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Alcohol fuels, primarily ethanol and methanol, have emerged as one of the important alternatives for sustainable transportation and power generation applications, due to the overall lower carbon dioxide (CO2) emissions. The higher octane number of alcohol makes it suitable for spark ignition (SI) engines while lower blend ratios can be used for compression ignition (CI) engines as well. Since significant work and exploration have already been performed for the application of alcohol in SI engines, the present study is primarily focused on alcohol utilization in CI engines. This review majorly consists of three parts: first, a discussion on the physical and chemical properties of ethanol and methanol from the fuel perspective, second, combustion, and engine performance of CI engines fueled with alcohol and lastly, emissions characterization of alcohol as fuel. A summary of this review is provided which highlights the potential of alcohol utilization in the form of blend or under dual-fuel combustion modes, as well as neat alcohol fueled CI engine. Alcohol-fueled CI engine improves the soot-NOx trade-off characteristic in comparison to conventional diesel combustion, this fuel could be an enabler to meet future emissions regulations. Overall lower CO2 emissions (up to 15% lower compared to diesel) by utilizing alcohol as fuel make it suitable for sustainable transportation. [ABSTRACT FROM AUTHOR]

Ethanol fuelled homogenous charge compression ignition engine offers a better alternative to tackle the problems of achieving higher engine efficiency and lower emissions using renewable fuel. Present study computationally investigates the HCCI operating range of ethanol at different compression ratios by varying inlet air temperature and engine speed using stochastic reactor model. A newly developed reduced ethanol oxidation mechanism with NO x having 47 species and 272 reactions is used for simulation. HCCI operating range for compression ratios 17, 19 and 21 are investigated and found to be increasing with compression ratio. Simulations are conducted for engine speeds ranging from 1000 to 3000 rpm at different intake temperatures (range 365–465 K). Parametric study of combustion and emission characteristics is conducted and engine maps are developed at most efficient inlet temperatures. HCCI operating range is defined using combustion efficiency (>85%) and maximum pressure rise rate (<5 MPa/ms). In HCCI operating range, higher efficiency is found at higher engine loads and lower engine speeds. Emission characteristics of species (NO x , N 2 O, CO, CH 4 , C 2 H 4 , C 2 H 6 , CH 3 CHO, and HCHO) found in significant amount is also analysed for ethanol fulled HCCI engine. Emission maps for different species are presented and discussed for wide range of speed and load conditions. Some of unregulated species such as aldehydes are emitted in significantly higher quantities from ethanol fuelled HCCI engine at higher load and speed conditions. [ABSTRACT FROM AUTHOR]

Ethanol is considered a potential biofuel for internal combustion engines. In this study, homogeneous charge compression ignition (HCCI) simulations of ethanol engine experiments were performed using stochastic reactor model (SRM). Detailed ethanol oxidation mechanism is developed by including NO x reaction in existing detailed oxidation mechanism with 57 species and 383 reactions. Detailed ethanol mechanism with NO x used in this study contains 76 species and 495 reactions. This mechanism was reduced by direct relation graph (DRG) method, which was validated with the experimental results. Existing Lu’s 40-species skeletal mechanism with NO formation were also compared with detailed and reduced mechanisms for predicting maximum cylinder pressure, maximum heat release rate and crank angle position of maximum cylinder pressure in HCCI engine. Reduced mechanism developed in this study exhibited the best resemblance with the experimental data. This reduced mechanism was also validated by measured engine cylinder pressure curves and measured ignition delays in constant volume reactors. The results showed that reduced mechanism is capable of predicting HCCI engine performance parameters with sufficient accuracy. Sensitivity analysis was conducted to determine the influential reactions in ethanol oxidation. Results also show that detailed and reduced mechanism was able to predict NO x emission in good agreement with the corresponding experimental data. [ABSTRACT FROM AUTHOR]

