1. Construction of a New 3D Zn(II) MOF with a mog Topology From 2-(Hydroxymethyl)-1H-imidazole-4,5-dicarboxylate.
- Author
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Cai, Song-Liang, Huang, Xiao-Ling, He, Zi-Hao, Lin, Hui-Mei, Zheng, Sheng-Run, and Zhang, Wei-Guang
- Subjects
IMIDAZOLES ,DICARBOXYLIC acids ,HYDROXYMETHYL compounds ,X-ray diffraction ,ZINC - Abstract
Abstract: A new 3D Zn(II) MOF based on 2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylic acid (H
4 hmIDC), formulated as {[Zn3 (HhmIDC)2 (H2 O)2 ]·2H2 O}n , has been successfully prepared under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, elemental analysis and infrared spectroscopy, as well as power X-ray diffraction. It is worth noting that the unique HhmIDC3− ligand in the title compound adopts an unusual coordination mode, namely µ4 -kN,O: kN′,O′: kO″,O‴: kO′′′′ to link the Zn(II) ions into an interesting 3D coordination framework. Such a 3D network can be further simplified as a binodal 4-connected mog (moganite) topology with the Schläfli symbol of (4·64 ·8)2 (42 ·62 ·82 ). Moreover, the title Zn(II) MOF shows a relatively high thermal stability up to 340 °C, and exhibits an intense blue emission centered at 450 nm upon excitation at 370 nm.Graphical Abstract: A new 3D microporous Zn(II) MOF with an uncommon binodal 4-connected mog topology has been constructed from 2-(hydroxymethyl)-1H-imidazole-4,5-dicarboxylic acid (H4 hmIDC). Such a Zn(II) MOF displays a relatively high thermal stability and exhibits very strong blue photoluminescence with a maximum emission band at 450 nm when excited at 370 nm.[ABSTRACT FROM AUTHOR]
- Published
- 2018
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