer fixings. It is also very important because of the rope effect trigger interesting mechanisms that avoids fragile failures without warning of the joints. For these reasons, it is essential to know how these configurations work, how they help the joint to resist the external loads and how much is the increase resistance capacity in relationship with the joint displacement. The methods used to address these issues consisted of a campaign of experimental tests using actual size specimens with flat surface dowels, threaded surface dowels and dowels with washer-nut fixings at their ends. The resistance capacity results obtained in all the cases has been compared with the values that will come using the equations in the standards. After the tests the specimens were cut to analyze the timber crushings, their widths, the positions and level of plasticizations suffer in the steel dowels and in the washer-nut fixings and the angle formed in the dowel plastic hinges. With all this information the failure mode suffered by the joints has been identified and compared with the ones that the standards predict. The results for the size materials and types of joints studied shows that the crush width average values go from 20 mm with flat surface dowels, to 24 mm in threaded to 32 mm in threaded with washer-nut fixings. The rope effect force/displacement goes from 100 N/m in threaded surface dowels to 500 N/m in threaded with washer-nut fixings. Finally, the load capacities are on average 290% higher those indicated in the standard. The main conclusion is that the rope effect force should be considered in the standards in more detail as a function of multiple variables, especially the displacement of the joint.

Solid-state reaction was used for Li7La3Zr2O12 material synthesis from Li2CO3, La2O3 and ZrO2 powders. Phase investigation of Li7La3Zr2O12 was carried out by x-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive x-ray spectroscopy (EDS) methods. The thermodynamic characteristics were investigated by calorimetry measurements. The molar heat capacity (Cp,m), the standard enthalpy of formation from binary compounds (ΔoxHLLZO) and from elements (ΔfHLLZO), entropy (S0298), the Gibbs free energy of the Li7La3Zr2O12 formation (∆f G0298) and the Gibbs free energy of the LLZO reaction with metallic Li (∆rGLLZO/Li) were determined. The corresponding values are Cp,m = 518.135 + 0.599 × T − 8.339 × T−2, (temperature range is 298–800 K), ΔoxHLLZO = −186.4 kJ·mol−1, ΔfHLLZO = −9327.65 ± 7.9 kJ·mol−1, S0298 = 362.3 J·mol−1·K−1, ∆f G0298 = −9435.6 kJ·mol−1, and ∆rGLLZO/Li = 8.2 kJ·mol−1, respectively. Thermodynamic performance shows the possibility of Li7La3Zr2O12 usage in lithium-ion batteries.

The preparation of ultra-high-performance concrete (UHPC) with both high-early-strength and good workability contributes to further promotion of its development and application. This study investigated the effects of different accelerators (SM, alkaline powder accelerator; SF, alkaline powder accelerator containing fluorine; and AF, alkali-free liquid accelerator containing fluorine) on the workability and strength properties of UHPC. The microstructure of UHPC was also characterized by using XRD and SEM. Several dosage levels of accelerators (2%, 4%, 6%, and 8% by mass) were selected. The results indicate that the setting time and fluidity of UHPC are gradually decreased with an increase in accelerators dosage. Compared with fluorine-containing SF/AF, fluorine-free SM evidently facilitates UHPC early strength gain speed. However, the fluorine-containing accelerators have a higher 28 d strength ratio, especially AF. The maximum compressive and flexural strength ratios are obtained at a dosage of 6%, which are 95.5% and 98.3%, respectively. XRD and SEM tests further reveal the effect of different accelerators on the macroscopic properties of UHPC from the micro level.

In one of our previously published articles, we reported the synthesis, spectroscopic, thermal, and catalytic properties of four new M(II) acetate (where M = Co, Ni, Cu, Zn) complexes with imidazole. Presented compounds exhibited activity in the reaction on catalytic oxidation of styrene. In this study we have synthesized and investigated properties of analogous compounds, however using formates or propionates of mentioned metal cations instead of acetates. Such an approach allowed us to draw valuable conclusions concerning the relationship between the carbon chain length and catalytic activity, which is an important factor for catalyst modeling. Synthesized compounds have been thoroughly investigated using appropriate analytic techniques: AAS (Atomic Absorption Spectrometry), FTIR (Fourier-Transform Infrared Spectroscopy), and TGA (Thermogravimetric Analysis). Catalytic properties have been studied under the same previous conditions, using GC-FID (GC-chromatograph equipped with FID detector).

The aim of the paper was to study the structure, magnetic properties and critical behavior of the Fe60Co12Gd4Mo3B21 alloy. The X-ray diffractometry and the Mössbauer spectroscopy studies confirmed amorphous structure. The analysis of temperature evolution of the exponent n (ΔSM = C·(Bmax)n) and the Arrott plots showed the second order phase transition in investigated material. The analysis of critical behavior was carried out in order to reveal the critical exponents and precise TC value. The ascertained critical exponents were used to determine the theoretical value of the exponent n, which corresponded well with experimental results.

This study aimed to determine the relative densities of populations of particles emitted in fire experiments of selected materials through direct measurement and parametrization of size distribution as number (NSD), volume (VSD), and mass (MSD). As objects of investigation, four typical materials used in construction and furniture were chosen: pinewood (PINE), laminated particle board (LPB), polyurethane (PUR), and poly(methyl methacrylate) (PMMA). The NSD and VSD were measured using an electric low-pressure impactor, while MSD was measured by weighing filters from the impactor using a microbalance. The parametrization of distributions was made assuming that each distribution can be expressed as the sum of an arbitrary number of log-normal distributions. In all materials, except PINE, the distributions of the particles emitted in fire experiments were the sum of two log-normal distributions; in PINE, the distribution was accounted for by only one log-normal distribution. The parametrization facilitated the determination of volume and mass abundances, and therefore, the relative density. The VSDs of particles generated in PINE, LPB, and PUR fires have similar location parameters, with a median volume diameter of 0.2–0.3 µm, whereas that of particles generated during PMMA burning is 0.7 µm. To validate the presented method, we burned samples made of the four materials in similar proportions and compared the measured VSD with the VSD predicted based on the weighted sum of VSD of raw materials. The measured VSD shifted toward smaller diameters than the predicted ones due to thermal decomposition at higher temperatures.

Based on electron backscatter diffraction (EBSD), hollow structures of Ni foam struts fabricated by electroplating on a chemically removable template were observed. Three-dimensional (3D) pore structures of Ni foams were also obtained using X-ray computed tomography (CT), and microstructural features such as porosity, pore size and strut thickness were statistically quantified. Evolution of microstructure and mechanical properties during ex situ compression of open-cell Ni-foams was investigated based on X-ray CT, and experimental results were compared with predictions by the finite element method (FEM). 3D microstructures obtained by X-ray CT revealed that the stress drop started with the buckling of struts at the center of the Ni-foams. The flow stress increased after the buckling of the struts spreads to most of the regions. For effective simulation of the compressive deformation and determination of the microstructural evolution, small domains of interest were selected from the entire set of observed 3D microstructures based on X-ray CT, and struts of Ni foams with a hollow structure were simplified with relevant thin-solid struts. Numerical 3D modeling comprehensively disclosed that compression caused the transverse buckling of the struts, with the bending and buckling of struts thus reducing the stress. Thickness variation of the struts causes a change in the porosity of Ni-foams without a change in pore shape or connectivity. The overall range of strut thickness was from 59 to 133 μm, and the range of porosity values was from 80% to 93.7%. A stress drop was predicted with a decrease in the strut thickness or an increase in the porosity, as measured experimentally. It was also found that the stress drop contributed to an increase in the calculated energy absorption efficiency.

In this work, a series of Bi2Te3/X mol% MoS2 (X = 0, 25, 50, 75) bulk nanocomposites were prepared by hydrothermal reaction followed by reactive spark plasma sintering (SPS). X-ray diffraction analysis (XRD) indicates that the native nanopowders, comprising of Bi2Te3/MoS2 heterostructure, are highly reactive during the electric field-assisted sintering by SPS. The nano-sized MoS2 particles react with the Bi2Te3 plates matrix forming a mixed-anion compound, Bi2Te2S, at the interface between the nanoplates. The transport properties characterizations revealed a significant influence of the nanocomposite structure formation on the native electrical conductivity, Seebeck coefficient, and thermal conductivity of the initial Bi2Te3 matrix. As a result, enhanced ZT values have been obtained in Bi2Te3/25 mol% MoS2 over the temperature range of 300–475 K induced mainly by a significant increase in the electrical conductivity.

