1. Effect of Bi-substitution on the dielectric properties of polycrystalline yttrium iron garnet
- Author
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Zhao, Hongjie, Zhou, Ji, Bai, Yang, Gui, Zhilun, and Li, Longtu
- Subjects
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GARNET , *DIELECTRICS , *ELECTRICAL engineering materials , *SILICATE minerals - Abstract
The effect of Bi-substitution on the dielectric properties of yttrium iron garnet (YIG) was studied in this paper. The Bi-substituted YIG (YIG:Bi) polycrystalline samples, having composition of Y3-xBixFe5O12, were prepared by the solid-state reaction method.
x varied from 0 to 1.2. The phase formation and microstructure were performed by X-ray diffraction and scanning electron microscopy, respectively. Ions valency was identified by X-ray photoelectron spectroscopy. The impedance analyzers are used to measure the frequency dependence and the temperature dependence of relative dielectric constant (#x03B5;r ) and loss tangent (tan δ ). The experimental results show that the Bi-substitution lowers the phase formation and sintering temperature. Electronic carrier concentration drops dramatically due to limitation of ferric valency variation. Hence,#x03B5;r andtan δ decrease with addition of Bi. Dispersion characteristic indicates non-Debye-type dispersion. A maximum of#x03B5;r appears as the temperature rises. [Copyright &y& Elsevier]- Published
- 2004
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