1. Flexible Perfluoropolyethers-Functionalized CNTs-Based UHMWPE Composites: A Study on Hydrogen Evolution, Conductivity and Thermal Stability.
- Author
-
Sansotera, Maurizio, Marona, Valeria, Marziani, Piergiorgio, Dintcheva, Nadka Tzankova, Morici, Elisabetta, Arrigo, Rossella, Bussetti, Gianlorenzo, Navarrini, Walter, and Magagnin, Luca
- Subjects
- *
THERMAL conductivity , *MULTIWALLED carbon nanotubes , *THERMAL stability , *ATOMIC force microscopy , *CARBON nanotubes , *CARBON composites , *FUEL cells , *HYDROGEN evolution reactions - Abstract
Flexible conductive composites based on ultra-high molecular weight polyethylene (UHMWPE) filled with multi-walled carbon nanotubes (CNTs) modified by perfluoropolyethers (PFPEs) were produced. The bonding of PFPE chains, added in 1:1 and 2:1 weight ratios, on CNTs influences the dispersion of nanotubes in the UHMWPE matrix due to the non-polar nature of the polymer, facilitating the formation of nanofillers-rich conductive pathways and improving composites' electrical conductivity (two to five orders of magnitude more) in comparison to UHMWPE-based nanocomposites obtained with pristine CNTs. Electrochemical atomic force microscopy (EC-AFM) was used to evaluate the morphological changes during cyclic voltammetry (CV). The decrease of the overpotential for hydrogen oxidation peaks in samples containing PFPE-functionalized CNTs and hydrogen production (approximately โ1.0 V vs. SHE) suggests that these samples could find application in fuel cell technology as well as in hydrogen storage devices. Carbon black-containing composites were prepared for comparative study with CNTs containing nanocomposites. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF