Search

This study examines Fe-Mn crusts that form on seamounts along the California continental-margin (CCM), within the United States 200 nautical mile exclusive economic zone. The study area extends from approximately 30° to 38° North latitudes and from 117° to 126° West longitudes. The area of study is a tectonically active northeast Pacific plate boundary region and is also part of the North Pacific Subtropical Gyre with currents dominated by the California Current System. Upwelling of nutrient-rich water results in high primary productivity that produces a pronounced oxygen minimum zone. Hydrogenetic Fe-Mn crusts forming along the CCM show distinct chemical and mineral compositions compared to open-ocean crusts. On average, CCM crusts contain more Fe relative to Mn than open-ocean Pacific crusts. The continental shelf and slope release both Fe and Mn under low-oxygen conditions. Silica is also enriched relative to Al compared to open-ocean crusts. This is due to the North Pacific silica plume and enrichment of Si along the path of deep-water circulation, resulting in Si enrichment in bottom and intermediate waters of the eastern Pacific. The CCM Fe-Mn crusts have a higher percentage of birnessite than open-ocean crusts, reflecting lower dissolved seawater oxygen that results from the intense coastal upwelling and proximity to zones of continental slope pore-water anoxia. Carbonate fluorapatite (CFA) is not present and CCM crusts do not show evidence of phosphatization, even in the older sections. The mineralogy indicates a suboxic environment under which birnessite forms, but in which pH is not high enough to facilitate CFA deposition. Growth rates of CCM crusts generally increase with increasing water depth, likely due to deep-water Fe sources mobilized from reduced shelf and slope sediments. Many elements of economic interest including Mn, Co, Ni, Cu, W, and Te have slightly or significantly lower concentrations in CCM crusts relative to crusts from the Pacific Prime Crust Zone and other open-ocean basins. However, concentrations of total rare earth elements and yttrium average only slightly lower contents and in the future may be a strategic resource for the U.S.

The Taney Seamounts are a NW-SE trending linear, near mid-ocean ridge chain consisting of five volcanoes located on the Pacific plate 300 km west of San Francisco, California. Taney Seamount-A, the largest and oldest in the chain, is defined by four well-exposed calderas, which expose previously infilled lavas. The calderas can be differentiated in time by their cross-cutting relationships, creating a relative chronology. The caldera walls and intracaldera pillow mounds were sampled systematically by a remotely operated vehicle (ROV) to obtain stratigraphically-controlled samples, a unique aspect of this study. The geochemistry of the seamount varies from more differentiated to more primitive with time (6.2–8.6 wt.% MgO), suggesting that the sub-caldera reservoir is open and undergoes periodic collapse, replenishment, crystallization, and eruption. The youngest and least differentiated lavas entrained a crystal cargo of plagioclase (An80–90) with melt inclusion volatile saturation pressures indicating entrapment in the lower oceanic crust and upper mantle (6–12 km, with 45% between 8 and 10 km below the sea floor). Melt inclusions exhibit high Al2O3, low SiO2, positive Sr and Eu anomalies and negative Zr and Nb anomalies when normalized to typical Pacific mid-ocean ridge basalt (MORB). In comparison, the host lavas exhibit positive Sr anomalies, but no concurrent Zr, and Nb anomalies. Based on thermodynamic modeling using alphaMELTS, we develop a melt-rock interaction model defined by melting and assimilation of plagioclase-rich cumulates by hot, primitive mantle-derived melts. Significantly, the variability of the negative Zr and Nb anomalies cannot be explained by either cumulate melting or AFC alone. We propose that the melt inclusions record the interaction between cumulate partial melts and the assimilating melt, demonstrating the importance of cumulate melting during the assimilation process. Later percolating melts underwent diffusive interaction with, and entrained, recrystallized plagioclase cumulates resulting in the positive Sr signal without the concurrent Eu, Zr, or Nb anomalies observed in the host lavas. These results demonstrate that melt-rock interaction at the lower crust or upper mantle is an important process at Taney Seamount-A, and potentially other magmatic systems associated with seamount chains and ridge axes.

