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Since I was a young student, becoming a researcher has been my dream. With such an ambitious desire, you can easily imagine why I decided to pursue a PhD study immediately after graduation. Luckily, I had the opportunity to join the Technology Innovation Laboratory of the University of Bologna, led by Professors Andrea Cavallini and Davide Fabiani, both being well recognized in the world as high voltage insulation experts.

The research on nanofluids has shown important improvements of the electrical performance, but so far the attention has only been focused on their use in transformers. The target of this work is to understand if nanofluids can be applied as insulators for power electronics modules, where the major stresses are caused by square waves or PWM voltages. Breakdown events in non-uniform field conditions and different voltage configurations have been deeply investigated revealing the effects of space charge mechanisms. While for DC fields the nanofluids contribution is positive, a completely different conclusion can be evinced from sinusoidal and square waves, where the situation even worsens at higher frequencies. Schlieren images of breakdown events seem to confirm the postulated hypotheses.

A recent investigation on the DC stability of nanofluids has revealed some interesting phenomena regarding the polarization current; some unexpected slow peaks appeared after the voltage reached a precise value. In this work we have deepened and analyzed the possible mechanisms which could cause such experimental results. While in low concentration nanofluids a charge trapping mechanism seems to be the prevailing one, at higher concentration, the reduced nanoparticles distances and the lower energy barrier between two consecutive nanoparticles is able to activate the tunneling charge transfer among them, thus increasing their apparent mobility.

We have compared the DC conduction of a nanofluid based on mineral oil and magnetite nanoparticles with that of the base mineral oil using a point/plane electrode configuration. The results show that the nanofluid has higher conduction currents and that transition from ohmic to tunneling-controlled conduction occurs at higher fields. This latter evidence might explain why nanofluids improve partial discharge inception voltage under AC conditions. After some tests we observed that the nanofluid is not stable under DC: the nanoparticles are separated from the base fluid by coulombic forces and dielectrophoresis. We have compared the DC conduction of a nanofluid based on mineral oil and magnetite nanoparticles with that of the base mineral oil using a point/plane electrode configuration. The results show that the nanofluid has higher conduction currents and that transition from ohmic to tunneling-controlled conduction occurs at higher fields. This latter evidence might explain why nanofluids improve partial discharge inception voltage under AC conditions. After some tests we observed that the nanofluid is not stable under DC: the nanoparticles are separated from the base fluid by coulombic forces and dielectrophoresis.

In this work, we compare the dielectric withstand performance of nanofluids prepared using Shell Diala D as a base fluid, and magnetite, graphene oxide and silicone dioxide as nanoadditives. The ac withstand capability of the nanofluids was investigated as well as partial discharge inception voltage, partial discharge and repetition rate under ac, dc positive and dc negative voltages. The results indicate that, for all nanofluids, nanoparticle concentrations around 0.2 g/l enhance dielectric withstand properties under quasi uniform fields. Under divergent fields, partial discharge characteristics are improved under ac conditions. Under dc conditions silica nanofluid performs better than mineral oil, but the other two nanofluids do not perform well. In this work, we compare the dielectric withstand performance of nanofluids prepared using Shell Diala D as a base fluid, and magnetite, graphene oxide and silicone dioxide as nanoadditives. The ac withstand capability of the nanofluids was investigated as well as partial discharge inception voltage, partial discharge and repetition rate under ac, dc positive and dc negative voltages. The results indicate that, for all nanofluids, nanoparticle concentrations around 0.2 g/l enhance dielectric withstand properties under quasi uniform fields. Under divergent fields, partial discharge characteristics are improved under ac conditions. Under dc conditions silica nanofluid performs better than mineral oil, but the other two nanofluids do not perform well.