Red mud and iron tailings are representative solid wastes in China, which have caused serious environmental pollution and potential harmful risk to people. Based on the alkali characteristic of Bayer red mud and natural fine-grained feature of iron tailings, these two solid wastes were used as raw materials to prepare alkali-activated cementitious mortar (AACM). The microstructure of C-A-S-H gel, pore structure characteristics, environmental impact and economic potential of this AACM were investigated. The results show that C-A-S-H gel was mainly composed of SiQ3 structure in the 28-day cured AACM. The relative content of SiQ4 structure increased while that of SiQ2 structure decreased as the hydration time advanced from 7 to 28 days, resulting in the increase of relative bridge oxygen value by 11.02%. The pores in the AACM sample accounted for 6.73% of the total volume, and these pores were not connected. The pore distribution was relatively uniform, which supported the good development of mechanical strength for AACM. This research elucidates the formation mechanism of C-A-S-H gels in the Bayer red mud–iron tailings-based AACM. In addition, the lower embodied carbon and material cost demonstrate that the prepared AACM has great environmental benefit and certain economic potential.

A timely knowledge of concrete and ultra-high-performance concrete (UHPC) strength is possible through the so-called strength-equivalent time (Et) curves. A timely knowledge of concrete strength is useful, for instance, to precisely determine when the shores of a hardening structural element can be safely removed. At the present time, the preparation of the strength-Et curves requires time-consuming and labor-intensive testing prior to the beginning of construction operations. This paper proposes an innovative method to derive the strength-Et and total heat-Et curves for both normal strength and UHPC. Results confirmed that the proposed method is fast, inexpensive, self-calibrating, accurate and can detect any variation of the concrete mix proportions or components quality. In addition, the quality of predictions of strength–maturity curves can be constantly improved as the specimens’ population increases. Finally, results obtained with the proposed method were compared with those obtained using standard methods, showing a good agreement.

A novel manufacturing approach was used to fabricate metallic scaffolds. A calibration of the laser cutting process was performed using the kerf width compensation in the calculations of the tool trajectory. Welding defects were studied through X-ray microtomography. Penetration depth and width resulted in relative errors of 9.4%, 1.0%, respectively. Microhardness was also measured, and the microstructure was studied in the base material. The microhardness values obtained were 400 HV, 237 HV, and 215 HV for the base material, HAZ, and fusion zone, respectively. No significant difference was found between the microhardness measurement along with different height positions of the scaffold. The scaffolds’ dimensions and porosity were measured, their internal architecture was observed with micro-computed tomography. The results indicated that geometries with dimensions under 500 µm with different shapes resulted in relative errors of ~2.7%. The fabricated scaffolds presented an average compressive modulus ~13.15 GPa, which is close to cortical bone properties. The proposed methodology showed a promising future in bone tissue engineering applications.

A new slurry cementation method was used to produce silicide-aluminide protective coatings on austenitic stainless steel 1.4541. The slurry cementation processes were carried out at temperatures of 800 and 1000 °C for 2 h with and without an additional oxidation process at a temperature of 1000 °C for 5 min. The microstructure and thickness of the coatings were studied by scanning electron microscopy (SEM). The intention was to produce coatings that would increase the heat resistance of the steel in a nitriding atmosphere. For this reason, the produced coatings were subjected to gas nitriding at a temperature of 550–570 °C in an atmosphere containing from 40 to 60% of ammonia. The nitriding was carried out using four time steps: 16, 51, 124, and 200 h, and microstructural observations using SEM were performed after each step. Analysis of the chemical composition of the aluminide coatings and reference sample was performed using wavelength (WDS) and energy (EDS) dispersive X-ray microanalysis, and phase analysis was carried out using X-ray diffraction (XRD). The resistance of the aluminide coatings in the nitriding atmosphere was found to depend strongly on the phase composition of the coating. The greatest increase in resistance to gas corrosion under nitriding atmosphere conditions was achieved using a manufacturing temperature of 1000 °C.

