1. Optimum Pt and Ru atomic composition of carbon-supported Pt–Ru alloy electrocatalyst for methanol oxidation studied by the polygonal barrel-sputtering method
- Author
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Hiromi, Chikako, Inoue, Mitsuhiro, Taguchi, Akira, and Abe, Takayuki
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PLATINUM alloys , *ELECTROCATALYSIS , *CARBON , *CATALYST supports , *METHANOL , *OXIDATION , *MAGNETRON sputtering , *FUEL cells - Abstract
Abstract: The optimum Pt and Ru atomic composition of a carbon-supported Pt–Ru alloy (Pt–Ru/C) used in a practical direct methanol fuel cell (DMFC) anode was investigated. The samples were prepared by the polygonal barrel-sputtering method. Based on the physical properties of the prepared Pt–Ru/C samples, the Pt–Ru alloy was found to be deposited on a carbon support. The microscopic characterization showed that the deposited alloy forms nanoparticles, of which the atomic ratios of Pt and Ru (Pt:Ru ratios) are uniform and are in accordance with the overall Pt:Ru ratios of the samples. The formation of the Pt–Ru alloy is also supported by the electrochemical characterization. Based on these results, methanol oxidation on the Pt–Ru/C samples was measured by cyclic voltammetry and chronoamperometry. The results indicated that the methanol oxidation activities of the prepared samples depended on the Pt:Ru ratios, of which the optimum Pt:Ru ratio is 58:42at.% at 25°C and 50:50at.% at 40 and 60°C. This temperature dependence of the optimum Pt:Ru ratio is well explained by the relationship between the methanol oxidation reaction process and the temperature, which is reflected in the rate-determining steps considered from the activation energies. It should be noted that at 25–60°C, the Pt–Ru/C with Pt:Ru=50:50at.% prepared by our sputtering method has the higher methanol oxidation activity than that of a commercially available sample with the identical overall Pt:Ru ratio. Consequently, the polygonal barrel-sputtering method is useful to prepare the practical DMFC anode catalysts with the high methanol oxidation activity. [Copyright &y& Elsevier]
- Published
- 2011
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