1. Densification by Compaction as an Effective Low‐Cost Method to Attain a High Areal Lithium Storage Capacity in a CNT@Co3O4 Sponge.
- Author
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Chen, Yijun, Wang, Yunsong, Wang, Zhipeng, Zou, Mingchu, Zhang, Hui, Zhao, Wenqi, Yousaf, Muhammad, Yang, Liusi, Cao, Anyuan, and Han, Ray P. S.
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CARBON nanotubes , *ELECTRODES , *GRAPHITE , *ANODES , *POROUS materials , *CURRENT density (Electromagnetism) - Abstract
Abstract: Achieving a high areal capacity is essential for the transfer of outstanding laboratory electrode results to commercial applications and also to ensure there exists a capacity matched cathode and anode for a properly tuned battery. Despite intensive efforts, most electrode materials exhibit areal capacities lower than that of the graphite anodes (4 mA h cm−2). An effective and low‐cost approach is reported to attain a high areal capacity via an intense densification by compacting a porous carbon nanotube sponge grafted with Co3O4 nanoparticles. The hybrid sponge can be compacted to a large degree (up to a tenfold densification) while still keeping its structural integrity and the 3D porous network. This method allows achieving a mass loading of up ‑to 14.3 mg cm−2 and an areal capacity of 12 mA h cm−2 (at a current density of 200 mA g−1) together with a gravimetric capacity of >800 mA h g−1. This densification by compaction approach offers an effective and low‐cost strategy to develop high mass loading and areal capacity electrodes for practical energy storage systems. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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