The patterns of axial hydrothermal circulation at mid-ocean ridges both affect and are influenced by the styles of magma plumbing. Therefore, the intensity and distribution of hydrothermal alteration in the lower oceanic crust (LOC) can provide constraints on LOC accretion models (e.g., “gabbro glacier” vs. “multiple sills”). Gabbroic xenoliths from Hualalai Volcano, Hawaii include rare fragments of in situ Pacific lower oceanic crust. Oxygen and strontium isotope compositions of 16 LOC-derived Hualalai gabbros are primarily within the range of fresh MORB, indicating minimal hydrothermal alteration of the in situ Pacific LOC, in contrast to pervasive alteration recorded in LOC xenoliths from the Canary Islands. This difference may reflect less hydrothermal alteration of LOC formed at fast ridges than at slow ridges. Mid-ocean ridge magmas from slow ridges also pond on average at greater and more variable depths and undergo less homogenization than those from fast ridges. These features are consistent with LOC accretion resembling the “multiple sills” model at slow ridges. In contrast, shallow magma ponding and limited hydrothermal alteration in LOC at fast ridges are consistent with the presence of a long-lived shallow magma lens, which limits the penetration of hydrothermal circulation into the LOC. Most Hualalai gabbros have geochemical and petrologic characteristics indicating derivation from Hualalai shield-stage and post-shield-stage cumulates. These xenoliths provide information on the evolution of Hawaiian magmas and magma storage systems. MELTS modeling and equilibration temperatures constrain the crystallization pressures of 7 Hualalai shield-stage-related gabbros to be ∼2.5–5 kbar, generally consistent with inferred local LOC depth. Therefore a deep magma reservoir existed within or at the base of the LOC during the shield stage of Hualalai Volcano. Melt–crust interaction between Hawaiian melts and in situ Pacific crust during magma storage partially overprinted clinopyroxene Sr and Nd isotope compositions of LOC-derived gabbros. Although minor assimilation of Pacific crust by Hawaiian melts cannot be excluded, the range of oxygen isotope compositions recorded in Hawaiian lavas and cumulates cannot be generated by assimilation of the in situ LOC gabbros, which have relatively uniform and MORB-like δ18O values. To first order, the isotopic heterogeneity observed in Hawaiian melts appears to derive from the heterogeneous plume source(s), rather than assimilation of local oceanic crust.

A comprehensive understanding of explosive basaltic eruption processes in the deep-sea relies upon detailed analysis and comparison of the variety of volcaniclastic lithologies on the seafloor, which has been challenged by insufficient sample recovery. A dedicated ROV-based sampling approach using long push cores offers an unparalleled opportunity to fully characterize the diversity of unconsolidated volcaniclastic lithofacies on a recently active seamount. Lithofacies from Axial Seamount record two styles of pyroclastic eruptions, strombolian and phreatomagmatic, at 1.5 km water depth. Strombolian eruptions are represented by abundant fluidal and highly vesicular (up to 50%) vitriclasts within limu o Pele lapilli tuff and tuffaceous mud lithofacies. Lapilli-ash grain size, normal grading, good sorting, rip-up clasts and homogeneous glass geochemistry characterize individual limu o Pele lapilli tuff beds, and imply proximal deposition from a turbidity flow associated with a single eruption (i.e. event bed). Limu o Pele lapilli tuff beds are interbedded with poorly sorted, chemically heterogeneous and bioturbated tuffaceous mud units that preserve reworking and biologic habitation of more distal pyroclastic fallout and dilute turbidity flows. The phreatomagmatic eruption style is preserved by hydrothermal mineral-bearing muddy tuff that exhibits characteristics distinct from lapilli ash and tuffaceous mud lithofacies. Hydrothermal muddy tuff lithofacies are well-sorted and fine-grained with notable components of non-fluidal basaltic ash (∼45%), fluidal ash (∼30%) and accessory lithics (∼25%). Heterogeneous geochemistry of ash shards implies that juvenile components are minimal. The abundance, mineralogy and texture of lithic components (Fe–Mg clays, pyrite, epidote, actinolite, altered glass, basalt/diabase, hydrothermal breccia and agglutinate), and very fine-grain size of basaltic ash, are consistent with phreatomagmatic eruption deposits. A lack of bioturbation or other interbedded lithofacies, and presence of normal grading suggests prolonged eruption activity and deposition via turbidity flows or suspension fallout. The proximity of ancient hydrothermal muddy tuff lithofacies and active hydrothermal vents to caldera walls suggest that phreatomagmatic activity was linked to shallow circulation of fluids along caldera ring-faults rooted to underlying magma conduits and shallow reservoirs. This study provides evidence for two distinctly different pyroclastic eruption styles and provides a framework to further develop existing models of deep-sea explosive volcanism.

