28 results on '"Raghu Sivaramakrishnan"'
Search Results
2. Effects of non-thermal termolecular reactions on wedge-induced oblique detonation waves
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Swapnil Desai, Yujie Tao, Raghu Sivaramakrishnan, and Jacqueline H. Chen
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Fuel Technology ,General Chemical Engineering ,General Physics and Astronomy ,Energy Engineering and Power Technology ,General Chemistry - Published
- 2023
3. Ring opening in cycloheptane and dissociation of 1-heptene at high temperatures
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C. Franklin Goldsmith, Travis Sikes, Raymond L. Speth, Kirsten Bell Burdett, Robert S. Tranter, and Raghu Sivaramakrishnan
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Materials science ,Cyclohexane ,Diradical ,Mechanical Engineering ,General Chemical Engineering ,Radical ,Heptene ,Dissociation (chemistry) ,chemistry.chemical_compound ,chemistry ,Physical chemistry ,Physical and Theoretical Chemistry ,Cyclopentane ,Cycloheptane ,Bond cleavage - Abstract
Cycloalkanes and alkenes are important components of real fuels but there is little kinetic and mechanistic data on the dissociation of most large cyclic and olefinic molecules at elevated temperatures. We present here the first experimental and theoretical investigation of dissociation of cycloheptane and the initial product from ring opening, 1-heptene. Experiments were performed in a diaphragmless shock tube using laser schlieren densitometry. Pyrolysis of cycloheptane (0.5–4% in Kr) was studied over 1450–2000 K and 30–120 Torr. Experiments with 1-heptene (1–4% in Kr) covered 1200–1650 K and 30–120 Torr. A newly developed chemical kinetic mechanism for pyrolysis of cycloheptane and 1-heptene is presented herein. Simulations are in very good agreement with the experimental measurements. Rate coefficients for the initial ring-opening process in cycloheptane, k1, and dissociation of 1-heptene, k2, were determined from the experiments. Both k1 and k2 are in falloff, and the pressure and temperature dependencies were well reproduced by theoretical calculations allowing extrapolation to conditions beyond the scope of this work. These calculations yielded the following expressions for k1 and k2 with the uncertainties estimated as ±40% and ±50% respectively: k 1 , ∞ = 5.94 × 10 17 exp ( − 44 , 521 T ) s − 1 and k 2 , ∞ = 8.86 × 10 16 exp ( − 35 , 887 T ) s − 1 . The results of this study indicate that cycloheptane dissociates similarly to cyclopentane and cyclohexane, i.e. ring-opening via C C scission to a diradical that rapidly isomerizes to a conjugate 1-alkene. The secondary chemistry is dominated by the dissociation products of the 1-alkenes i.e. allyl and n-alkyl radicals. Furthermore, rates of dissociation of the cycloalkanes are size dependent and kcyclopentane
- Published
- 2021
4. Termolecular chemistry facilitated by radical-radical recombinations and its impact on flame speed predictions
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Stephen J. Klippenstein, Ahren W. Jasper, Raghu Sivaramakrishnan, Yujie Tao, and Yuri Georgievskii
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Arrhenius equation ,Exothermic reaction ,Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Radical ,Thermodynamics ,Combustion ,Kinetic energy ,Flame speed ,Reaction rate ,symbols.namesake ,Master equation ,symbols ,Physical and Theoretical Chemistry - Abstract
Recent theoretical studies have shown that termolecular chemistry can be facilitated through reactions of flame radicals (H, O, and OH) or O2 with highly-energized collision complexes (either radical or stable species) formed in exothermic reactions. In this work, radical-radical recombination reaction induced termolecular chemistry and its impact on combustion modeling was studied. Two recombination reactions, H + CH3 + M → CH4 + M and H + OH + M → H2O + M, were analyzed using ab-initio master equation analyses guided by quasiclassical trajectory results. The dynamics results and the master equation calculations indicate that CH4⁎ and H2O⁎ (formed in the two radical-radical reactions outlined above) react rapidly with flame radicals and O2 at rates that are competitive with collisional cooling. The addition of these processes into conventional combustion modeling requires two modifications: the inclusion of the new nonthermal termolecular reaction rates and the simultaneous reduction of the competing recombination reaction rates. The former is described with newly derived Arrhenius expressions based on quasiclassical trajectories, and the latter is achieved by perturbing the recombination reaction rate during the simulation. Kinetic modeling was used to gauge the impact of including this nonthermal chemistry for H2/CH4-air laminar flames speeds. Inclusion of this nonthermal chemistry has a noticeable impact on simulated flame speeds. The procedure developed here can be utilized to properly quantify the effects of such nonthermal reactions in macroscopic kinetic models.
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- 2021
5. The role of energy transfer and competing bimolecular reactions in characterizing the unimolecular dissociations of allylic radicals
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Jaeyoung Cho, Ahren W. Jasper, Yuri Georgievskii, Stephen J. Klippenstein, and Raghu Sivaramakrishnan
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Fuel Technology ,General Chemical Engineering ,General Physics and Astronomy ,Energy Engineering and Power Technology ,General Chemistry - Published
- 2022
6. Effects of non-thermal termolecular reactions on detonation development in hydrogen (H2)/methane (CH4) - air mixtures
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Swapnil Desai, Yujie Tao, Raghu Sivaramakrishnan, Yunchao Wu, Tianfeng Lu, and Jacqueline H. Chen
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Fuel Technology ,General Chemical Engineering ,General Physics and Astronomy ,Energy Engineering and Power Technology ,General Chemistry - Published
- 2022
7. HȮ2 + HȮ2: High level theory and the role of singlet channels
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Stephen J. Klippenstein, Raghu Sivaramakrishnan, Ultan Burke, Kieran P. Somers, Henry J. Curran, Liming Cai, Heinz Pitsch, Matteo Pelucchi, Tiziano Faravelli, and Peter Glarborg
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Fuel Technology ,General Chemical Engineering ,General Physics and Astronomy ,Energy Engineering and Power Technology ,General Chemistry - Published
- 2022
8. A chemical pathway perspective on the kinetics of low-temperature ignition of propane
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Shirong Bai, Raghu Sivaramakrishnan, Rex T. Skodje, and Michael J. Davis
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010304 chemical physics ,Chemistry ,General Chemical Engineering ,Kinetics ,General Physics and Astronomy ,Energy Engineering and Power Technology ,02 engineering and technology ,General Chemistry ,Kinetic energy ,01 natural sciences ,law.invention ,Catalysis ,Ignition system ,Chemical kinetics ,chemistry.chemical_compound ,Fuel Technology ,020401 chemical engineering ,law ,Propane ,Computational chemistry ,Scientific method ,0103 physical sciences ,0204 chemical engineering - Abstract
The chemistry of low-temperature ignition in propane/air mixtures is analyzed using a recently developed pathway representation of the chemical kinetics. The “Sum Over Histories Representation” allows time-dependent kinetic observables to be computed using an expansion over global chemical pathways that follow chemical moieties as they move through a complex reaction network. This methodology assigns probabilities to complete chemical pathways through which specific intermediate or product species are generated. The growth of the radical pool during the ignition process is analyzed by enumerating chemical pathways that constitute catalytic cycles, in particular the catalyzed production of the highly reactive OH-radical. In addition to the well-known reaction route followed in low-temperature ignition of hydrocarbons which involves the QOOH and keto-hydroperoxide species, we have explicitly identified several other cycles that are responsible for most of the remaining OH-production.
- Published
- 2019
9. Direct measurements of channel specific rate constants in OH + C3H8 illuminates prompt dissociations of propyl radicals
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C. Franklin Goldsmith, S. L. Peukert, Joe V. Michael, and Raghu Sivaramakrishnan
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Reaction rate constant ,Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Atmospheric chemistry ,Radical ,Analytical chemistry ,Physical and Theoretical Chemistry ,Absorption (chemistry) ,Atmospheric temperature range ,Combustion ,Mass spectrometry ,Fluorescence - Abstract
OH + molecules are an important class of reactions in combustion and atmospheric chemistry. Consequently, numerous studies have measured rate constants for these processes over an extended temperature range. A large majority of these experimental studies have utilized the decay of [OH] profiles (monitored either by absorption or laser-induced fluorescence) to obtain total rate constants. However, there are limited direct measurements of channel specific rate constants in this important class of reactions, particularly at combustion relevant temperatures. In the present experiments, we have directly measured site-specific rate constants for abstraction of the secondary C H bond in OH + C3H8 at high temperatures. Atomic resonance absorption spectrometry (ARAS) was used to monitor the formation of H-atoms from shock-heated mixtures of tert-butylhydroperoxide and C3H8 at high temperatures. Simulations for the experimental H-atom profiles are sensitive only to abstraction of the secondary C H bond leading to unambiguous measurements of the rate constants for this reaction. Over the T-range, 921 K k = ( 3.935 ± 1.387 ) × 10 − 11 exp ( − 1681 ± 362 K / T ) c m 3 molecul e − 1 s − 1 Simulations of the lower temperature data (T
- Published
- 2019
10. Corrigendum to 'A Chemical Pathway Perspective on the Kinetics of Low-Temperature Ignition of Propane' [Combust. Flame 202 (2019) 154-178]
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Rex T. Skodje, Michael Davis, Shirong Bai, and Raghu Sivaramakrishnan
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Materials science ,General Chemical Engineering ,Perspective (graphical) ,Kinetics ,General Physics and Astronomy ,Energy Engineering and Power Technology ,Thermodynamics ,General Chemistry ,law.invention ,Ignition system ,chemistry.chemical_compound ,Fuel Technology ,chemistry ,Propane ,law - Published
- 2021
11. Ramifications of including non-equilibrium effects for HCO in flame chemistry
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Nicole J. Labbe, Stephen J. Klippenstein, Yuri Georgievskii, Raghu Sivaramakrishnan, James A. Miller, and C. Franklin Goldsmith
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chemistry.chemical_classification ,Laminar flame speed ,Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Radical ,Inorganic chemistry ,Kinetics ,Thermodynamics ,Laminar flow ,Combustion ,Chemical kinetics ,Hydrocarbon ,Elementary reaction ,Physical and Theoretical Chemistry - Abstract
The formation and destruction pathways of the formyl radical (HCO) occupy a pivotal role in the conversion of fuel molecules (and their intermediates) to eventual products CO and CO2, and therefore, HCO has been a prescient indicator for heat release in combustion. In this work, we have characterized the impact of including non-equilibrium effects for HCO, i.e. “prompt” dissociation of HCO to H + CO, in simulations of laminar flame speeds for archetypal hydrocarbon and oxygenated molecules relevant to combustion. Prompt dissociation probabilities for HCO were systematically applied to all elementary reactions that included this radical (as either a product or reactant) in literature combustion kinetics models. Simulations with the prompt HCO dissociation corrected models predicted a 7–13% increase in laminar flame speeds at 1 atm for the fuels characterized here (CH4, n-C7H16, CH3OH, CH3OCH3) relative to the predictions using the original models. It is evident that simulations of other fuel-air flames at 1 atm will be similarly impacted, suggesting the indispensability of incorporating these non-equilibrium effects for predictive flame modeling. Simulations of higher pressure (10 atm) heptane-air flames predicted a more modest effect ( O2 Ar mixtures were also impacted to a noticeable extent. Lastly, it is also worth noting that prompt dissociations are a ubiquitous feature of all weakly-bound radicals; the kinetics of many of which (C2H3, C2H5, CH3O, CH2OH, etc.) are central to our current understanding of combustion chemistry. Theory/modeling studies are in progress to address the relevance of prompt dissociations in these weakly-bound radicals to combustion modeling.
