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• Polyphase tectonics shapes hydrothermal pathways in fractured Devonian carbonates. • Exhumed analogue of low-enthalpy geothermal reservoir reveals structural complexities. • Hydrothermal carbonate vein analyses unveil long-lived hydrothermal fluid pathways. • Proposal of geothermal exploration targets in strike slip tectonic settings. This study examines the impact of polyphase tectonics on the development of structurally controlled hydrothermal fluid pathways in carbonate geothermal reservoirs. Our case study focuses on hydrothermal carbonate veins and vein-filled faults in Devonian carbonates from the North Rhine-Westphalia region in western Germany, currently being explored as a potential low-enthalpy geothermal reservoir at depths of 4–5 km. These veins, which can be up to 20 m thick, are subvertical and strike NNW, N, or ESE. They exhibit pinch-and-swell undulating geometries, faulted vein-wall contacts, and occasional fillings of hydrothermal breccias. Vein-filled normal faults show hybrid shear-dilatant openings, with fault tips characterized by horsetail vein terminations. The textures, orientations, and age of the veins suggest their formation at low confining pressures and at depths < 2 km during the Post-Variscan East-West extension. Orthogonal North- and East-striking strike slip faults, inherited from the Variscan orogeny, were likely reactivated during post-Variscan extension, with a significant dilatant component that formed the observed veins. In the Ruhr Basin, the dilation tendency analysis indicates that NNW-striking veins or joints are optimally oriented for re-opening under the current strike-slip stress regime, characterized by NNW-trending maximum horizontal stress. The intersections of fractures may currently create moderately SSE-plunging linear zones of enhanced fluid flow. The main uncertainty regards the presence of similar structures at geothermal reservoir depths of ∼4–5 km in the Middle Devonian carbonates underneath the Ruhr Basin. As the study veins are likely to have formed at depths <2 km, the existence of analogous dilatant conduits at greater depths remains speculative. Eventually, we propose that zones characterized by open discontinuities and channelized fluid flow in carbonate geothermal reservoir in strike-slip tectonic settings can be: (a) dilational jogs between overlapping strike-slip faults, (b) bends along faults, and (c) strike-slip fault terminations with horsetail extensional structures. These zones can also be prone to enhanced karstification. [ABSTRACT FROM AUTHOR]

We applied field structural data and isotope geochemical (δ13C, δ18O and 87Sr/86Sr) analyses to understand the relationship among calcite veins, fault damage zones and carbonate host rocks in a thrust fault damage zone in the Achado quarry, Irecê Basin in the São Francisco Craton, NE Brazil. Our results reveal three hydrological packages with different rheological behaviours in a stratified carbonate succession. The upper package includes the Achado fault damage zone that is characterised by interlayered dolomitised grainstones and mudstones. These rocks display high positive δ13C values (10‰–13‰), negative δ18O values (mean −6.34‰) and radiogenic (87Sr/86Sr) isotope values (0.70885–0.71519). A second package is marked by a cataclastic brittle shear zone lateral parallel to dolograinstones bedding. These rocks show low to positive δ13C values (−3.41‰ to +8.85‰), more positive δ18O values (mean −3.73‰) and radiogenic (87Sr/86Sr) isotope values (0.71039–0.71373). The lower package is characterised by well‐preserved pristine limestone succession that shows δ13C values ranging between −0.46‰ and +3.17‰, mean δ18O = −5.41‰ and less radiogenic 87Sr/86Sr values (0.70762–0.70818). In contrast to the upper and intermediate packages, rocks from the lower one exhibit very low permeability and behaved as a seal for fluid migration. Fluid flow occurred several times during basin evolution, for example along syn‐rift fault damage zones, bedding‐parallel carbonate breccia, thrust faults, cataclastic shear zones, synorogenic conjugate shear fractures or joints and opening mode I fracture‐fill calcite veins. These fractures allowed pervasive fluid flow in the porous intermediate cataclastic shear zone where fluids flowed and formed veins, as diffuse fluid flow in randomly oriented fracture swarms, or channelised fluid flow in aligned fracture corridors. They record significant centimetre‐scale to km‐scale hydrological behaviour within carbonate layers. Most carbonates that are associated with veins, fault damage zones and hydraulic breccia were formed by fluids of the same origin with low δ13C (−6.0 to −2.0‰) and δ18O (−6.0 to −8.5‰) values, and more radiogenic 87Sr/86Sr values compared to the carbonate host rocks. [ABSTRACT FROM AUTHOR]

