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In today's electric power network, fast changes are the norm, and auxiliary services such as automatic generation control (AGC) play a crucial role in maintaining the quality of the power supply. AGC ensures a balance between power generation, demand, and losses to sustain frequency stability and variation in tie‐line power within a set limit, even when the load changes. To accomplish this, it is always beneficial to consider new approaches to controlling the situation. This paper introduces the design of new AGC regulators that consider deviation in DC tie‐line power as an extra control variable for the turbine controller. In this study, three different deregulated power systems (containing two control areas), namely three thermal generations, the combination of one thermal and two hydro generations, and three hydro generations, including two power distribution companies (DISCOs) in each control area. These optimal AGC regulators are implemented in the proposed thermal–thermal–thermal system to carry out the various power contracts. The results have shown that the dynamic outcomes meet the AGC standards. To improve further dynamic results and the proposed systems' stability margins by incorporating redox flow batteries (RFB). In actual operating conditions, the system parameters do not remain constant due to the aging effect, assumptions made in simplifying the mathematical model, etc. Thus, ±50% deviations in the nominal value of system parameters to assess how well the optimal AGC regulators perform in the system under investigation. The suggested realistic AGC system incorporates many parameter fluctuations and works well with the optimal AGC regulators developed for the proposed plans. This study expanded to include a two‐area, thermal‐hydro‐hydro (THH) system under a deregulated framework connected via an asynchronous transmission link with or without a thyristor‐controlled phase shifter (TCPS) and RFB. The genetic algorithm (GA) can solve many issues and has global search, flexibility to varied problem types, intrinsic parallelism, and the ability to handle massive, complex search spaces. Thus, a two‐area deregulated hydro‐hydro‐hydro system with parallel tie‐lines utilizes GA‐PID, GA‐FOPID, and GA‐(1 + PI)‐FOPID controllers. Moreover, a random load disturbance (RLD) is employed in each section of the offered approach to show the resilience and elite performance of the proposed control strategy. To produce various dynamic reactions in the plans, MATLAB software version R2013a is employed. [ABSTRACT FROM AUTHOR]

Basic studies on concentrated solutions are becoming more and more important due to the practical industrial and geological applications. The use in redox flow batteries is one of the most important applications of these solutions. Specifically, in this paper we investigated highconcentrated copper chloro-complexes solutions with different additives. The concentration of ligands and additives affects the physicochemical and electrochemical properties of 2 M solutions of Cu(I) and Cu(II). Solutions with calcium chloride and HCl as Cl-source were investigated with Cu:Cl ratios of 1:5 and 1:7, the 1:5 Cu:Cl ratio being the best performing. The substitution of calcium chloride with ammonium chloride increased the conductivity. However, while the effect on the positive electrode process was not very evident, the reversibility of the copper deposition-stripping process was greatly improved. Orthophosphoric acid could be a viable additive to decrease the complexation of calcium with chloride anions and to improve the stability of Cu(II) chlorocomplexes. Absorption spectroscopy demonstrated that phosphate ions do not coordinate copper(II) but lead to a shift in the distribution of copper chloro-complexes toward more coordinated species. Electrochemically, the increased availability of chloride anions in solution stabilized the Cu(II)-rich solution and led to increased reversibility of the Cu(II)/Cu(I) redox process. [ABSTRACT FROM AUTHOR]