- Published
- 2017
12. Reference natural gas flames at nominally autoignitive engine-relevant conditions
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Raghu Sivaramakrishnan, Alex Krisman, James A. Miller, Jacqueline H. Chen, Christine Mounaïm-Rousselle, Laboratoire pluridisciplinaire de recherche en ingénierie des systèmes, mécanique et énergétique (PRISME), Université d'Orléans (UO)-Institut National des Sciences Appliquées - Centre Val de Loire (INSA CVL), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA), and Rousselle, Christine
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Laminar flame speed ,Hydrogen ,Explosive material ,020209 energy ,General Chemical Engineering ,Thermodynamics ,chemistry.chemical_element ,02 engineering and technology ,7. Clean energy ,01 natural sciences ,010305 fluids & plasmas ,law.invention ,law ,0103 physical sciences ,0202 electrical engineering, electronic engineering, information engineering ,Physical and Theoretical Chemistry ,Engine knocking ,ComputingMilieux_MISCELLANEOUS ,Turbulence ,Mechanical Engineering ,[SPI.FLUID]Engineering Sciences [physics]/Reactive fluid environment ,Laminar flow ,Autoignition temperature ,[SPI.FLUID] Engineering Sciences [physics]/Reactive fluid environment ,Ignition system ,chemistry ,13. Climate action - Abstract
Laminar natural gas flames are investigated at engine-relevant thermochemical conditions where the ignition delay time τ is short due to very high ambient temperatures and pressures. At these conditions, it is not possible to measure or calculate well-defined values for the laminar flame speed sl, laminar flame thickness δl, and laminar flame time scale τ l = δ l / s l due to the explosive thermochemical state. Here, the corresponding reference values, sR, δR, and τ R = δ R / s R , that account for the effects of autoignition, are numerically estimated to investigate the enhancement of flame propagation, and the competition with autoignition that arises under nominally autoignitive conditions (characterised here by the number τ/τR). Large values of τ/τR indicate that autoignition is unimportant, values near or below unity indicate that flame propagation is not possible, and intermediate values indicate that a combination of both flame propagation and autoignition may be important, depending upon factors such as device geometry, turbulence, stratification, et cetera. The reference quantities are presented for a wide range of temperatures, equivalence ratios, pressures, and hydrogen concentrations, which includes conditions relevant to stationary gas turbine reheat burners and boosted spark ignition engines. It is demonstrated that the transition from flame propagation to autoignition is only dependent on residence time, when the results are non-dimensionalised by the reference values. The temporal evolution of the reference values are also reported for a modelled boosted SI engine. It is shown that the nominally autoignitive conditions enhance flame propagation, which may be an ameliorating factor for the onset of engine knock. The calculations are performed using a recently-developed, detailed 177 species mechanism for C0–C3 chemistry that is derived from theoretical chemistry and is suitable for a wide range of thermochemical conditions as it is not tuned or optimised for a particular operating condition.
- Published
- 2018
13. Combustion chemistry in the twenty-first century: Developing theory-informed chemical kinetics models
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Ahren W. Jasper, Raghu Sivaramakrishnan, Nils Hansen, Michael P. Burke, Yujie Tao, C. Franklin Goldsmith, Nicole J. Labbe, James A. Miller, Judit Zádor, and Peter Glarborg
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Non-adiabatic chemistry ,Management science ,Computer science ,020209 energy ,General Chemical Engineering ,Twenty-First Century ,Transport ,Energy Engineering and Power Technology ,Theoretical kinetics ,02 engineering and technology ,Combustion chemistry ,021001 nanoscience & nanotechnology ,Hot radicals ,Fuel Technology ,Theoretical methods ,0202 electrical engineering, electronic engineering, information engineering ,Master equation ,0210 nano-technology - Abstract
Over the last 20 to 25 years theoretical chemistry (particularly theoretical chemical kinetics) has played an increasingly important role in developing chemical kinetics models for combustion. Theoretical methods of obtaining rate parameters are now competitive in accuracy with experiment, particularly for small molecules. Moreover, theoretical methods can deal with conditions that experiments frequently cannot. In addition to increased accuracy, theory has rejuvenated methods and discovered phenomena that were completely unappreciated, or at least underappreciated, in the 20th century. Our primary interest here is in molecular-level issues, i.e. in calculating rate and transport parameters. However, dealing with kinetics models that involve thousands of reactions and hundreds of species is important for practical applications and is relatively new to the 21st century. Theory, in a general sense, and theoretical methods development have a role to play here too. We discuss in this review all these topics in some detail with an emphasis on issues and methods that have emerged in the last 20 years or so. Even so, our review is selective, rather than comprehensive, out of necessity.
- Published
- 2021
14. High temperature rate constants for H/D+n-C4H10 and i-C4H10
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S. L. Peukert, Joe V. Michael, and Raghu Sivaramakrishnan
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Arrhenius equation ,Chemistry ,General Chemical Engineering ,Mechanical Engineering ,Kinetics ,Ab initio ,Electronic structure ,Transition state theory ,symbols.namesake ,Reaction rate constant ,Kinetic isotope effect ,symbols ,Chemical Engineering(all) ,Molecule ,Physical chemistry ,Physical and Theoretical Chemistry - Abstract
The reactions of D/H with n-C 4 H 10 and i-C 4 H 10 have been studied with both shock-tube experiments and ab initio transition state theoretical calculations. D-atom profiles were measured behind reflected shock waves using D-atom atomic resonance absorption spectrometry (ARAS) in mixtures with C 2 D 5 I (D-atom precursor, 200 ppm), over the T-range 1063–1327 K, at pressures ≅0.5 atm. D-atom depletion in the present experiments is sensitive only to the reactions, D + n - C 4 H 10 → products ( A ) D + i - C 4 H 10 → products . ( B ) Simulations of the measured D-atom profiles allow for determinations of total rate constants for the processes (A) and (B). The experimental rate constants are well represented by the Arrhenius equations, k A = 2.11 × 10 - 9 exp ( - 5661 K / T ) cm 3 molecules - 1 s - 1 ( 1074 – 1253 K ) k B = 2.57 × 10 - 9 exp ( - 5798 K / T ) cm 3 molecules - 1 s - 1 ( 1063 – 1327 K ) The title reactions have also been characterized using electronic structure theory at the CCSD(T)/cc-pV∞Z//M06-2X/cc-pvtz level of theory. Over the T-range of the present experiments, the ab initio based transition state theory (TST) kinetics predictions for the isotope effects, k D / k H , are near unity. The theoretical predictions are in good agreement with the experimental results and can be represented by the modified Arrhenius equations, k A,THEORY = 6.677 × 10 - 17 T 2.118 exp ( - 2700 K / T ) cm 3 molecules - 1 s - 1 ( 500 – 2000 K ) k B,THEORY = 5.627 × 10 - 20 T 2.934 exp ( - 1225 K / T ) cm 3 molecules - 1 s - 1 ( 500 – 2000 K ) To our knowledge, the present experiments are the first direct measurements for the title reactions and the rate constants from this combined experimental/theoretical effort are recommended for use in combustion modeling. Results from the present studies on n-C 4 H 10 and i-C 4 H 10 along with prior studies on C 2 H 6 and C 3 H 8 suggest the applicability of rate rules for H + Alkanes that are based on generic primary, secondary, and tertiary abstraction sites.
