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Abstract: Two novel two-dimensional spindle-type fluorinated chromophores with fluorinated phenyl as side groups connecting to the π conjugated bridge were prepared for second-order nonlinear optical applications. The detailed synthetic procedure was reported. Thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) revealed that the spindle-type fluorinated chromophores have excellent thermal stability. Host–guest doped materials had been used to prepare the second-order nonlinear optical films. The nonlinear electro-optic (EO) coefficient of the poled films was measured by Teng–Man technique at the fundamental wavelength of 1310nm, and the r 33 up to 28pm/V was achieved. [Copyright &y& Elsevier]

In this paper, a new type of single-mode embedded dye-doped electro-optic (EO) polymeric waveguide switch based on cross-linkable negative photoresist was successfully designed and fabricated using direct photodefinition technique. The optical properties of the UV cross-linkable poled polymer were characterized. By optimizing the poling temperature and the dopant levels of Disperse Red 1, the DR1/SU-8 material showed excellent photostability and exhibited an EO coefficient, \gamma33, of 25 pm/V. The characteristic parameters of both the waveguide and the electrode were carefully designed and simulated by MATLAB program. The Mach–Zehnder interferometer switch on-off time obtained was about 6 \mus. The new fabrication technique is a simple, rapid, and controllable process. The easy-to-fabricate waveguide structure is suitable for planar active lightwave circuit applications. The dye-doped polymer photosensitive waveguide devices will be very useful in realizing EO modulators and switches. [ABSTRACT FROM AUTHOR]

Abstract: In this paper, functionalized alkoxysilane dye (ICTES-STC) was formed by the reaction of two-dimensional spindle-type chromophores (STC) with 3-isocyanatopropyltriethoxysilane (ICTES). The transparent films having silica network matrix and covalently bonded chromophores were fabricated via the sol–gel process. From TGA thermogram, the initial decomposition temperature of the hybrid film was determined to be 269°C. The electro-optic (EO) coefficient (r33) of the poled films was measured to be around 12pm/V by Teng–Man technique. The thermal stability of the NLO coefficient of the film was investigated by the depoling experiment and temporal decay test, and the result showed that the hybrid film had a good thermal stability, implying its potential applications for EO devices. [Copyright &y& Elsevier]