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Abstract: A novel SOFC system control strategy has been developed for rapid load following. The strategy was motivated from the performance of a baseline control strategy developed from control concepts in the literature. The basis for the fuel cell system control concepts are explained by a simplified order of magnitude time scale analysis. The control concepts are then investigated in a detailed quasi-two-dimensional integrated dynamic system model that resolves the physics of heat transfer, chemical kinetics, mass convection and electrochemistry within the system. The baseline control strategy is based on the standard operating method of constant utilization with no control of the combustor temperature. Simulation indicates that with this control strategy large combustor transients can take place during load transients because the fuel flow to the combustor increases faster than the air flow. To alleviate this problem, a novel control structure that maintains the combustor temperature within acceptable ranges without any supplementary hardware was introduced. The combustor temperature is controlled by manipulating the current to change the combustor inlet stoichiometry. The load following capability of SOFC systems is inherently limited by anode compartment fuel depletion during the time of fuel delivery delay. This research indicates that future SOFC systems with proper system and control configurations can exhibit excellent load following characteristics. [Copyright &y& Elsevier]

Abstract: A detailed dynamic model incorporating geometric resolution of a molten carbonate fuel cell (MCFC) with dynamic simulation of physical and electrochemical processes in the stream-wise direction is presented. The model was developed using mass and momentum conservation, electrochemical and chemical reaction mechanisms, and heat-transfer. Results from the model are compared with data from an experimental MCFC unit. Furthermore, the model was applied to predict dynamic variations of voltage, current and temperature in an MCFC as it responds to varying load demands. The voltage was evaluated using two different approaches: one applying a model developed by Yuh and Selman [C.Y. Yuh, J.R. Selman, The polarization of molten carbonate fuel cell electrodes: I. Analysis of steady-state polarization data, J. Electrochem. Soc. 138 (1991) 3642–3648; C.Y. Yuh, J.R. Selman, The polarization of molten carbonate fuel cell electrodes: II. Characterization by AC impedance and response to current interruption, J. Electrochem. Soc. 138 (1991) 3649–3655] and another applying simplified equations using average local temperatures and pressures. The results show that both models can be used to predict voltage and dynamic response characteristics of an MCFC and the model that uses the more detailed Yuh and Selman approach can predict those accurately and consistently for a variety of operating conditions. [Copyright &y& Elsevier]

Abstract: Current high temperature fuel cell (HTFC) systems used for stationary power applications (in the 200–300kW size range) have very limited dynamic load following capability or are simply base load devices. Considering the economics of existing electric utility rate structures, there is little incentive to increase HTFC ramping capability beyond 1kWs−1 (0.4%s−1). However, in order to ease concerns about grid instabilities from utility companies and increase market adoption, HTFC systems will have to increase their ramping abilities, and will likely have to incorporate electrical energy storage (EES). Because batteries have low power densities and limited lifetimes in highly cyclic applications, ultra capacitors may be the EES medium of choice. The current analyses show that, because ultra capacitors have a very low energy storage density, their integration with HTFC systems may not be feasible unless the fuel cell has a ramp rate approaching 10kWs−1 (4%s−1) when using a worst-case design analysis. This requirement for fast dynamic load response characteristics can be reduced to 1kWs−1 by utilizing high resolution demand data to properly size ultra capacitor systems and through demand management techniques that reduce load volatility. [Copyright &y& Elsevier]

Abstract: Several methods to prevent fuel starvation in solid oxide fuel cells are developed and investigated. Fuel starvation can occur during transients, if fuel is consumed in the fuel cell faster than it can be supplied by the fuel processing and delivery system. It is demonstrated through simulation that fuel depletion can occur in the fuel cell if no corrective action is employed. Fuel starvation can be prevented by the use of rate limiters, reference governors, and modifications to the fuel-flow controller. The various methods to prevent fuel depletion within the fuel cell are developed and compared. Analysis indicates that reference governors can avoid hydrogen depletion with much less of an impact on transient load following capability than rate limiters. Hence, various reference governors ranging in level of fidelity were developed and compared for performance. It was further demonstrated that with knowledge of the fuel preprocessor response, it is possible to manipulate the fuel flow to minimize reformer flow dynamics, minimizing the need to govern the fuel cell transient capability. [Copyright &y& Elsevier]

Abstract: This study is focused on a hybrid fuel cell/gas turbine (FC/GT) system with an atmospheric pressure solid oxide fuel cell (SOFC). The impact of the gas turbine rotational speed on dynamic performance and controllability of a hybrid system is investigated. The transient response of the FC/GT system to perturbations in the power demand has been investigated. Two operational strategies of gas turbines are compared: (1) fixed speed operation, and (2) variable speed operation. For both operation strategies, a wide range of power production is numerically simulated. The results show that variable speed operation is superior for the FC/GT hybrid configuration studied. Variable speed operation allows a 50% turn down in power with no additional balance of plant equipment required. The system efficiency is maintained above 66% for variable speed operation compared to 53% for fixed speed operation with auxiliary combustion. [Copyright &y& Elsevier]