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- 2015
- Full Text
- View/download PDF
15. The role of radical+fuel-radical well-skipping reactions in ethanol and methylformate low-pressure flames
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Stephen J. Klippenstein, Raghu Sivaramakrishnan, and Nicole J. Labbe
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Ethanol ,General Chemical Engineering ,Radical ,Mechanical Engineering ,Ab initio ,Combustion ,Mole fraction ,Medicinal chemistry ,Chemical kinetics ,chemistry.chemical_compound ,Reaction rate constant ,chemistry ,Computational chemistry ,Yield (chemistry) ,Chemical Engineering(all) ,Physical and Theoretical Chemistry - Abstract
Although the reactions of fuel-radicals with other dominant flame radicals such as H and CH 3 are important reactions in low-pressure flames, they have not been well studied. These reactions may occur through either recombination to form stabilized molecular complexes or direct abstractions and chemically activated addition–eliminations to yield bimolecular products. Here, the role of such reactions in low-pressure flames of ethanol and methylformate is studied through a combination of theoretical characterizations of key reactions and detailed kinetic modeling. In particular, H and CH 3 + fuel-radical reactions have been characterized theoretically in this work and these are shown to make a pronounced impact on the formation of intermediates. Theoretical calculations for H + CH 3 CHOH and CH 3 + CH 3 CHOH predict that at low pressures recombinations are minor processes with well-skipping (addition–eliminations) dominating the reaction flux. Direct abstraction was also considered in H + CH 3 CHOH and theory suggests that abstraction at the CH 3 -site forming CH 2 CHOH is the only important channel. Notably, this result is counter to analogy based predictions that CH 3 CHO should be the dominant abstraction product. Low-pressure ethanol flame simulations indicate that addition–elimination reactions from H + CH 3 CHOH and CH 3 + CH 3 CHOH are a major source for C 2 H 4 and C 3 H 6 profiles, respectively. Similar results are observed in simulations of a low-pressure methylformate flame, where addition–elimination reactions of H + CH 2 OCHO and CH 3 + CH 2 OCHO have a significant impact on CH 3 OH and C 2 H 4 mole fraction profiles, respectively. The present results suggest that the well-skipping reactions of relatively stable fuel-radicals with ubiquitous flame radicals such as H, O, OH, and CH 3 should be considered extensively in combustion models.
- Published
- 2015
- Full Text
- View/download PDF
16. High temperature rate constants for H/D + methyl formate and methyl acetate
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Meng-Chih Su, S. L. Peukert, Joe V. Michael, and Raghu Sivaramakrishnan
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Arrhenius equation ,Methyl formate ,Mechanical Engineering ,General Chemical Engineering ,Methyl acetate ,Ab initio ,Analytical chemistry ,Atmospheric temperature range ,chemistry.chemical_compound ,symbols.namesake ,Transition state theory ,Reaction rate constant ,chemistry ,Computational chemistry ,Kinetic isotope effect ,symbols ,Physical and Theoretical Chemistry - Abstract
The reactions of D/H with methyl formate (MF) and methyl acetate (MA) have been studied with both shock-tube experiments and ab initio transition state theoretical calculations. D-atom profiles were measured behind reflected shock waves using D-atom atomic resonance absorption spectrometry (ARAS) over the temperature range 1050–1270 K, at pressures ≅0.5 atm. The title reactions have been theoretically studied at the CCSD(T)/cc-pv∞z//MP2/aug-cc-pvtz and CCSD(T)/cc-pv∞z//B3LYP/6-311++G(d,p) levels of theory. Theoretical calculations suggest the dominance of the abstraction processes in comparison to addition processes in the 300–2000 K T-range. Over the T-range of the present experiments, the theoretically predicted isotope effects, kD/kH, are near unity. D-atom depletion in the present experiments is sensitive only to the reactions, (A) D + CH 3 OC(O)H → products (B) D + CH 3 OC(O)CH 3 → products Simulations of the measured D-atom profiles allow for determinations of total rate constants for the processes (A) , (B) . In combination with results obtained from recent H-ARAS experiments from our laboratory on MF decomposition, total experimental rate constants kA can be described by the Arrhenius equation, k A = ( 4.47 ± 1.54 ) × 10 - 10 exp ( - 5843 ± 416 K / T ) cm 3 molecule - 1 s - 1 ( 1050 – 1270 K ) For H/D + MF, total experimental rate constants, kA, and branching ratios agree well with theoretical predictions. For D/H + MA, total rate constants predicted by theory are in reasonable agreement with the experimental data. The theoretical predictions are preferred for use, with kB represented by the modified Arrhenius equation, k B = 3.078 × 10 - 19 T 2.78 exp ( - 3261 K / T ) cm 3 molecule - 1 s - 1 ( 500 – 2000 K ) To our knowledge, the present experiments are the first direct measurements for the title reactions and the rate constants from this combined experimental/theoretical effort are recommended for use in combustion modeling.