U-Pb dating and geochemical analyzes (δ18O, δ13C, Δ47, 87Sr/86Sr and elemental composition) have been applied to fracture-filling calcite veins and host carbonates from the Bóixols-Sant Corneli anticline, which developed along the front of the Bóixols thrust sheet in the Southern Pyrenees. This robust dataset is used to determine: (i) the absolute timing of fracturing and mineralization from fluid flow; (ii) the age and duration of fold evolution; and (iii) the variations and implications of fluid behavior across the anticline, as has been described in the article “Spatio-temporal variation of fluid flow behavior along a fold: The Bóixols-Sant Corneli anticline (Southern Pyrenees) from U–Pb dating and structural, petrographic, and geochemical constraints – Marine and Petroleum Geology (2022) (Muñoz-López et al., 2022).In this new contribution, we present the raw data that have been analyzed and discussed in the related research article and, also, the whole elemental and REE composition of calcite veins and host carbonates that has not been published yet. These data may be used to unravel the age and origin of veins, to understand their sequential evolution in orogenic belts and to compare our results with those obtained in similar settings worldwide.

Based on the published data of pillow lava-hosted mineralized veins, this study compares post-magmatic fracturing, fluid flow, and secondary mineralization processes in the Troodos and Izu–Bonin supra-subduction zone (SSZ) and discusses the crucial factors for the development of distinct vein types. Thin section and cathodoluminescence petrography, Raman spectroscopy, fluid inclusion microthermometry, and trace element and isotope (87Sr/86Sr, δ18O, δ13C, Δ47) geochemistry indicate that most veins consist of calcite that precipitated from pristine to slightly modified seawater at temperatures < 50 °C. In response to the mode of fracturing, fluid supply, and mineral growth dynamics, calcites developed distinct blocky (precipitation into fluid-filled fractures), syntaxial (crack and sealing), and antitaxial (diffusion-fed displacive growth) vein microtextures with vein type-specific geochemical signatures. Blocky veins predominate in all study areas, whereas syntaxial veins represent subordinate structures. Antitaxial veins occur in all study areas but are particularly abundant in the Izu–Bonin rear arc where the local geological setting was conducive of antitaxial veining. The temporal framework of major calcite veining coincides with the onset of extensional faulting in the respective areas and points to a tectonic control on veining. Thus, major calcite veining in the Troodos SSZ began contemporaneously with volcanic activity and extensional faulting and completed within ~ 10–20 Myr. This enabled deep seawater downflow and hydrothermal fluid upflow. In the Izu–Bonin forearc, reliable ages of vein calcites point to vein formation > 15 Myr after subduction initiation. Therefore, high-T mineralization (calcite, quartz, analcime) up to 230 °C is restricted to the Troodos SSZ. [ABSTRACT FROM AUTHOR]

Vein mineralization observed in boreholes, quarries and outcrops of Upper Permian and Mesozoic sediments in the Thuringian Syncline, Germany, was investigated for the first time by petrography, electron microprobe analysis and stable isotope analysis. The objective was a characterization of paleo-fluid systems within this basin. Veins are mostly restricted to NW-SE trending fault systems and comprise carbonates (calcite, dolomite), minor sulfates (gypsum/anhydrite, celestite, barite), and rarely sulfides. They are variably distributed within the Late Paleozoic to Mesozoic succession. Calcite vein mineralization occurs in almost all Triassic strata, though dominating in the Lower Muschelkalk subgroup (mu). Gypsum/anhydrite veins occur in the Middle Keuper subgroup (km), Middle Muschelkalk subgroup (mm), Middle and Upper Buntsandstein subgroup (sm, so) as well as in the Upper Permian (Zechstein). Sulfate and carbonate isotope analyses indicate that most vein mineralization dominantly crystallized from intraformational fluids within the Upper Permian and Triassic sediments. Crystallization from descending meteoric waters was observed especially for calcite veins in the Lower Muschelkalk, but also for gypsum/anhydrite veins in the Upper Buntsandstein. Mineralization from ascending, carbonate-pH-buffered, warm waters was restricted to individual parts of the southern, deep reaching main border fault zone of the Thuringian Syncline. Mixing and fault crossing fluid movements are subordinate within the Thuringian Syncline. We conclude that no large scale cross-formational fluid flow occurred in Thuringian Syncline over the last millions of years. • No large scale cross-formational fluid flow within Thuringian Syncline • Precipitation first and foremost from intraformational fluids • Close to the surface mineralization subordinately from descending meteoric water • Locally indications for ascending, warmer fluids along the main fault system [ABSTRACT FROM AUTHOR]

