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On the basis of observations using Cs-corrected STEM, we identified three types of surface modification probably formed by space weathering on the surfaces of Itokawa particles. They are (1) redeposition rims (2-3 nm), (2) composite rims (30-60 nm), and (3) composite vesicular rims (60-80 nm). These rims are characterized by a combination of three zones. Zone I occupies the outermost part of the surface modification, which contains elements that are not included in the unchanged substrate minerals, suggesting that this zone is composed of sputter deposits and/or impact vapor deposits originating from the surrounding minerals. Redeposition rims are composed only of Zone I and directly attaches to the unchanged minerals (Zone III). Zone I of composite and composite vesicular rims often contains nanophase (Fe,Mg)S. The composite rims and the composite vesicular rims have a two-layered structure: a combination of Zone I and Zone II, below which Zone III exists. Zone II is the partially amorphized zone. Zone II of ferromagnesian silicates contains abundant nanophase Fe. Radiation-induced segregation and in situ reduction are the most plausible mechanisms to form nanophase Fe in Zone II. Their lattice fringes indicate that they contain metallic iron, which probably causes the reddening of the reflectance spectra of Itokawa. Zone II of the composite vesicular rims contains vesicles. The vesicles in Zone II were probably formed by segregation of solar wind He implanted in this zone. The textures strongly suggest that solar wind irradiation damage and implantation are the major causes of surface modification and space weathering on Itokawa. [ABSTRACT FROM AUTHOR]

The mineralogy and mineral chemistry of Itokawa dust particles captured during the first and second touchdowns on the MUSES-C Regio were characterized by synchrotron-radiation X-ray diffraction and field-emission electron microprobe analysis. Olivine and low- and high-Ca pyroxene, plagioclase, and merrillite compositions of the first-touchdown particles are similar to those of the second-touchdown particles. The two touchdown sites are separated by approximately 100 meters and therefore the similarity suggests that MUSES-C Regio is covered with dust particles of uniform mineral chemistry of LL chondrites. Quantitative compositional properties of 48 dust particles, including both first- and second-touchdown samples, indicate that dust particles of MUSES-C Regio have experienced prolonged thermal metamorphism, but they are not fully equilibrated in terms of chemical composition. This suggests that MUSES-C particles were heated in a single asteroid at different temperatures. During slow cooling from a peak temperature of approximately 800 °C, chemical compositions of plagioclase and K-feldspar seem to have been modified: Ab and Or contents changed during cooling, but An did not. This compositional modification is reproduced by a numerical simulation that modeled the cooling process of a 50 km sized Itokawa parent asteroid. After cooling, some particles have been heavily impacted and heated, which resulted in heterogeneous distributions of Na and K within plagioclase crystals. Impact-induced chemical modification of plagioclase was verified by a comparison to a shock vein in the Kilabo LL6 ordinary chondrite where Na-K distributions of plagioclase have been disturbed. [ABSTRACT FROM AUTHOR]