- Published
- 2013
17. Development of a reduced biodiesel surrogate model for compression ignition engine modeling
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Michael J. Davis, Sibendu Som, Raghu Sivaramakrishnan, Tianfeng Lu, Douglas E. Longman, and W. Liu
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Biodiesel ,Heptane ,Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Thermodynamics ,Combustion ,law.invention ,Reaction rate ,Ignition system ,chemistry.chemical_compound ,Surrogate model ,law ,Elementary reaction ,Physical and Theoretical Chemistry ,Oxygenate ,Simulation - Abstract
Methylbutanoate (MB), a C 4 methyl ester, represents the simplest surrogate that captures the chemical effects of the ester moiety in biodiesel and biodiesel surrogates. An updated chemical kinetic model has been developed to characterize the ignition and flame characteristics of MB. The mechanistic elements within this model that relate to the MB and smaller ester/oxygenate sub-mechanisms are drawn from the prototypical Fisher et al. model and from more recent theory and modeling efforts. The MB model development which is based on an iterative procedure involving global sensitivity analyses to identify elementary reactions that govern ignition and subsequent high level ab initio based theoretical updates to these reaction rates are presented. The MB model makes reasonable predictions of ignition delays and laminar flame speeds. The C 5 –C 7 submechanisms from the LLNL n -heptane (NH) model were merged with the present MB model to obtain a detailed chemical kinetics model for a surrogate blend representing biodiesel. The detailed MB-NH model (661 species) was reduced using graph based techniques. The robust reduction techniques employed result in a reduced model (145 species) that is in good agreement with the detailed model over a wide range of conditions. 3-D compression ignition (CI) engine simulations utilizing this reduced chemistry model for MB-NH blends as a surrogate for biodiesel show good agreement with the experimental data suggesting the utility of this model for predictions of combustion and emission characteristics of biodiesel in realistic CI engine simulations.
- Published
- 2013
18. Experiment and theory on methylformate and methylacetate kinetics at high temperatures: Rate constants for H-atom abstraction and thermal decomposition
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Meng-Chih Su, S. L. Peukert, Joe V. Michael, and Raghu Sivaramakrishnan
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Arrhenius equation ,Chemistry ,General Chemical Engineering ,Radical ,Thermal decomposition ,General Physics and Astronomy ,Energy Engineering and Power Technology ,General Chemistry ,Kinetic energy ,Decomposition ,Transition state theory ,symbols.namesake ,Fuel Technology ,Reaction rate constant ,Ab initio quantum chemistry methods ,symbols ,Physical chemistry - Abstract
The shock tube technique was used to study the high temperature thermal decomposition of methylformate (MF) and methylacetate (MA). The formation of H-atoms was measured behind reflected shock waves by using atomic resonance absorption spectrometry (ARAS). The experiments span a T-range of 1194–1371 K at pressures ∼0.5 atm. The H-atom profiles were simulated using a detailed chemical kinetic mechanism for MF and MA thermal decomposition. The simulations were used to derive rate constants for sensitive decomposition and H-abstraction reactions in MF and MA. In methylformate, the most sensitive reactions that determine H-atom profiles are: equation(A) CH3OC(O)H→HCO2+CH3CH3OC(O)H→HCO2+CH3 equation(B) CH3OC(O)H+H→CH3OCO+H2CH3OC(O)H+H→CH3OCO+H2 where H is formed from HCO2 → H + CO2. In methylacetate the most sensitive reactions affecting H-atom formation are: equation(C) CH3OC(O)CH3→CH3+OC(O)CH3CH3OC(O)CH3→CH3+OC(O)CH3 equation(D) CH3OC(O)CH3+H→CH2OC(O)CH3+H2CH3OC(O)CH3+H→CH2OC(O)CH3+H2 Minor sensitivity was observed for the energetically higher lying bond fission, equation(E) CH3OC(O)CH3→CH3+CH3OCOCH3OC(O)CH3→CH3+CH3OCO and H-atom abstraction from MA by CH3 through, equation(F) CH3OC(O)CH3+CH3→CH2OC(O)CH3+CH4CH3OC(O)CH3+CH3→CH2OC(O)CH3+CH4 equation(G) CH3OC(O)CH3+CH3→CH3OC(O)CH2+CH4CH3OC(O)CH3+CH3→CH3OC(O)CH2+CH4 Unlike MF, where H-atoms are formed instantaneously at high-temperatures from (A), in MA, H-atoms form from the CH3 radicals (through CH3 + CH3 → C2H4 + 2H) generated primarily through the C–O bond fission channel (C) with minor contributions from (E). A master equation analysis was performed using CCSD(T)/cc-pv∞z//B3LYP/6-311++G(d,p) energetics and molecular properties for all thermal decomposition processes in MF and MA. The theoretical predictions were found to be in good agreement with the present experimentally derived rate constants for the bond fissions. TST calculations employing CCSD(T)/cc-pv∞z//MP2/aug-cc-pvtz energies and molecular properties for reactions (B) and (D) (the only sensitive abstraction processes in MF and MA) are in good agreement with the experimental rate constants. The theoretically derived rate constants for these processes can be represented by modified Arrhenius expressions for the bond fissions at 0.5 atm over the T-range 1000–2000 K and for the bimolecular abstractions over the 500–2000 K regime. kA(T)=9.79×1068T-15.95exp(-57,434K/T)s-1kB(T)=5.67×10-19T2.50exp(-3188K/T)cm3molecule-1s-1kC(T)=1.42×1084T-19.60exp(-63,608K/T)s-1kD(T)=1.18×10-18T2.58exp(-3714K/T)cm3molecule-1s-1kE(T)=1.90×1082T-19.30exp(-64,724K/T)s-1 Our theoretical predictions for MA + CH3 give over the T-range 500–2000 K, kF(T)=2.12×10-25T3.93exp(-4440K/T)cm3molecule-1s-1kG(T)=3.40×10-25T3.88exp(-4149K/T)cm3molecule-1s-1 To our knowledge this is the first study providing experimentally derived rate constant values for the primary bond fission and abstraction reactions in MF and MA.
