Black carbon (BC) is an important pollutant for both air quality and earth's radiation balance because of its strong absorption enhancement. The enhanced light absorption of BC caused by other pollutants is one of the most important sources of uncertainty in global radiative forcing. The light absorption of BC is highly dependent on the emission source and very few studies have been carried out for the source apportionment of BC absorption enhancement. Thus, with this objective, continuous measurements of particulate matter (PM2.5) were performed at three different sites: a traffic site in Nanjing, an urban site in Jinan, and a rural site in Yucheng; the BC absorption enhancement and its source contributions were determined. The mass absorption cross-section (MAC) of BC aerosols was reduced after the removal of the coating material. The maximum MAC enhancement (EMAC) was found to be 2.25 ± 0.5 at the rural site, followed by 2.07 ± 0.7 at the urban site and 1.7 ± 0.6 at the traffic site, suggesting an approximately double enhancement in BC absorption due to different coating materials. The source apportionment of absorption enhancement of BC analysis using the positive matrix factorization model suggests five major emission sources. Among them, secondary sources were the main source of EMAC at all the three sites with a percentage contribution of 43.4% (rural site), 34.6% (traffic site), and 31% (urban site). However, other emission sources, such as biomass burning (21.1% at rural site) and vehicular emissions (33.8% at traffic site) also had a significant contribution to EMAC, suggesting that there could be large variations in BC absorption enhancement due to differences in emission sources together with aerosol aging processes.