Calcite veins in carbonate fracture have been investigated by petrographic, fluid inclusion, geochemical analyses and coupled with basin modeling techniques to provide useful insights into fluid activity and deformation conditions of the Cambrian to Triassic Shizhu synclinorium from the western region of Mid-Yangtze, central China. The results of the fluid inclusion microthermometry show a wide range of homogenization temperatures (78.6-215.5 °C) and salinities (0.18-23.11 wt.% NaCl equivalent), indicating the formation under diverse fluid conditions. All the calcite veins have negative Ce anomalies, which are the typical characteristic of marine carbonate sediments; it is therefore plausible that calcite veins were precipitated from the marine basin fluid. The stable carbon iso-topic compositions of calcites ( δ C=-2.5‰-4.26‰) and host limestones ( δ C=-3.56‰-5.80‰) are very similar with a correlation coefficient of 0.86, however, four calcites from the Lower Permian and Lower Triassic show lower δ C values relative to the host limestones, and they are depleted in total REE concentrations (ΣREE ratio varies from 0.74 to 2.06), suggesting the derivation of dissolved carbon from marine carbonates hosting the calcite veins and, less commonly, from the degradation of organic matter. Calculated δ O of the fluids-precipitating calcites ( δ O=-0.41‰-14.42‰), Sr/Sr ratios varying in the range of coeval seawater and the distinct REE pattern simultaneously suggest calcite-forming fluids in each stratigraphic unit could have formed from the involvement of fluids that originated from coeval seawater and evolved through different degrees of water rock interaction. However, the presence of more radiogenic Sr/Sr ratios than coeval seawater and pronounced positive Eu anomalies in calcites of Lower to Middle Ordovician rocks indicate that terrestrial input from upper strata mudstone and siliciclastic rocks could be involved in the precipitation of the Ordovician calcite. Fluid-inclusion data combined with burial and thermal history modeling indicate there was large-scale flow of evolved basinal fluids through the carbonate formation fractures spanning a time frame from 135 to 50 Ma (Early Cretaceous-Eocene). Therefore, the geochemical characteristics of calcite veins can provide the basis for deformation events in Late Yanshanian and Early Himalayan orogeny. [ABSTRACT FROM AUTHOR]

Calcite veins hosted in the Triassic Stockton, Lockatong and Passaic formations of the Newark Basin are investigated to reconstruct the fluid evolution. To constrain the parameters of calcite precipitation, a microthermometry study was carried, which reveals precipitation of calcite from a low to moderate saline H 2 O-NaCl fluid (0.4 to 13.2 wt% NaCl equiv.) under low to moderate hydrothermal (137 °C to 232 °C) conditions. This fluid composition is interpreted to reflect mixing between a deep basement-derived heated diluted fluid and relatively low to moderate saline diagenetic formation waters hosted in the different Triassic formations. Carbon and strontium isotope analysis on the vein calcites suggests that these elements are derived from the pre-Triassic basement and the sedimentary cover through fluid-rock interactions. The aforementioned geochemical findings are supported by Rare Earth Elements and Yttrium (REY) systematics and oxygen isotope data. The Late Triassic extensional activity and gravity-driven fluid flow mechanism facilitated the infiltration of meteoric waters to deeper lithostratigraphic units (i.e., Precambrian-Paleozoic basement-Triassic Stockton Formation) where they became heated. In response to the extensional tectonics, the deep-seated hydrothermal basement-derived diluted fluids migrated upward along the tectonic-related fractures and the major faults to upper shallow crustal levels. Here, the heated, diluted meteoric waters were mixed with low, moderately saline, and relatively cooler formation waters, leading to calcite precipitation. The pH increase is suggested to be a contributing factor in the precipitation of calcite. [Display omitted] • During Late Triassic extensional activity, the meteoric waters descended to deep parts of the Newark basin. • Cross-basinal migration of these deep-seated hydrothermal fluids was ensured primarily by the topographically-driven flow mechanism • During Early Jurassic, extension tectonics facilitated the upward migration of the deep-seated fluids to shallow crustal levels • Fluid mixing occured between the basement-derived diluted fluids and shallowformational waters, leading to calcite precipitation. [ABSTRACT FROM AUTHOR]