- Published
- 2012
19. Roaming radicals in the thermal decomposition of dimethyl ether: Experiment and theory
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Joe V. Michael, Raghu Sivaramakrishnan, Yuri Georgievskii, Lawrence B. Harding, Richard Dawes, Albert F. Wagner, Stephen J. Klippenstein, and Ahren W. Jasper
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Arrhenius equation ,General Chemical Engineering ,Thermal decomposition ,Ab initio ,General Physics and Astronomy ,Energy Engineering and Power Technology ,General Chemistry ,Quantum chemistry ,Dissociation (chemistry) ,chemistry.chemical_compound ,symbols.namesake ,Transition state theory ,Fuel Technology ,chemistry ,symbols ,Physical chemistry ,Dimethyl ether ,Shock tube - Abstract
The thermal dissociation of dimethyl ether has been studied with a combination of reflected shock tube experiments and ab initio dynamics simulations coupled with transition state theory based master equation calculations. The experiments use the extraordinary sensitivity provided by H-atom ARAS detection with an unreversed light source to measure both the total decomposition rate and the branching to radical products versus molecular products, with the molecular products arising predominantly through roaming according to the theoretical analysis. The experimental observations also provide a measure of the rate coefficient for H + CH3OCH3. An evaluation of the available experimental results for H + CH3OCH3 can be expressed by a three parameter Arrhenius expression as
- Published
- 2011
20. Pyrolysis of C6D5CH3: Rate constants and branching ratios in the high-temperature thermal decomposition of toluene
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Joe V. Michael and Raghu Sivaramakrishnan
- Subjects
Arrhenius equation ,Branching fraction ,Mechanical Engineering ,General Chemical Engineering ,Thermal decomposition ,Analytical chemistry ,Branching (polymer chemistry) ,Toluene ,chemistry.chemical_compound ,symbols.namesake ,Reaction rate constant ,chemistry ,Kinetic isotope effect ,symbols ,Physical and Theoretical Chemistry ,Pyrolysis - Abstract
The thermal decomposition of toluene-d5 (C6D5CH3) has been studied at high temperatures with the reflected shock-tube technique using H- and D-atom ARAS. The experiments were performed at high-T (1469–1859 K) at nominal pressures ≈0.25–1.50 atm. The present study utilizing the ultra-sensitive H-atom ARAS technique has provided a direct measurement of the branching ratio in the two-channel high-temperature thermal decomposition of toluene-d5 giving (1) C6D5CH2 + H and (2) C6D5 + CH3. Fall-off is observed in both decomposition channels at high-T (>1700 K), but the lower-T rate constants can be well represented by simple Arrhenius expressions in units of s−1 as, k1=6.91×1013exp(-40180/T)(1469–1714K)k2=5.99×1015exp(-50060/T)(1469–1714K) The experimental results were also used to obtain rate constants for total toluene-d5 decomposition. Arrhenius analysis gives in units of s−1, kTotal=2.21×1014exp(-41760/T)(1469–1714K) The isotope effect is minimal and the present results therefore represent direct measurements of branching ratios and rate constants for toluene decomposition. The branching ratios to benzyl + H vary from ≈0.9 at lower-T ( 1700 K). The excellent agreement between the present experiments and the theoretical predictions by Klippenstein et al. lead us to conclude that the high-T thermal decomposition of toluene is now well-characterized.
- Published
- 2011
21. H- and D-atom formation from the pyrolysis of C6H5CH2Br and C6H5CD2Br: Implications for high-temperature benzyl decomposition
- Author
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Meng-Chih Su, Joe V. Michael, and Raghu Sivaramakrishnan
- Subjects
Arrhenius equation ,Mechanical Engineering ,General Chemical Engineering ,Analytical chemistry ,Decomposition ,symbols.namesake ,chemistry.chemical_compound ,Reaction rate constant ,Acetylene ,chemistry ,Cyclopentadienyl complex ,Atom ,symbols ,Physical and Theoretical Chemistry ,Spectroscopy ,Pyrolysis - Abstract
The thermal decompositions of benzyl (C6H5CH2) and benzyl,α,ά-d2 (C6H5CD2) have been studied at high temperatures with the reflected shock tube technique using H- and D-atom Atomic Resonance Absorption Spectroscopy (ARAS). The experiments were performed at high-T (1437–1801 K) at nominal pressures ≈ 0.3–1.3 atm. The present experiments utilizing the ultra-sensitive H- and D-atom ARAS technique reveal that there are three unique channels that contribute to benzyl decomposition: H-atom removal from the ring, H/D-atom removal from the side-chain, and a non-atom producing process (postulated to be cyclopentadienyl + acetylene). The rate constants for the three channels can be represented in s−1 by, k H,ring = 1.14 × 10 12 exp ( - 32180 K / T ) ( 1475 – 1801 K ) k H / D,side-chain = 4.50 × 10 13 exp ( - 40650 K / T ) ( 1487 – 1789 K ) k non-atom = 1.55 × 109 exp ( - 23470 K / T ) ( 1437 – 1627 K ) The experimental data was also used to obtain rate constants for total benzyl decomposition and an Arrhenius fit gives, k total = 1.05 × 10 12 exp ( - 31450 K / T ) ( 1437 – 1801 K ) The present study gives reliable determinations of rate constants for the three channels that, when coupled with the postulated mechanistic interpretations for these processes, should be useful in future theoretical and experimental characterizations of benzyl decomposition.
