1. On the Mechanism of Magnesium Storage in Microand Nano-Particulate Tin Battery Electrodes.
- Author
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Nacimiento, Francisco, Cabello, Marta, Pérez-Vicente, Carlos, Alcántara, Ricardo, Lavela, Pedro, Ortiz, Gregorio F., and Tirado, José L.
- Subjects
ELECTRODES ,NANOPARTICLES ,DIFFUSION - Abstract
This study reports on the electrochemical alloying-dealloying properties of Mg
2 Sn intermetallic compounds.119 Sn Mössbauer spectra of β-Sn powder, thermally alloyed cubic-Mg2 Sn, and an intermediate MgSn nominal composition are used as references. The discharge of a Mg/micro-Sn half-cell led to significant changes in the spectra line shape, which is explained by a multiphase mechanism involving the coexistence of c-Mg2 Sn, distorted Mg2 -δ Sn, and Mg-doped β-Sn. Capacities and capacity retention were improved by using nanoparticulate tin electrodes. This material reduces significantly the diffusion lengths for magnesium and contains surface SnO and SnO2 , which are partially electroactive. The half-cell potentials were suitable to be combined versus the MgMn2 O4 cathodes. Energy density and cycling properties of the resulting full Mg-ion cells are also scrutinized. [ABSTRACT FROM AUTHOR]- Published
- 2018
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