1. Nickel/Cobalt Molybdate Hollow Rods Induced by Structure and Defect Engineering as Exceptional Electrode Materials for Hybrid Supercapacitor.
- Author
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Chu, Dawei, Zhao, Xun, Xiao, Boxin, Libanori, Alberto, Zhou, Yihao, Tan, Lichao, Ma, Huiyuan, Pang, Haijun, Wang, Xinming, Jiang, Yanxia, and Chen, Jun
- Subjects
SUPERCAPACITOR electrodes ,STRUCTURAL engineering ,NICKEL ,COBALT ,ENERGY density ,ENERGY storage - Abstract
Oxygen defects and hollow structures positively impact pseudocapacitive properties of diffusion/surface‐controlled processes, a component of critical importance when building high‐performance supercapacitors. Hence, we fabricated hollow nickel/cobalt molybdate rods with O‐defects (D−H−NiMoO4@CoMoO4) through a soft‐template and partial reduction method, enhancing D−H−NiMoO4@CoMoO4's electrochemical performance, yielding a specific capacitance of 1329 F g−1, and demonstrating excellent durability with 95.8 % capacity retention after 3000 cycles. D−H−NiMoO4@CoMoO4 was used as the positive electrode to construct an asymmetric supercapacitor, displaying an energy density of up to 34.13 Wh kg−1 and demonstrating good predisposition towards practical applications. This work presents an effective approach to fabricate and use hollow nickel/cobalt molybdate rods with O‐defects as pseudocapacitor material for high‐performance capacitive energy storage devices. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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