- Published
- 2011
22. Shock tube measurements of high temperature rate constants for OH with cycloalkanes and methylcycloalkanes
- Author
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Raghu Sivaramakrishnan and Joe V. Michael
- Subjects
Arrhenius equation ,Order of reaction ,Cyclohexane ,General Chemical Engineering ,General Physics and Astronomy ,Energy Engineering and Power Technology ,Order (ring theory) ,General Chemistry ,Cycloalkane ,chemistry.chemical_compound ,symbols.namesake ,Fuel Technology ,chemistry ,symbols ,Physical chemistry ,Absorption (logic) ,Methylcyclohexane ,Cyclopentane - Abstract
High temperature experiments were performed with the reflected shock tube technique using multi-pass absorption spectrometric detection of OH radicals at 308 nm. The present experiments span a wide T-range, 801-1347 K, and represent the first direct measurements of the title rate constants at T>500 K for cyclopentane and cyclohexane and the only high temperature measurements for the corresponding methyl derivatives. The present work utilized 48 optical passes corresponding to a total path length 4.2 m. As a result of this increased path length, the high [OH] detection sensitivity permitted unambiguous analyses for measuring the title rate constants. The experimental rate constants in units, cm3 molecule-1 s-1, can be expressed in Arrhenius form as k{sub OH+Cyclopentane} = (1.90 {+-} 0.30) x 10{sup -10} exp(-1705 {+-} 156 K/T) (813-1341 K), k{sub OH+Cyclohexane} = (1.86 {+-} 0.24) x 10{sup -10} exp(-1513 {+-} 123 K/T) (801-1347 K), k{sub OH+Methylcyclopentane} = (2.02 {+-} 0.19) x 10{sup -10} exp(-1799 {+-} 96 K/T) (859-1344 K), k{sub OH+Methylcyclohexane} = (2.55 {+-} 0.30) x 10{sup -10} exp(-1824 {+-} 114 K/T) (836-1273 K). These results and lower-T experimental data were used to obtain three parameter evaluations of the experimental rate constants for the title reactions over an even wider T-range.more » These experimental three parameter fits to the rate constants in units, cm{sup 3} molecule{sup -1} s{sup -1}, are k{sub OH+Cyclopentane} = 1.390 x 10{sup -16}T{sup 1.779} exp(97 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (209-1341 K), k{sub OH+Cyclohexane} = 3.169 x 10{sup -16} T{sup 1.679} exp(119 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (225-1347 K), k{sub OH+Methylcyclopentane} = 6.903 x 10{sup -18}T{sup 2.148} exp(536 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (296-1344 K), k{sub OH+Methylcyclohexane} = 2.341 x 10{sup -18}T{sup 2.325} exp(602 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (296-1273 K). High level electronic structure methods were used to characterize the first three reactions in order to provide reliable extrapolations of the rate constants from 250-2000 K. The results of the theoretical predictions for OH + cyclohexane and OH + methylcyclopentane were sufficient to make a theoretical prediction for OH + methylcyclohexane. The present recommended rate expressions for OH with cyclohexane, and methylcyclohexane, give rate constants that are 15-25% higher (over the T-range 800-1300 K) than the rate constants utilized in recent modeling efforts aimed at addressing the oxidation of cyclohexane and methylcyclohexane. The current measurements reduce the uncertainties in rate constants for the primary cycloalkane consumption channel in a high temperature oxidation environment.« less
- Published
- 2009
23. High temperature rate constants for OH+ alkanes
- Author
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Srinivasan Nk, Raghu Sivaramakrishnan, Meng-Chih Su, and Joe V. Michael
- Subjects
Arrhenius equation ,Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Ab initio ,Extrapolation ,Electronic structure ,Transition state ,symbols.namesake ,Transition state theory ,chemistry.chemical_compound ,Reaction rate constant ,Propane ,symbols ,Physical chemistry ,Physical and Theoretical Chemistry - Abstract
Rate constants for H-atom abstractions by OH radicals from a series of alkanes (propane, n-butane, i-butane and neo-pentane) have been measured at high temperatures with the reflected shock tube technique using multi-pass absorption spectrometric detection of OH radicals at 308 nm. The experiments represent the first direct measurements of these rate constants at T > 1000 K and span a wide T-range, 797–1259 K. The present work utilized 80 optical passes corresponding to a total path length of ∼7 m. As a result of this increased path length, the high [OH] detection sensitivity permitted pseudo-first-order analysis for unambiguously measuring the total rate constants. The experimental rate constants can be represented in Arrhenius form as, kC3H8+OH=6.671×10-11exp(-1543K/T)cm3molecule-1s-1(797–1248K)kn-C4H10+OH=9.674×10-11exp(-1569K/T)cm3molecule-1s-1(800–1236K)ki-C4H10+OH=9.114×10-11exp(-1654K/T)cm3molecule-1s-1(846–1221K)kneo-C5H12+OH=1.060×10-10exp(-1947K/T)cm3molecule-1s-1(841–1259K) The present results have been combined with prior lower-T measurements to generate three-parameter rate expressions that adequately represent the available direct measurements (within 25%) over a wide temperature regime (250–1250 K). High-level ab-initio electronic structure theory computations of the molecular properties of reactants, products and transition states have been used to estimate theoretical rate constants with conventional transition state theory (CTST). The theoretical rate constants are excellent representations of the available experimental data (deviations less than 25%) and thereby offer a reliable method for extrapolation to higher-T as well as for extracting branching ratios for primary, secondary and tertiary abstractions.
- Published
- 2009
24. The high-pressure pyrolysis of saturated and unsaturated C7 hydrocarbons
- Author
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S. Garner, Raghu Sivaramakrishnan, and Kenneth Brezinsky
- Subjects
Biodiesel ,Heptane ,Argon ,Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Analytical chemistry ,chemistry.chemical_element ,Shock (mechanics) ,Chemical kinetics ,chemistry.chemical_compound ,Reagent ,Organic chemistry ,Physical and Theoretical Chemistry ,Shock tube ,Pyrolysis - Abstract
Pyrolysis experiments on n -heptane, 1-heptene and 1,6-heptadiene have been performed using the UIC High-Pressure Shock Tube (HPST) at pressures relevant to diesel combustion systems. The experimental pressures for these experiments ranged from 25 to 50 atm and temperatures varied from 1000 to 1350 K with reaction times ranging from 1 to 3 ms. Dilute reagent mixtures ∼100 ppm were prepared in bulk argon and shock heated to study the stable intermediates. The experimental data has been used to develop and validate an updated kinetic model for the pyrolysis of saturated and unsaturated C 7 hydrocarbons. The experimental results and their implication on increased NO emissions from biodiesel blends will also be discussed.
