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The characteristic distribution patterns of hydrocarbons have been used for fingerprinting to identify their sources. The historical air depositions of hydrocarbons recorded in natural media help to understand the evolution of the air environment. Travertine is a natural acceptor of air deposition that settles on the ground layer by layer. To reconstruct the historical air environment of hydrocarbons in the North Tibetan Plateau (NTP), a unique background region, twenty-seven travertine samples were collected systematically from a travertine column according to its precipitated year. For each sample, the precipitated year was dated while n-alkanes and polycyclic aromatic hydrocarbons (PAHs) were determined. Based on source identification, the air environment of hydrocarbons in the past century was studied for the region of NTP. Before World War II, the anthropogenic sources of hydrocarbons showed little influence on the air environment. During World War II and China's War of Liberation, hydrocarbons increased significantly, mainly from the use of fossil fuels. Between 1954 and 1963, hydrocarbons in the air decreased significantly because the sources of petroleum combustion decreased. From the mid-1960s through the end of the 1990s, air hydrocarbons, which mainly originated from biomass burning, increased gradually because agriculture and animal husbandry were developing steadily in Tibet and China. From the late 1990s, hydrocarbons in the atmosphere increased rapidly due to the rapid increase of tourism activities, which might increase hydrocarbon emissions from traffic. The reconstruction of the historical air hydrocarbons in NTP clearly reflects the evolution of the region and global development.

Forty-four soil samples were collected across the central Tibetan Plateau (CTP) at altitudes between 3711 m and 5352 m, and their polycyclic aromatic hydrocarbons (PAHs) contents were measured to be from 0.43 to 26.66 ng/g. The main sources of PAHs were identified for each of four sub-areas, and their concentrations in soils were determined to be mainly influenced by local sources. Along a 600 km sampling trajectory from Lhasa, which served as the biggest local source, the concentrations of PAHs decreased logarithmically with increasing distances from the source. Meanwhile, the fractional proportions of PAHs were observed to change logarithmically according to the transport distances. Conclusively, PAHs from local sources were transported within the CTP and dominated PAHs concentrations in the soils, but few of them were transported outside the CTP. In global cycling, the soils in the CTP mainly serve as background and a “sink” for PAHs.

Forty-two congeners of polybrominated diphenyl ethers (PBDEs) were detected for each of 27 surface-soil samples collected at an area near the Changwengluozha Glacier in the Central Tibetan Plateau (CTP), a remote background area at altitude from 5080 to 5217 m. The total concentrations of BDEs in soils ranged from 15.3 to 248.0 ng/kg, which were found to be positively correlated with the clay contents in the soil. In addition to adsorption, the clay was found to serve as a catalyst for the debromination of PBDEs in soils. Three pieces of evidence confirmed that the clay was significantly correlated with the debrominating transformation from the higher brominated congeners to the less brominated congeners. The transforming rate was found to be increased 3.5% with a 10% increase in clays. Debromination is an important way for highly brominated congeners to transform into lighter brominated congeners that are more toxic. This study first provided the direct field evidences for clays contributing to the debromination of PBDEs, and elucidated the importance of it in PBDEs' environmental fate.