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Crystalline domains in rhyolitic domes and coulees are commonly characterized by spherulites and lithophysae. Spherulites typically range from microscopic to a few centimeters in diameter. Larger spherulites, termed "megaspherulites," are rare but have been reported in the USA and Mexico. The uncommon nature of such structures supports the need for a study to explore the factors and special conditions that allow them to reach such a large size. In the Southern Puna of Argentina, El Viejo Coulee includes megaspherulites up to 4 m in diameter. We present observations from field work, petrography, scanning electron microscopy, bulk geochemistry, and Fourier transform infrared spectroscopy. The megaspherulites occur in obsidian lenses that differ in phenocryst content and composition from the foliated coherent facies that forms the rest of the coulee. The obsidian lacks vesicles and microlites and is unaltered. The megaspherulites comprise growth cones consisting of micropoikilitic texture where quartz encloses potassium feldspar. The growth cones are separated by interconal areas composed of lithophysae. We propose that the megaspherulites were formed above the glass transition temperature (Tg) and are the product of primary crystallization of rhyolitic melt. The exceptionally large size of the megaspherulites implies high diffusion rates which are favored by temperatures above Tg during crystallization. The large size also suggests scarcity of nucleation sites, which is consistent with the megaspherulites being hosted by unaltered microlite- and vesicle-free glass. The position of the obsidian lens at the base of the coulee may have played a critical role in maintaining the temperature above the Tg long enough to allow the crystallization of the megaspherulites. These conditions also favored crystallization in the most advanced stage where micropoikilitic texture replaced the fans of crystal fibers typical of spherulites. Crystallization of anhydrous quartz and feldspar in the growth cones led to the concentration of volatiles in the melt in the interconal areas, resulting in volatile exsolution and formation of vesicles that became nucleation sites for lithophysae. The study advances our understanding of some of the special processes that are involved in the cooling and solidification of rhyolitic magmas. Fundamentally, we find that the position of the obsidian at the base of the coulee was critically important because this position favored maintenance of the temperature above the Tg which, in turn, favored high diffusion rates. Also, the scarcity of nucleation sites in the obsidian melt allowed only a small number of spherulites to nucleate; those that nucleated therefore grew very large. The meter-scale megaspherulites may have taken ~ 55 years to create. [ABSTRACT FROM AUTHOR]

• An integrated conceptual model of the Tocomar Geothermal system is presented. • Compositional data of thermal fluids along with structural, Raman spectroscopic, and in-situ permeability data from the Tocomar Geothermal area are reported. • Cation geothermometers indicates reservoir temperatures up to 235 °C. • The structural control on flow pathways and fluids-rock interaction processes are discussed. • The geothermal electric potential is stochastically assessed. The Argentinean Andean region hosts a vast geothermal resource clustered by active magmatic and tectonic activity. One of the most studied geothermal areas is the Tuzgle-Tocomar geothermal system in Central Puna (NW Argentina). However, despite the existence of several studies since the 1970′s highlighting the geothermal potential of the area, only highly schematic and dissimilar conceptual models have been proposed for the Tocomar Geothermal System. This study presents new detailed geological-structural and hydrogeochemical data, together with in-situ permeability analysis of fault zones and Raman spectroscopic characterization of hydrothermal-alteration minerals. The electrical generating capacity has also been evaluated using the volumetric method and a stochastic approach. A new comprehensive conceptual model of the studied area was constructed highlighting the role of the Calama-Olacapato-El Toro (COT) fault-system in the circulation of hydrothermal fluids. The reservoir of the Tocomar geothermal system has a Na+-Clˉ(HCO 3)ˉ composition and an estimated temperature of ∼235 °C. Such a reservoir is hosted in fractured Ordovician rocks and controlled by the COT-like Chorrillos transpressive fault at 1000–1500 m depth b.g.l. The water isotopic data and hydrological features indicate a regional recharge beyond the Tocomar sub-basin boundaries (>5000 m a.s.l.). Additionally, the main hydrothermal reservoir receives inputs of magmatic fluids from the degassing of the intra-crustal rhyolitic magma chamber of the Tocomar volcanic center. The Monte Carlo simulations suggest that the Tocomar geothermal system has a probable power production capacity above 1.23 MWe (P90), 6.18 MWe (P50) and 11.67 MWe (P10) at different confidence levels. All calculations were biased towards minimum values, thus a tighter definition of the resource size and fracture porosity would significantly impact on the predictions. Notwithstanding, the strategic position of the Tocomar geothermal field encourages move forward towards more in-depth exploration phases. [ABSTRACT FROM AUTHOR]