- Published
- 2009
25. Combustion of CO/H2 mixtures at elevated pressures
- Author
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Scott G. Davis, Robert S. Tranter, Hai Wang, Andrea Comandini, Raghu Sivaramakrishnan, and Kenneth Brezinsky
- Subjects
Shock wave ,Chemical kinetics ,Work (thermodynamics) ,Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Radical ,Analytical chemistry ,Physical and Theoretical Chemistry ,Atmospheric temperature range ,Combustion ,Shock tube ,Stoichiometry - Abstract
The high pressure oxidation of dilute CO mixtures doped with 150–200 ppm of H 2 has been studied behind reflected shock waves in the UIC high pressure single pulse shock tube. The experiments were performed over the temperature range from 1000 to 1500 K and pressures spanning 21–500 bars for stoichiometric ( Φ = 1) and fuel lean ( Φ = 0.5) oxidation. Stable species sampled from the shock tube were analyzed by standard GC, GC/MS techniques. The experimental data obtained in this work were simulated using a detailed model for H 2 /CO combustion that was validated against a variety of experimental observables/targets that span a wide range of conditions. These simulations have shown that within experimental error the model is able to capture the experimental trends for the lower pressure data sets (average nominal pressures of 24 and 43 bars). However the model under predicts the CO and O 2 decay and subsequent CO 2 formation for the higher pressure data sets (average nominal pressures of 256 and 450 bars). The current elevated pressure data sets span a previously unmapped regime and have served to probe HO 2 radical reactions which appear to be among the most sensitive reactions in the model under these conditions. With updated rate parameters for a key HO 2 radical reaction OH + HO 2 = H 2 O + O 2 , the model is able to reconcile the elevated pressure data sets thereby extending its capability to an extreme range of conditions.
- Published
- 2007
26. A SHOCK-TUBE STUDY OF THE HIGH-PRESSURE THERMAL DECOMPOSITION OF BENZENE
- Author
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Raghu Sivaramakrishnan, Kenneth Brezinsky, Robert S. Tranter, and H. Vasudevan
- Subjects
Shock wave ,Computer simulation ,General Chemical Engineering ,Thermal decomposition ,General Physics and Astronomy ,Energy Engineering and Power Technology ,Mineralogy ,Thermodynamics ,General Chemistry ,Combustion ,Toluene ,chemistry.chemical_compound ,Fuel Technology ,chemistry ,Benzene ,Shock tube ,Pyrolysis - Abstract
The high-temperature, high-pressure pyrolysis of the prototype aromatic, benzene, has been studied behind reflected shock waves in the UIC High Pressure Single Pulse Shock Tube. Three sets of experiments were performed at nominal pressures of 30 and 50 bars in the high temperature regime from 1200–1800 K. Stable species sampled from the shock tube were analyzed offline using gas chromatographic techniques. The present data set was simulated using the three most recent models, two of the models developed and validated against high-temperature benzene pyrolysis shock-tube data for stable species profiles as well as H atom production rates and the third model, a “work-in-progress” model from our laboratory aimed at resolving the high-pressure combustion of primary aromatics such as benzene and toluene. The simulations reflect the complexities and uncertainties involved not only in describing the primary decay steps but also the subsequent high-temperature secondary chemistry for even the simplest ar...
- Published
- 2006
27. High-pressure, high-temperature oxidation of toluene
- Author
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Raghu Sivaramakrishnan, Kenneth Brezinsky, and Robert S. Tranter
- Subjects
Atmospheric pressure ,General Chemical Engineering ,Analytical chemistry ,General Physics and Astronomy ,Energy Engineering and Power Technology ,General Chemistry ,Combustion ,Toluene ,chemistry.chemical_compound ,Fuel Technology ,chemistry ,Reagent ,Gas chromatography ,Shock tube ,Stoichiometry ,Bar (unit) - Abstract
The high-pressure single pulse shock tube (HPST) at the University of Illinois at Chicago has been used to study the oxidation of toluene at reflected shock pressures from 22 to 550 bar and temperatures from 1210 to 1480 K. Experiments were performed for dilute stoichiometric, Φ = 1 , and rich, Φ = 5 , reagent mixtures. Stable species were analyzed using gas chromatography and gas chromatography/mass spectrometry. The resulting data set is the first that provides species concentrations over such extremes of pressure, temperature, and stoichiometry, and it serves as an excellent base for the validation and refinement of future detailed chemical kinetic models. Two literature models for the oxidation of toluene that have been validated against atmospheric pressure turbulent flow reactor and jet stirred reactor data were used to simulate the experimental data. Several modifications were made to one model to more accurately simulate the high-pressure/high-temperature experimental data. The modified model reproduces the Φ = 1 experimental data well and forms the first step in the development of a more comprehensive model for toluene combustion validated over wide ranges of temperature and pressure.
- Published
- 2004
28. A high pressure model for the oxidation of toluene
- Author
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Robert S. Tranter, Raghu Sivaramakrishnan, and Kenneth Brezinsky
- Subjects
Chemistry ,Mechanical Engineering ,General Chemical Engineering ,Analytical chemistry ,Atmospheric temperature range ,Combustion ,Toluene ,Toluene oxidation ,chemistry.chemical_compound ,Chemical engineering ,High pressure ,Physical and Theoretical Chemistry ,Shock tube ,Pyrolysis ,Stoichiometry - Abstract
A detailed chemical kinetic model has been developed to predict the oxidation of toluene in the high temperature regime (1200–1500 K) over wide pressure ranges (25–610 bar) based on experimental data obtained in the high pressure single pulse shock tube at the University of Illinois at Chicago. The experimental data were obtained at pressures of 25, 50, and 610 bar over the temperature range from 1210 to 1480 K for stoichiometries of Φ = 1 and Φ = 5. The proposed model is derived from an earlier literature model for toluene oxidation that had been validated against experimental data obtained at 1 atm and at lower temperatures ( Φ = 5 (fuel-rich) data set and forms the first step in the development of a more comprehensive model for toluene combustion for fuel-rich oxidation and pyrolysis.
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