1. Solidification Pattern of Si-Alloyed, Inoculated Ductile Cast Irons, Evaluated by Thermal Analysis
- Author
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Stelian Stan, Iulian Riposan, Iuliana Stan, and Denisa Anca
- Subjects
Materials science ,Silicon ,Base (chemistry) ,silicon alloying ,chemistry.chemical_element ,02 engineering and technology ,engineering.material ,01 natural sciences ,end of solidification ,0103 physical sciences ,metastable system ,inoculation ,General Materials Science ,Supercooling ,Thermal analysis ,Cooling curve ,Eutectic system ,010302 applied physics ,chemistry.chemical_classification ,Mining engineering. Metallurgy ,ductile cast iron ,Inoculation ,Metallurgy ,TN1-997 ,Metals and Alloys ,021001 nanoscience & nanotechnology ,chemistry ,eutectic reaction ,engineering ,Cast iron ,solidification ,0210 nano-technology ,stable system ,cooling curve analysis ,eutectic undercooling - Abstract
The solidification cooling curve itself as well as its first derivative, and related temperatures, reported to the calculated equilibrium temperatures in stable and metastable solidification systems, are used to predict the solidification characteristics of the cast iron. Silicon, as the most representative cast iron element, and inoculation, as graphitizing metallurgical treatment, have a major influence on the transition from the liquid to the solid state. Six experimental programs are performed, with Si content typically for non-alloyed (<, 3.0% Si), low (3.0–3.5% Si) and medium alloyed (4.5–5.5% Si) ductile cast irons, as Si-content increasing, and inoculation simultaneous effects. Silicon is an important influencing factor, but the base and minor elements also affect the equilibrium eutectic temperatures, much more in the Fe-C-Si-Xi stable system (15–20 °C) than in the metastable system (5–10 °C), comparing with their calculation based only on a Si effect (Fe-C-Si system). The highest positive effect of inoculation is visible in non-Si alloyed cast irons (2.5% Si): 9–15 °C for the eutectic reaction and 3 to 4 times increased at the end of solidification (37–47 °C). Increased Si content decreases inoculation power to 7–9 °C for low alloying grade (up to 3.5% Si), with the lowest contribution at more than 4.5% Si (0.3–2.0 °C). 2.5–3.5% Si ductile cast irons are more sensitive to high solidification undercooling, especially at the end of solidification (but with a higher efficiency of inoculation), compared to 4.5–5.5% Si ductile cast irons, at a lower undercooling level, and at lower inoculation contribution, as well.
- Published
- 2021
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