This study integrates field structural data, petrographic and geochemical (δ18O, δ13C, Δ 47 , 87Sr/86Sr, and elemental composition) analyses and U–Pb dating of calcite veins cutting the Bóixols-Sant Corneli anticline (Southern Pyrenees) in order to date and to investigate the spatio-temporal relationships between fluid flow and fold evolution. This E-W trending anticline grew from Late Cretaceous to Paleocene at the front of the Bóixols thrust sheet deforming pre-growth and growth sedimentary sequences. U–Pb dating reveals Late Cretaceous to late Miocene deformation ages, which agree with the age of growth strata deposition and the sequence of deformation interpreted from field and microstructural data. Dates coeval (71.2 ± 6.4 to 56.9 ± 1.4 Ma) and postdating (55.5 ± 1.2 to 27.4 ± 0.9 Ma) Upper Cretaceous to Paleocene growth strata are interpreted to record: (i) the growth of the Bóixols-Sant Corneli anticline during the Bóixols thrust emplacement, and (ii) the tightening of the anticline during the southern tectonic transport of the South-Central Pyrenean Unit. Other ages (20.8 ± 1.2 to 9.0 ± 4.6 Ma) postdate the folding event and have been associated with the collapse of the Bóixols-Sant Corneli anticline. The geochemistry of calcite veins indicates that the fluid flow behavior varied across the Bóixols-Sant Corneli anticline through its growth, showing a compartmentalized fluid system. In the hinge of the anticline and in the upper Santonian to middle Campanian syn-orogenic sequence along the footwall of the Bóixols thrust, the similar petrographic and geochemical features between all calcite cements and host rocks point towards a locally-derived or well-equilibrated fluid system. Contrarily, along large faults such as the Bóixols thrust, and in the anticline limbs, the geochemistry of vein cements indicates a different scenario. Cements in large faults yielded the lightest δ18O values, from −8 to −14 ‰VPDB, and variable enrichment in δ13C, 87Sr/86Sr, elemental composition and δ18O fluid. This is interpreted as the migration of fluids, through fault zones, that evolved from distinct fluid origins. Cements in the fold limbs exhibit δ18O and δ13C between −8 and −6 ‰VPDB and between −10 and + 2 ‰VPDB, respectively, the lowest Sr contents and the lowest precipitation temperatures, suggesting that the anticline limbs recorded the infiltration and evolution of meteoric waters. The paleohydrological system in the Bóixols-Sant Corneli anticline was restricted to the Bóixols thrust sheet. The Upper Triassic evaporitic basal detachment likely acted as a lower fluid barrier, preventing the input of fluids from deeper parts of the Pyrenean crustal thrust system. This study provides a well-constrained absolute timing of fracturing and fluid flow during basin inversion and folding evolution and highlights the suitability of U–Pb geochronology to refine the age of fractures and veins and their sequential evolution in orogenic belts. • Twenty-three new U-Pb dates provide a well-constrained timing of deformation in an anticline that preserves pre-, syn- and post-folding fractures that do not exhibit a symmetrical orientation with respect to the fold axis, which have important implications for the interpretation of fold-fracture systems. • We further constrain the age and duration of fold evolution in the Bóixols-Sant Corneli anticline. • The geochemistry of calcite veins reveals that the fluid flow behavior varied across the different structural positions of the Bóixols-Sant Corneli anticline, evidencing a compartmentalized fluid system. • The paleohydrological system in the Bóixols-Sant Corneli anticline only involves fluids sourced above the detachment levels, which may act as a lower boundary for the fluid system, preventing the input of fluids from deeper parts of the belt. [ABSTRACT FROM AUTHOR]