A series of strontium titanates-vanadates (STVN) with nominal cation composition Sr1-xTi1-y-zVyNizO3-δ (x = 0–0.04, y = 0.20–0.40 and z = 0.02–0.12) were prepared by a solid-state reaction route in 10% H2–N2 atmosphere and characterized under reducing conditions as potential fuel electrode materials for solid oxide fuel cells. Detailed phase evolution studies using XRD and SEM/EDS demonstrated that firing at temperatures as high as 1200 °C is required to eliminate undesirable secondary phases. Under such conditions, nickel tends to segregate as a metallic phase and is unlikely to incorporate into the perovskite lattice. Ceramic samples sintered at 1500 °C exhibited temperature-activated electrical conductivity that showed a weak p(O2) dependence and increased with vanadium content, reaching a maximum of ~17 S/cm at 1000 °C. STVN ceramics showed moderate thermal expansion coefficients (12.5–14.3 ppm/K at 25–1100 °C) compatible with that of yttria-stabilized zirconia (8YSZ). Porous STVN electrodes on 8YSZ solid electrolytes were fabricated at 1100 °C and studied using electrochemical impedance spectroscopy at 700–900 °C in an atmosphere of diluted humidified H2 under zero DC conditions. As-prepared STVN electrodes demonstrated comparatively poor electrochemical performance, which was attributed to insufficient intrinsic electrocatalytic activity and agglomeration of metallic nickel during the high-temperature synthetic procedure. Incorporation of an oxygen-ion-conducting Ce0.9Gd0.1O2-δ phase (20–30 wt.%) and nano-sized Ni as electrocatalyst (≥1 wt.%) into the porous electrode structure via infiltration resulted in a substantial improvement in electrochemical activity and reduction of electrode polarization resistance by 6–8 times at 900 °C and ≥ one order of magnitude at 800 °C.

Additive manufacturing enables innovative structural design for industrial applications, which allows the fabrication of lattice structures with enhanced mechanical properties, including a high strength-to-relative-density ratio. However, to commercialize lattice structures, it is necessary to define the designability of lattice geometries and characterize the associated mechanical responses, including the compressive strength. The objective of this study was to provide an optimized design process for lattice structures and develop a lattice structure characterization database that can be used to differentiate unit cell topologies and guide the unit cell selection for compression-dominated structures. Linear static finite element analysis (FEA), nonlinear FEA, and experimental tests were performed on 11 types of unit cell-based lattice structures with dimensions of 20 mm × 20 mm × 20 mm. Consequently, under the same relative density conditions, simple cubic, octahedron, truncated cube, and truncated octahedron-based lattice structures with a 3 × 3 × 3 array pattern showed the best axial compressive strength properties. Correlations among the unit cell types, lattice structure topologies, relative densities, unit cell array patterns, and mechanical properties were identified, indicating their influence in describing and predicting the behaviors of lattice structures.

In this paper, three commercial cermet powders, WC-Co-Cr, WC-Co and WC-Cr3C2-Ni, were sprayed by the High Velocity Oxy Fuel (HVOF) method onto magnesium alloy AZ31 substrate. The coatings were investigated in terms of their microstructure, phase analysis and residual stress. The manufactured coatings were analyzed extensively using optical microscopy (OM), X-ray diffraction (XRD), scanning (SEM) and transmission electron microscopy (TEM). Based on microstructure studies, it was noted that the coatings show satisfactory homogeneity. XRD analysis shows that in WC-Co, WC-Co-Cr and WC-Cr3C2-Ni coatings, main peaks are related to WC. Weaker peaks such as W2C, Co0.9W0.1, Co and W for WC-Co and W2C, Cr3C2 and Cr7C3 for WC-Cr3C2-Ni also occur. In all cermet coatings, linear stress showed compressive nature. In WC-Co and WC-Cr3C2-Ni, residual stress had a similar value, while in WC-Co-Cr, linear stress was lower. It was also proved that spraying onto magnesium substrate causes shear stress in the WC phase, most likely due to the low elastic modulus of magnesium alloy substrate.

