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1. High-nuclearity, mixed-valence Mn₁₇, Mn₁₈ and {Mn₆₂}n complexes from the use of triethanolamine.

2. High-nuclearity, mixed-valence Mn17, Mn18and {Mn62}ncomplexes from the use of triethanolamineElectronic supplementary information (ESI) available: Crystallographic data (CIF format) for 1·2CH2Cl2·4Et2O, 2·5MeCN and 3·26MeCN, synthetic details for the 1–3, and various structural and magnetism figures. CCDC 700136–700138. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0cc01701a

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