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Application of energy saving and consumption reduction technologies in the iron and steel industry (ISI) is an effective way to achieve sustainable development. As the highly energy‐consuming ironmaking system is an important part of steel production, reducing its exergy loss is of great significance for overall energy saving in ISI. The optimization model of the ironmaking system is established in this study based on the law of conservation of mass and the second law of thermodynamics. For the target of minimum exergy loss, material and energy systems of ironmaking are optimized and analyzed. Factors that influence the ironmaking system are further discussed. The results show that the minimum exergy loss of the ironmaking system is 4605.80 MJ t‐HM−1 by improving operation conditions. Among them, 51.15% of the total exergy loss is contributed by the blast furnace ironmaking process. [ABSTRACT FROM AUTHOR]

[Display omitted] • Exergy loss of enterprise is optimized by building mathematical programming model. • Influences of 9 key factors on system's total exergy loss and cost are discussed. • Recovery and utilization of waste heat are optimized by detailed technical models. • Waste heat potential and heating capacity of enterprise are evaluated. • Interface loss between upstream & downstream processes is quantified by exergy. A substantial quantity of waste heat resources generated in iron and steel manufacturing process (ISMP) can fulfill certain demand for urban heating. However, the waste heat utilization level of different iron and steel enterprises varies a lot and few studies have combined the upstream enterprise's production with downstream waste heat utilization for discussion. By establishing an optimization model based on material balance, thermodynamic laws and reaction mechanism of the ISMP, this study firstly obtain the minimum exergy loss and the corresponding production cost ＆ exergy efficiency. The total exergy loss of ISMP is reduced from 8413.19 MJ/t-MS to 7669.27 MJ/t-MS. The exergy efficiency of the whole process is increased from 63.75 % to 65.46 % and the total waste heat potential reaches 1471.25 MJ/t-MS. It is found that coke ratio, air leakage rate, scrap steel ratio, etc. have great impact on exergy loss of ISMP. Then, the optimization and evaluation of the waste heat utilization are carried out by establishing models with taking urban heating into consideration. The available external heat supply is 813.15 to 853.55 MJ/t-MS and the enterprise's heating load can reach 229.23–251.47 MW, which allow to supply heat for an area of 5.46–5.93 million m2. Finally, the problem of waste heat instability in the heating process is briefly discussed and some solution strategies are proposed to overcome this defect. [ABSTRACT FROM AUTHOR]

Intensive energy consumption and high pollutant emission have always been the obstacles for achieving the sustainable development of the iron and steel (I&S) industry. The complex material flows, energy flows and emission flow of I&S industry require better assessment to implement comprehensive governance and impact analysis. The 48-month data of a typical I&S enterprise is used for evaluating intensities and analyzing influencing factors from the perspective of material, exergy and emission networks. The results show that the exergy intensity and carbon emission intensity of the whole site including main processes and auxiliary processes are 23.804 GJ/t-CS and 1642.7 kg/t-CS, respectively. In particular, auxiliary process plays a critical role, whose exergy loss accounts for about 28.85% of the total. The terms of energy structure, technology capacity, product structure and environmental conditions are considered to analyze on the influencing factors of the case, and then providing relevant suggestions. On the whole, integration assessment of material-exergy-emission networks of I&S industry is necessary and helpful to find their changes and migration, and to further implement energy management and emission reduction. • Material-exergy-emission network is analyzed for the whole iron & steel enterprise. • The data of main and auxiliary processes with time granularity are analyzed. • The intensities of energy, exergy and emission of various products are presented. • The influencing factors for the material-exergy-emission network are discussed. [ABSTRACT FROM AUTHOR]

The traditional iron and steel industry (ISI) began to implement technological innovations aimed at lowering carbon footprint and emissions, resulting in hydrogen metallurgy gradually becoming a new trend of green development in ISI. However, there is a lack of comprehensive and in-depth analysis of energy-exergy based on the second law of thermodynamics in the current research of hydrogen metallurgy. To address these issues, a numerical calculation model of hydrogen metallurgy based on material-energy-exergy is established. Two novel evaluation indexes are introduced to better evaluate the impact of various parameters on hydrogen metallurgy. It was found that the exergy intensity is mainly affected by the amount of reducing gas, and increasing the preheating temperature of the ore cannot always reduce the exergy intensity due to the influence of element conservation. And when the ore preheating temperature is higher than 623 K, the exergy utilization efficiency decreases. After calculation, the lowest exergy intensity is 1.23 × 107 kJ/t-DRI when the H 2 content is 41.37% and the ore temperature is 773 K. Furthermore, a simple process is designed to recover a substantial volume of unreacted gas from the furnace top gas. Overall, this study can serve as a reference for actual hydrogen metallurgy production. [Display omitted] • A material-energy-exergy model based on the second law of thermodynamics is created. • In addition to the traditional evaluation indexes, two novel ones are also introduced. • Preheating ore temperature above 623 K reduces the exergy utilization efficiency. • Rising ore preheating temperature does not decrease exergy intensity continuously. • A simple waste energy recovery process is proposed. [ABSTRACT FROM AUTHOR]