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In the field of dye‐sensitized solar cells (DSSCs), although Pt is commonly used as counter electrode materials owing to its great electrocatalytic activity and conductivity, the high price and small reserves of Pt limit its large‐scale application. In this paper, heteromorphic Ni decorated Fe‐containing carbon nanofibers (Ni/NiO@Fe‐CNFs) was prepared by a thermal synthesis method, and applied as composite counter electrode materials for DSSCs. It was found that the as‐synthesized Ni/NiO@Fe‐CNFs shows better electrocatalytic activity than that of Fe‐CNFs and CNFs for the reduction reaction of triiodide to iodide. The improved electrocatalytic activity is not only attributed to the introduction of Fe2O3 to form Fe‐CNFs, but also attributed to the heteromorphic Ni decoration and their synergistic effect. The photoelectric conversion efficiency of DSSCs with Ni/NiO@Fe‐CNFs counter electrode is 4.81 %, much higher than that of CNFs (0.62 %) and Fe‐CNFs counter electrode (3.65 %), and comparable to the value of Pt counter electrode (5.10 %). Accordingly, the Ni/NiO@Fe‐CNFs is expected to be a potential counter electrode material to replace Pt. [ABSTRACT FROM AUTHOR]

To screen out suitable electrode materials and overcome the shortcomings of the existed electrode materials for the application in dye-sensitized solar cells and supercapacitors, NiS 2 /reduced graphene oxide (NiS 2 /rGO) composite material was prepared by a simple one-step hydrothermal method in this paper and applied in the field of both dye-sensitized solar cells and supercapacitors as electrode material. In an electrolyte of 6 M KOH, the NiS 2 /rGO composite material with bilayer capacitance characteristics exhibited a high specific capacitance of 259.20 F g−1 at the current density of 0.6 A g−1, which was significantly higher than that of rGO (188.94 F g−1). Moreover, at a current density of 2 A g−1, the NiS 2 /rGO composite material had 92.85% capacitance retention after 2000 cycles. When applied as counter electrode material for the dye-sensitized solar cells, the NiS 2 /rGO composite material counter electrode exhibited a satisfactory photoelectric conversion efficiency (η) of 3.16% under standard simulated sunlight (AM 1.5 G), which was significantly higher than that of single rGO counter electrode (improved by 90.40%). The NiS 2 /rGO composite electrode material prepared by a simple one-step hydrothermal method is a potential bi-functional composite electrode materials for both dye-sensitized solar cells and supercapacitors. [Display omitted] • NiS 2 /reduced graphene oxide composite was prepared by one-step hydrothermal method. • NiS 2 /reduced graphene oxide exhibits excellent electrochemical performance. • High photoelectric conversion efficiency was obtained for dye sensitized solar cells. • Excellent specific capacitance and durability were obtained for supercapacitors. [ABSTRACT FROM AUTHOR]