Alcohols (ethanol and methanol) are being widely considered as alternative fuels for automotive applications. At the same time, homogeneous charge compression ignition (HCCI) engine has attracted global attention due to its potential of providing high engine efficiency and ultralow exhaust emissions. Environmental legislation is becoming increasingly stringent, sharply focusing on particulate matter (PM) emissions. Recent emission norms consider limiting PM number concentrations in addition to PM mass. Therefore, present study is conducted to experimentally investigate the effects of engine operating parameters on the PM size-number distribution in a HCCI engine fueled with gasoline, ethanol, and methanol. The experiments were conducted on a modified four-cylinder diesel engine, with one cylinder modified to operate in HCCI mode. Port fuel injection was used for preparing homogeneous charge in the HCCI cylinder. Intake air preheating was used to enable auto-ignition of fuel-air mixture. Engine exhaust particle sizer (EEPS) was used for measuring size-number distribution of soot particles emitted by the HCCI engine cylinder under varying engine operating conditions. Experiments were conducted at 1200 and 2400 rpm by varying intake air temperature and air-fuel ratio for gasoline, ethanol, and methanol. In this paper, the effect of engine operating parameters on PM size-number distribution, count mean diameter (CMD), and total PM numbers is investigated. The experimental data show that the PM number emissions from gasoline, ethanol, and methanol in HCCI cannot be neglected and particle numbers increase for relatively richer mixtures and higher intake air temperatures. [ABSTRACT FROM AUTHOR]

Homogeneous charge compression ignition (HCCI) engines have potential to provide both diesel like efficiencies and very low NOx and particulate matter (PM) emissions. There is growing global interest in using alternative biofuels in order to reduce the reliance on conventional fossil fuels. Therefore this experimental study was carried out to investigate performance, combustion and emission characteristics of HCCI engine fueled with ethanol and methanol and compare it with baseline gasoline fuel. The experiments were conducted on a modified four-cylinder four-stroke engine at different engine speeds using port fuel injection technique for preparing homogeneous charge. To achieve auto-ignition of air-fuel mixture in the combustion chamber, intake air pre-heater was used. In-cylinder pressure data acquisition with subsequent heat release analysis and exhaust emission measurements were done for combustion and emission diagnostics. In this paper, effect of intake air temperature and air-fuel ratio on combustion parameters, thermal efficiency, combustion efficiency, ringing intensity and emissions in HCCI engine is analyzed and discussed. Results show that methanol and ethanol are good replacements to gasoline in HCCI combustion mode. [ABSTRACT FROM AUTHOR]

Highlights: [•] Combustion phasing is analyzed by fitting probability density functions. [•] Combustion stability improves on increasing intake air temperature. [•] Test conditions with late start of combustion have larger cyclic variations. [•] Large deviations from normal distribution in combustion duration for knocking/misfire. [•] GEV distribution covers full range of distribution shapes for combustion duration/phasing. [Copyright &y& Elsevier]

Abstract: The homogeneous charge compression ignition (HCCI) is an alternative combustion concept for in reciprocating engines. The HCCI combustion engine offers significant benefits in terms of its high efficiency and ultra low emissions. In this investigation, port injection technique is used for preparing homogeneous charge. The combustion and emission characteristics of a HCCI engine fuelled with ethanol were investigated on a modified two-cylinder, four-stroke engine. The experiment is conducted with varying intake air temperature (120–150°C) and at different air–fuel ratios, for which stable HCCI combustion is achieved. In-cylinder pressure, heat release analysis and exhaust emission measurements were employed for combustion diagnostics. In this study, effect of intake air temperature on combustion parameters, thermal efficiency, combustion efficiency and emissions in HCCI combustion engine is analyzed and discussed in detail. The experimental results indicate that the air–fuel ratio and intake air temperature have significant effect on the maximum in-cylinder pressure and its position, gas exchange efficiency, thermal efficiency, combustion efficiency, maximum rate of pressure rise and the heat release rate. Results show that for all stable operation points, NO x emissions are lower than 10ppm however HC and CO emissions are higher. [Copyright &y& Elsevier]

Abstract: Combustion in HCCI engines is a controlled auto ignition of well-mixed fuel, air and residual gas. Since onset of HCCI combustion depends on the auto ignition of fuel/air mixture, there is no direct control on the start of combustion process. Therefore, HCCI combustion becomes unstable rather easily, especially at lower and higher engine loads. In this study, cycle-to-cycle variations of a HCCI combustion engine fuelled with ethanol were investigated on a modified two-cylinder engine. Port injection technique is used for preparing homogeneous charge for HCCI combustion. The experiments were conducted at varying intake air temperatures and air–fuel ratios at constant engine speed of 1500rpm and P-θ diagram of 100 consecutive combustion cycles for each test conditions at steady state operation were recorded. Consequently, cycle-to-cycle variations of the main combustion parameters and performance parameters were analyzed. To evaluate the cycle-to-cycle variations of HCCI combustion parameters, coefficient of variation (COV) of every parameter were calculated for every engine operating condition. The critical optimum parameters that can be used to define HCCI operating ranges are ‘maximum rate of pressure rise’ and ‘COV of indicated mean effective pressure (IMEP)’. [ABSTRACT FROM AUTHOR]