1. KMn[O.sub.4] determination of active carbon for laboratory routines: three long-term field experiments in Austria
- Author
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Tatzber, M., Schlatter, N., Baumgarten, A., Dersch, G., Korner, R., Lehtinen, T., Unger, G., Mifek, E., and Spiegel, H.
- Subjects
Oxalic acid -- Analysis ,Soils -- Carbon content ,Oxalates -- Analysis ,Cropping systems -- Analysis ,Soil management -- Analysis ,Agricultural industry ,Earth sciences ,Soil Science Society of America - Abstract
Recent studies show that a labile soil carbon (C) fraction determined with potassium permanganate (KMn[O.sub.4]) reflects the type of soil management. The present study combines the method for determining the active C (AC) pool with an alternative titration of the 0.02 m KMn[O.sub.4] solution with sodium oxalate ([Na.sub.2][C.sub.2]4) for routine laboratory analyses. Three long-term field experiments investigated: (i) different cropping systems and [sup.14]C-labelled organic amendments, (if) three different tillage systems, and (iii) the application of four different kinds of compost. The results showed the depletion of AC in the permanent bare-fallow system of the [sup.14]C-labelled field experiment. When calculating the ratio AC/total organic C (TOC), the depletion of the AC/TOC curve reflected a priming effect, in accord with previous work. We obtained significant positive correlations of AC with TOC, total nitrogen ([N.sub.t]), humic acid-C and remaining [sup.14]C-labelled material. The AC in the tillage systems experiment was significantly (Pc 0.05) different between all three tillage treatments at 0-10 cm depth, and the ratio AC/TOC also revealed a significant difference between minimum and conventional tillage treatments at 10-20 cm. For the compost field experiment, significant differences occurred between plots fertilised solely with N and plots receiving organic amendments. The AC/TOC ratio of the sewage sludge amendment was significantly lower than in all other systems. Correlations of AC with TOC for all samples of the different long-term field experiments revealed different behaviours in different soil types. The correlations of AC with [N.sub.t] showed higher coefficients than with TOC. The applied methodology has a potential for sensitive and reliable detections of differences in soil organic matter characteristics. Additional keywords: [sup.14]C label, compost, cropping systems, SOM, tillage systems, titration., Introduction Global storage of soil organic carbon (SOC) is estimated to be 1502 Pg C in the first metre of soil (Jobbagy and Jackson 2000), including active and more stable [...]
- Published
- 2015
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