ZnFe2O4 particles initially synthesized through a simple solvothermal method were coated using polyindole (PIn) to prepare an actively controllable core-shell typed hybrid material under both electric and magnetic fields. An advantage of this process is not needing to add the stabilizers or surfactants commonly used for uniform coating when synthesizing core or shell-structured particles. The synthesized ZnFe2O4/PIn particles have a lower density than conventional magnetic particles and have suitable properties as electrorheological (ER) particles. The expected spherical shape of the particles was proven using both scanning electron microscopy and transmission electron microscopy. The chemical characterization was performed using Fourier-transform infrared spectroscopy and X-ray diffraction analysis. To analyze the rheological properties, a ZnFe2O4/PIn based suspension was prepared, and dynamic rheological measurements were performed for different electric field strengths using a rotary rheometer. Both dynamic and elastic yield stresses of the ER fluid had a slope of 1.5, corresponding to the conductivity model. Excellent ER effect was confirmed through rheological analysis, and the prepared ER fluid had a reversible and immediate response to repeated electric fields.

This paper presents the results of experimental investigations performed on beams with corrugated webs. The aim of the research was to determine the effect of the geometric parameters of the sinusoidal web on the behavior of I-beams subjected to four-point bending. Special attention was paid to the effects of web thickness and wave geometry on the deflection of beams. The obtained failure modes of particular test samples are presented. Reference has also been made to the determined standard load capacities based on Annex D of the EC3 standard. In order to compare the performance of beams with corrugated webs, the results for beams with flat webs of the same thickness of web sheets are also presented.

From the producers’ point of view, there is no universal and quick method to predict bruise area when dropping an apple from a certain height onto a certain type of substrate. In this study the authors presented a very simple method to estimate bruise volume based on drop height and substrate material. Three varieties of apples were selected for the study: Idared, Golden Delicious, and Jonagold. Their weight, turgor, moisture, and sugar content were measured to determine morphological differences. In the next step, fruit bruise volumes were determined after a free fall test from a height of 10 to 150 mm in 10 mm increments. Based on the results of the research, linear regression models were performed to predict bruise volume on the basis of the drop height and type of substrate on which the fruit was dropped. Wood and concrete represented the stiffest substrates and it was expected that wood would respond more subtly during the free fall test. Meanwhile, wood appeared to react almost identically to concrete. Corrugated cardboard minimized bruising at the lowest discharge heights, but as the drop height increased, the cardboard degraded and the apple bruising level reached the results as for wood and concrete. Contrary to cardboard, the foam protected apples from bruising up to a drop height of 50 mm and absorbed kinetic energy up to the highest drop heights. Idared proved to be the most resistant to damage, while Golden Delicious was medium and Jonagold was least resistant to damage. Numerical models are a practical tool to quickly estimate bruise volume with an accuracy of about 75% for collective models (including all cultivars dropped on each of the given substrate) and 93% for separate models (including single cultivar dropped on each of the given substrate).

The non-heat-treated, die-cast aluminum alloy samples were prepared meticulously via die-casting technology. The crystal structure, microstructure, and phase composition of the samples were comprehensively studied through electron backscatter diffraction (EBSD), metallographic microscopy, spectrometer, and transmission electron microscopy (TEM). The microhardness and tensile properties of the samples were tested. The die-cast samples were found to have desirable properties by studying the structure and performance of the samples. There were no defects, such as pores, cold partitions, or surface cracks, found. The metallographic structure of the samples was mainly α-Al, and various phases were distributed at the grain boundaries. Before heat treating, α-Al grains were mainly equiaxed with a great number of second phase particles at the grain boundaries. After heat treating, the α-Al grains were massive and coarsened, and the second phase grains were refined and uniformly distributed, compared with those before the heat treating. The EBSD results showed that the grain boundary Si particles were solid solution decomposed after heat treatment. The particles became smaller, and their distribution was more uniform. Transmission electron microscopy found that there were nano-scale Al-Mn, Al-Cu, and Cu phases dispersed in the samples. The average microhardness of the samples before heat treating was 114 HV0.1, while, after the heat treating, the microhardness reached 121 HV0.1. The mechanical features of the samples were tremendous, and the obtained die-cast aluminum alloy had non-heat-treatment performance, which was greater than the ordinary die-cast aluminum alloys with a similar composition. The tensile strength of the aluminum alloys reached up to 310 MPa before heat treatment.

