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Membrane separation has been an efficient and energy saving technique in dealing with greenhouse gases, but the traditional membrane designs might not be able to handle the concomitant environmental pollution due to their fixed properties. Correspondingly, the use of an active-responsive smart membrane appears to be a new trend for membrane development in the coming future, which shows great potential to deal with the obstacles. In this research, we demonstrate a smart graphene-organic framework membrane to enable reversed electrical-switchable permselectivity in CO2 separation. The addition of polydopamine (PDA) to the polyvinylidene fluoride/Graphene (PVDF/G) membranes was done to (i) induce the β-phase of PVDF, since –NH2-functionalized graphene has specific interactions (dipole induced dipole interaction) between graphene-PDA and PVDF; (ii) modify the organic PVDF-inorganic graphene interface; and (iii) facilitate CO2 selective separation. Permeability and permselectivity was increased after applying voltage that resulted in the increase of gas permselectivity in response to the lowest applied voltage range (0–3 V) to the membrane. Digital image correlation method depicted the response of the membrane to voltage and proved that the membrane has high piezoelectric properties that is switchable. Furthermore, PALS studies confirmed the free volume and interlayers in the membrane. This membrane has unique properties because the pore changes from bimodal to single pore distribution.

The aim of this research is to investigate the effect of annealing treatment on mechanical properties and deformability of titanium alloy to form mini gear in squeezing process. Diameter of experimental specimen was 5mm of Grade 2 Ti alloy. It was annealed with temperature in a range of 500 to 1000 °C, resulting in different initial grain sizes. The mechanical properties and hardness of annealed specimens were obtained by means of tensile and micro-hardness test. In addition, a modulus of mini gear die was 0.92 and made of h13 steel. The annealed specimens were inserted in die and squeezed into mini gear. The experimental results show that microstructure of α-phase precipitates when annealing temperature reaches to 600 °C and hold time was 3 hours. The specimen which annealed with a temperature of 700 °C has the maximal elongation and die filling rate. The microstructural of β-phase precipitates when annealing temperature reaches to 1000 °C resulting in brittle behavior and the lowest die-filling rate.