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Hydrogen is a clean potential alternative fuel for internal combustion engines and completely eliminates the carbon based engine emissions (CO, CO 2 and unburned hydrocarbons). Homogenous charge compression ignition (HCCI) is a low temperature combustion mode with higher thermal efficiency and ultralow NO x emission. Hydrogen HCCI engine can combine potential benefit of fuel and combustion characteristics. In HCCI engine, combustion is governed by the chemical kinetics of the oxidation reactions. In-order to find a suitable reaction mechanism to numerically predict the combustion characteristics of hydrogen HCCI engine, 15 recent hydrogen combustion mechanisms are compared and analyzed. All mechanisms were simulated using a stochastic reactor model (SRM) to evaluate the combustion parameters for HCCI engine. Simulations were performed by varying inlet temperature (400–440 K), intake pressure (1.0–3.0 bar), engine speed (1000–3000 rpm) and relative air-fuel ratio (λ = 2 to 8) for all the mechanisms. Ignition delay predicted from different mechanism was compared with experimental data and ignition delay was also compared at engine like condition using all the test mechanisms. Error in prediction of different combustion parameters such as start of combustion (CA 10 ), maximum cylinder pressure (P max ) and maximum heat release rate (HRR max ) were evaluated using different hydrogen combustion mechanisms. It was found that a recently developed hydrogen mechanism (Maurya-2017) shows the closet resemblance with the experimental cylinder pressure data. The Oconaire-2004 mechanism was able to accurately predict the characteristics of hydrogen HCCI combustion. It was also found that NUIG-NGM-2010 and CRECK-2014 mechanisms were able to estimate the HCCI combustion characteristics under higher combustion temperature. [ABSTRACT FROM AUTHOR]

Hydrogen is a potential alternative and renewable fuel for homogenous charge compression ignition (HCCI) engine to achieve higher efficiency and zero emissions of CO, unburned hydrocarbons as well as other greenhouse gases such as CO 2 and CH 4 . In this study, a detailed hydrogen oxidation mechanism with NO x was developed by incorporating additional species and NO x reactions to the existing hydrogen combustion mechanism (10 species and 40 reactions). The detailed hydrogen combustion mechanism used in this study consists of 39 species and 311 reactions. A reduced mechanism consisting 30 species and 253 reactions was also developed by using directed relation graph (DRG) method from detailed mechanism. Developed mechanisms were validated with experimental data by HCCI engine simulation using stochastic reactor model. Sensitivity analysis was performed to identify the most important reactions in hydrogen combustion and NO x formation in HCCI engine. Pathway analysis was also performed to analyze the important reaction pathways at different temperatures. Results revealed that H2 + HO2 [=] H + H2O2 and O2 + NNH [=] N2 + HO2 are the most significant reactions in the hydrogen HCCI combustion and NO x formation respectively. Detailed parametric study of HCCI combustion was conducted using developed chemical kinetic model. Numerical simulations are performed at different engine operating condition by varying engine speed (1000–3000 rpm), intake air temperature (380–460 K), and compression ratio (16–18) at different relative air fuel ratios (λ). The HCCI operating range was determined for different compression ratios and results show that operating range expands with increase in compression ratio. The effect of intake temperature, engine speed and equivalence ratio on cylinder pressure and heat release rate were investigated. Maximum thermal efficiency of 46% and maximum combustion efficiency of 98% was observed among all the test conditions. Parametric study of NO x emissions was also conducted and it was found that NO x emissions decrease exponentially from higher to lower engine loads. [ABSTRACT FROM AUTHOR]

Ethanol is considered a potential biofuel for internal combustion engines. In this study, homogeneous charge compression ignition (HCCI) simulations of ethanol engine experiments were performed using stochastic reactor model (SRM). Detailed ethanol oxidation mechanism is developed by including NO x reaction in existing detailed oxidation mechanism with 57 species and 383 reactions. Detailed ethanol mechanism with NO x used in this study contains 76 species and 495 reactions. This mechanism was reduced by direct relation graph (DRG) method, which was validated with the experimental results. Existing Lu’s 40-species skeletal mechanism with NO formation were also compared with detailed and reduced mechanisms for predicting maximum cylinder pressure, maximum heat release rate and crank angle position of maximum cylinder pressure in HCCI engine. Reduced mechanism developed in this study exhibited the best resemblance with the experimental data. This reduced mechanism was also validated by measured engine cylinder pressure curves and measured ignition delays in constant volume reactors. The results showed that reduced mechanism is capable of predicting HCCI engine performance parameters with sufficient accuracy. Sensitivity analysis was conducted to determine the influential reactions in ethanol oxidation. Results also show that detailed and reduced mechanism was able to predict NO x emission in good agreement with the corresponding experimental data. [ABSTRACT FROM AUTHOR]