The study aimed to analyze whether the high compression of unique, tight-fitting sportswear influences the clothing physiology comfort of the athlete. Three specific sportswear with different compression were tested on four subjects while they were running on a treadmill with increasing intensity. The compression effect of the sportswear on the body of the test persons, the temperature distribution of the subjects, and the intensity of their perspiration during running were determined. The results indicate that the compression effect exerted by the garments significantly influences the clothing physiology comfort of the athlete; a higher compression load leads to more intense sweating and higher skin temperature.

The objective of the contribution is to understand the fatigue bond behaviour of brass-coated high-strength micro steel fibres embedded in ultra-high performance concrete (UHPC). The study contains experimental pullout tests with variating parameters like load amplitude, fibre orientation, and fibre-embedded length. The test results show that fibres are generally pulled out of the concrete under monotonic loading and rupture partly under cyclic tensile loading. The maximum tensile stress per fibre is approximately 1176 N/mm2, which is approximately one third of the fibre tensile strength (3576 N/mm2). The load-displacement curves under monotonic loading were transformed into a bond stress-slip relationship, which includes the effect of fibre orientation. The highest bond stress occurs for an orientation of 30° by approximately 10 N/mm2. Under cyclic loading, no rupture occurs for fibres with an orientation of 90° within 100,000 load changes. Established S/N-curves of 30°- and 45°-inclined fibres do not show fatigue resistance of more than 1,000,000 load cycles for each tested load amplitude. For the simulation of fibre pullout tests with three-dimensional FEM, a model was developed that describes the local debonding between micro steel fibre and the UHPC-matrix and captures the elastic and inelastic stress-deformation behaviour of the interface using plasticity theory and a damage formulation. The model for the bond zone includes transverse pressure-independent composite mechanisms, such as adhesion and micro-interlocking and transverse pressure-induced static and sliding friction. This allows one to represent the interaction of the coupled structures with the bond zone. The progressive cracking in the contact zone and associated effects on the fibre load-bearing capacity are the decisive factors concerning the failure of the bond zone. With the developed model, it is possible to make detailed statements regarding the stress-deformation state along the fibre length. The fatigue process of the fibre-matrix bond with respect to cyclic loading is presented and analysed in the paper.

In ferromagnetic semiconductors, the coupling of magnetic ordering with semiconductor character accelerates the quantum computing. The structural stability, Curie temperature (Tc), spin polarization, half magnetic ferromagnetism and transport properties of ZnX2Se4 (X = Ti, V, Cr) chalcogenides for spintronic and thermoelectric applications are studied here by density functional theory (DFT). The highest value of Tc is perceived for ZnCr2Se4. The band structures in both spin channels confirmed half metallic ferromagnetic behavior, which is approved by integer magnetic moments (2, 3, 4) μB of Ti, V and Cr based spinels. The HM behavior is further measured by computing crystal field energy ΔEcrystal, exchange energies Δx(d), Δx (pd) and exchange constants (Noα and Noβ). The thermoelectric properties are addressed in terms of electrical conductivity, thermal conductivity, Seebeck coefficient and power factor in within a temperature range 0–400 K. The positive Seebeck coefficient shows p-type character and the PF is highest for ZnTi2Se4 (1.2 × 1011 W/mK2) among studied compounds.

Bridges play an increasingly more important role in modern transportation, which is why many sensors are mounted on it in order to provide safety. However, supplying reliable power to these sensors has always been a great challenge. Scavenging energy from bridge vibration to power the wireless sensors has attracted more attention in recent years. Moreover, it has been proved that the linear energy harvester cannot always work efficiently since the vibration energy of the bridge distributes over a broad frequency band. In this paper, a nonlinear energy harvester is proposed to enhance the performance of harvesting bridge vibration energy. Analyses on potential energy, restoring force, and stiffness were carried out. By adjusting the separation distance between magnets, the harvester could own a low and flat potential energy, which could help the harvester oscillate on a high-energy orbit and generate high output. For validation, corresponding experiments were carried out. The results show that the output of the optimal configuration outperforms that of the linear one. Moreover, with the increase in vehicle speed, a component of extremely low frequency is gradually enhanced, which corresponds to the motion on the high-energy orbit. This study may give an effective method of harvesting energy from bridge vibration excited by moving vehicles with different moving speeds.

