1. The Role of Cobalt Ferrites Nanoparticles on Structural and Electrochemical Properties of Mesoporous Silica for Supercapacitor Applications.
- Author
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Salama, Reda. S., Alshammari, Riyadh H., Nafady, Ayman, Soomro, Razium Ali, Gouda, Mostafa S., and Awad, Fathi S.
- Subjects
MESOPOROUS silica ,COMPOSITE materials ,ELECTROLYTE solutions ,ENERGY density ,ENERGY storage ,SUPERCAPACITOR electrodes - Abstract
The research focuses on enhancing the energy storage capabilities of mesoporous silica (MCM-41) for supercapacitor applications. Electrodes made solely from MCM-41 do not possess the desired energy density required for electronic devices. To address this, combining ferrites with MCM-41 has been proposed as a means to enhance the electrochemical behavior. In this study, various contents of COF were loaded on MCM-41. Different characterization methods were used to study the physical and surface properties of the as synthesized materials like XRD, FTIR, SEM, TEM, EDX and SEM-mapping. TEM images confirmed that all the as-synthesized composites retained the mesoporous structure, and the particle size of ferrites ranged from 8 to 14 nm. The cyclic voltammetry (CV) and galvanostatic charge–discharge (GCD) techniques were employed to investigate the electrochemical characteristics of the composite materials in H
2 SO4 electrolyte solution (1.0 M) and a potential window ranging from 0.0 to 0.8 V. The results demonstrated that the incorporation of ferrites onto MCM-41 led to an elevation in specific capacitance, with the highest value (746 F.g−1 ) observed at 35 COF-MCM-41 composite. However, further increasing the content of ferrites resulted in a decrease in specific capacitance. Furthermore, the prepared composites exhibited excellent cycling stability even after 5000 cycles, with MCM-41, COF, and 35 COF-MCM-41 retaining 84.4%, 89.4%, and 94.8% of their initial specific capacitance, respectively. These findings highlight the significant role played by the dispersion of cobalt ferrite nanoparticles in enhancing pseudocapacitance behavior, thus improving the overall electrochemical performance of the composites. [ABSTRACT FROM AUTHOR]- Published
- 2024
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