1. Spin State Disproportionation in Insulating Ferromagnetic LaCoO3 Epitaxial Thin Films
- Author
-
Chen, Shanquan, Chang, Jhong-Yi, Zhang, Qinghua, Li, Qiuyue, Lin, Ting, Meng, Fanqi, Huang, Haoliang, Zeng, Shengwei, Yin, Xinmao, Duong, My Ngoc, Lu, Yalin, Chen, Lang, Guo, Er-Jia, Chen, Hanghui, Chang, Chun-Fu, Kuo, Chang-Yang, and Chen, Zuhuang
- Subjects
Condensed Matter - Materials Science ,Materials Science (cond-mat.mtrl-sci) ,FOS: Physical sciences - Abstract
The origin of insulating ferromagnetism in epitaxial LaCoO3 films under tensile strain remains elusive despite extensive research efforts have been devoted. Surprisingly, the spin state of its Co ions, the main parameter of its ferromagnetism, is still to be determined. Here, we have systematically investigated the spin state in epitaxial LaCoO3 thin films to clarify the mechanism of strain induced ferromagnetism using element-specific x-ray absorption spectroscopy and dichroism. Combining with the configuration interaction cluster calculations, we unambiguously demonstrate that Co3+ in LaCoO3 films under compressive strain (on LaAlO3 substrate) are practically a low spin state, whereas Co3+ in LaCoO3 films under tensile strain (on SrTiO3 substrate) have mixed high spin and low spin states with a ratio close to 1:3. From the identification of this spin state ratio, we infer that the dark strips observed by high-resolution scanning transmission electron microscopy indicate the position of Co3+ high spin state, i.e., an observation of a spin state disproportionation in tensile-strained LaCoO3 films. This consequently explains the nature of ferromagnetism in LaCoO3 films.
- Published
- 2023