1. Low‐Temperature Potassium Batteries Enabled by Electric and Thermal Field Regulation.
- Author
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Liu, Yanfang, Shi, Yating, Gao, Caitian, Shi, Zude, Ding, Hongbo, Feng, Yanhong, He, Yongmin, Sha, Junwei, Zhou, Jiang, and Lu, Bingan
- Subjects
ELECTRIC batteries ,ELECTRIC fields ,POTASSIUM ,THERMAL conductivity ,POTASSIUM ions ,TEMPERATURE distribution - Abstract
Recharging batteries operate at sub‐zero temperature is usually limited by the slow ion diffusion and uneven charge distribution at low temperature. Here, we report a strategy to regulate electric field and thermal field simultaneously, creating a fast and uniform deposition surroundings for potassium ion in potassium metal batteries (PMBs). This regulation is achieved by using a highly ordered 1D nanoarray electrode which provides a dense and flat surface for uniforming the electric field and high thermal conductivity for reducing the temperature fluctuation. Consequently, this electrode could achieve high‐areal capacity of 10 mAh cm−2. Besides, the dependence of potassium nucleation on temperature is unveiled. Furthermore, a full‐cell could steady operate with over 80 % of its room‐temperature capacity at −20 °C. Those respectable performances demonstrate that this strategy is valid, potentially providing guidelines for the rational design of advanced electrodes toward PMBs. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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