Aluminum matrix composites reinforced by CoCrFeMnNi high entropy alloy (HEA) particulates were fabricated using the stir casting process. The as-cast specimens were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). The results indicated that flake-like silicon particles and HEA particles were distributed uniformly in the aluminum matrix. TEM micrographs revealed the presence of both the matrix and reinforcement phases, and no intermetallic phases were formed at the interface of the matrix and reinforcement phases. The mechanical properties of hardness and tensile strength increased with an increase in the HEA content. The Al 6063–5 wt.% HEA composite had a ultimate tensile strength (UTS) of approximately 197 MPa with a reasonable ductility (around 4.05%). The LM25–5 wt.% HEA composite had a UTS of approximately 195 Mpa. However, the percent elongation decreased to roughly 3.80%. When the reinforcement content increased to 10 wt.% in the LM25 composite, the UTS reached 210 MPpa, and the elongation was confined to roughly 3.40%. The fracture morphology changed from dimple structures to cleavage planes on the fracture surface with HEA weight percentage enhancement. The LM25 alloy reinforced with HEA particles showed enhanced mechanical strength without a significant loss of ductility; this composite may find application in marine and ship building industries.

The inductively coupled plasma reactive ion etching (ICP-RIE) is a selective dry etching method used in fabrication technology of various semiconductor devices. The etching is used to form non-planar microstructures—trenches or mesa structures, and tilted sidewalls with a controlled angle. The ICP-RIE method combining a high finishing accuracy and reproducibility is excellent for etching hard materials, such as SiC, GaN or diamond. The paper presents a review of silicon carbide etching—principles of the ICP-RIE method, the results of SiC etching and undesired phenomena of the ICP-RIE process are presented. The article includes SEM photos and experimental results obtained from different ICP-RIE processes. The influence of O2 addition to the SF6 plasma as well as the change of both RIE and ICP power on the etching rate of the Cr mask used in processes and on the selectivity of SiC/Cr etching are reported for the first time. SiC is an attractive semiconductor with many excellent properties, that can bring huge potential benefits thorough advances in submicron semiconductor processing technology. Recently, there has been an interest in SiC due to its potential wide application in power electronics, in particular in automotive, renewable energy and rail transport.

Materials 15(1), 46 (2022). doi:10.3390/ma15010046, Here, we present the (element-specific) magnetic properties and cation ordering for ultrathin Co-rich cobalt ferrite films. Two Co-rich Co$_x$Fe$_{3−x}$O$_4$ films with different stoichiometry (x=1.1 and x=1.4) have been formed by reactive solid phase epitaxy due to post-deposition annealing from epitaxial CoO/Fe$_3$O$_4$ bilayers deposited before on Nb-doped SrTiO$_3$(001). The electronic structure, stoichiometry and homogeneity of the cation distribution of the resulting cobalt ferrite films were verified by angle-resolved hard X-ray photoelectron spectroscopy. From X-ray magnetic circular dichroism measurements, the occupancies of the different sublattices were determined using charge-transfer multiplet calculations. For both ferrite films, a partially inverse spinel structure is found with increased amount of Co$^{3+}$ cations in the low-spin state on octahedral sites for the Co$_{1.4}$Fe$_{1.6}$O$_4$ film. These findings concur with the results obtained by superconducting quantum interference device measurements. Further, the latter measurements revealed the presence of an additional soft magnetic phase probably due to cobalt ferrite islands emerging from the surface, as suggested by atomic force microscope measurements., Published by MDPI, Basel

The generated sp2 hybrid conjugate structure of a C atom, which resulted from the chemical reaction affected by temperature and time, is an effective six-membered ring planar structure of the final carbon fiber. This kind of hybrid conjugate structure determined the formation of the final structure and mechanical properties of carbon fiber. In this paper, the formation and evolution of sp2 hybrid conjugated structures of PAN precursor during thermal stabilization were investigated by Raman, UV-vis and 13C-NMR methods. The results indicated that with the increase of stabilization temperature, the degree of the sp2 hybrid conjugated structure of stabilized PAN fiber increases “linearly”, while the content of the sp2 hybrid carbon atoms increases with “S-type”. The final sp2 hybrid conjugated ring structure is mainly composed of single-ring, double-ring, triple-ring, and double-bond structures. Compared with the time factor, the temperature effect plays a decisive role in the formation of the sp2 hybrid conjugate structure.