Abstract: During compressive events, deformation in sedimentary basins is mainly accommodated by thrust faulting and related fold growth. Thrust faults are generally rooted in the basement and may act as conduits or barriers for crustal fluid flow. Most of recent studies suggest that fluid flow through such discontinuities is not apparent and depends on the structural levels of the thrust within the fold-and-thrust belt. In order to constrain the paleofluid flow through the Jaca thrust-sheet-top basin (Paleogene southwest-Pyrenean fold-and-thrust belt) this study compares on different thrust faults located at different structural levels. The microstructures in the different fault zones studied are similar and consist of pervasive cleavage, calcite shear veins (SV1), extension veins (EV1) and late dilatation veins (EV3). In order to constrain the nature and the source of fluids involved in fluid-rock interactions within fault zones, a geochemical approach, based on oxygen and carbon stable isotope and trace element compositions of calcite from different vein generations and host rocks was adopted. The results suggest a high complexity in the paleohydrological behaviors of thrust faults providing evidence for a fluid-flow compartmentalization within the basin. Previous studies in the southern part of the Axial Zone (North of the Jaca basin) indicates a circulation of deep metamorphic water, probably derived from the Paleozoic basement, along fault zones related to the major basement Gavarnie thrust. In contrast, in northern part of the Jaca basin, the Monte Perdido thrust fault is affected by a closed hydrological fluid system involving formation water during its activity. The Jaca and Cotiella thrust faults, in turn, both located more to the south in the basin, are characterized by a composite fluid flow system. Indeed, stable isotope and trace element compositions of the first generations of calcite veins suggest a relatively closed paleohydrological system, whereas the late calcite vein generations, which are probably associated with the late tectonic activity of the basin, support a contribution of both meteoric and marine waters. Based on these results, a schematic fluid-flow model is presented. This model allows visualization of three main fluid flow compartments along a N–S transect. [Copyright &y& Elsevier]

• Frontal thrusts act as a conduit for infiltration of meteoric-derived fluids. • Calcite precipitation occurred at temperatures between 10° and 54 °C. • Layer-parallel shortening and shear occurred during folding. • Pressure-solution, frictional sliding, and veining occurred during thrusting. • Slow deformation along thrust is consistent with aseismic growth of Jura anticline. Structural mapping and microstructural analyses are combined with stable, clumped, and radiogenic isotopes to unravel deformation mechanisms and syntectonic fluid flow during upward propagation along the frontal thrust (Fuans thrust) of the internal part of the Jura fold-and-thrust belt. The Fuans thrust cuts through Upper Jurassic-Lower Cretaceous carbonate deposits, branches into two splays, and generates a system of fault-propagation folds. Folding was accomodated by layer-parallel shortening and layer-parallel shear, which generated flexural slip along bedding surfaces, stylolites, and foliated fabric in marly limestone interbeds. Thrusting was characterized by cycles of mutually overprinting pressure-solution and brittle processes, such as frictional sliding and fracturing/veining. This generated foliated tectonites in marls and limestones without significant cataclasis of the host rock. Pressure-solution and micrometer slip along slickenfibers are evidence of aseismic slip, in agreement with the ongoing aseismic growth of anticlines in the Jura fold-and-thrust, while crackle-like vein texture may account for episodic seismic fracturing. Geochemical data show that Fuans thrust acted as a conduit for the downward infiltration of meteoric-derived fluids, which channeled along foliated tectonites during syntectonic fluid flow. Calcite mineralizations precipitated at temperatures between 54 °C and 10 °C, showing an increased contribution of organic carbon from soils in colder paleofluids. This indicates a progressive opening of the system, characterized by a more efficient and extensive meteoric fluids circulation. Considering the highest recorded temperature of 54 °C and assuming the modern geothermal gradient of 30 °C/km, thrusting in the study outcrop initiated at a burial depth of at least ∼1.4 km. [ABSTRACT FROM AUTHOR]