Seamounts formed adjacent to mid-ocean ridges are the most abundant on Earth, numbering several orders of magnitude higher than hotspot-related seamounts. The Taney Seamounts are a linear NW–SE-trending, near mid-ocean ridge chain consisting of five volcanoes located on the Pacific plate 300 km west of San Francisco, California. Taney Seamount-A, the largest and oldest in the chain, has four well-defined calderas. These calderas have clear cross-cutting relationships, creating a relative chronology. The caldera walls and intracaldera pillow mounds were sampled systematically by a remotely operated vehicle to obtain stratigraphically controlled samples, a unique aspect of this study. Changes in lava geochemistry are consistent with an open-system sub-caldera reservoir that undergoes periodic collapse, replenishment, shallow crystallization, and eruption. Replenishing magmas contain large, anorthite-rich plagioclase crystals that exhibit sieve textures and zoning indicating interaction with percolating melt. The enrichment of elements in the lavas that are incorporated in plagioclase (e.g. aluminum, strontium) provides chemical evidence for the interaction between mantle-derived melts and plagioclase cumulates in the lower oceanic crust or upper mantle (8–12 km), prior to magmas entering the sub-caldera plumbing system. Based on trace element variations, the erupted lavas vary from typical peridotite-derived normal mid-ocean ridge basalt (N-MORB) compositions to those with an apparent residual garnet signature. Geochemical and thermodynamic modeling shows that decompression melting of a MORB mantle peridotite re-fertilized by garnet pyroxenite partial melts can reproduce the garnet signature observed in the Taney-A edifice lavas. Hence the magmatic architecture of Taney Seamount-A is characterized by the melting of a mixed lithology mantle, melt–rock interaction in the upper mantle to lower oceanic crust, and open-system evolution in a sub-caldera magma reservoir.

Highlights • High-resolution AUV bathymetry is used to identify hydrothermal sulfides on the seafloor. • 1.2 Mt of massive sulfide is identified along 24 km of mid-ocean ridge length. • Massive sulfide accumulated at a rate of ∼400 t/yr. • Efficiency of sulfide deposition is ∼5% of total mobilized metals and reduced sulfur. • Current global seafloor sulfide estimates likely underestimate amount present by about a factor of four. Abstract Hydrothermal sulfide deposits that form on the seafloor are often located by the detection of hydrothermal plumes in the water column, followed by exploration with deep-towed cameras, side-scan sonar imaging, and finally by visual surveys using remotely-operated vehicle or occupied submersible. Hydrothermal plume detection, however, is ineffective for finding hydrothermally-inactive sulfide deposits, which may represent a significant amount of the total sulfide accumulation on the seafloor, even in hydrothermally active settings. Here, we present results from recent high-resolution, autonomous underwater vehicle-based mapping of the hydrothermally-active Endeavour Segment of the Juan de Fuca Ridge, in the Northeast Pacific Ocean. Analysis of the ridge bathymetry resulted in the location of 581 individual sulfide deposits along 24 km of ridge length. Hydrothermal deposits were distinguished from volcanic and tectonic features based on the characteristics of their surface morphology, such as shape and slope angles. Volume calculations for each deposit results in a total volume of 372,500 m3 of hydrothermal sulfide–sulfate–silica material, for an equivalent mass of ∼1.2 Mt of hydrothermal material on the seafloor within the ridge's axial valley, assuming a density of 3.1 g/cm3. Much of this total volume is from previously undocumented inactive deposits outside the main active vent fields. Based on minimum ages of sulfide deposition, the deposits accumulated at a maximum rate of ∼400 t/yr, with a depositional efficiency (proportion of hydrothermal material that accumulates on the seafloor to the total amount hydrothermally mobilized and transported to the seafloor) of ∼5%. The calculated sulfide tonnage represents a four-fold increase over previous sulfide estimates for the Endeavour Segment that were based largely on accumulations from within the active fields. These results suggest that recent global seafloor sulfide resource estimates, which were based mostly on the sizes and distribution of hydrothermally-active deposits, may be similarly underestimating the amount of sulfide along the global submarine neovolcanic zones.

[1] A combined study of mapping, observational, age constraint, and geochemical data at the summit of Axial Seamount, Juan de Fuca Ridge, has revealed its recent petrological history. Multiple basalt types erupted at the summit in a time sequence. At least three different magma batches have been present beneath the Axial Summit caldera during the last millennium, each with a range in differentiation. The first, prior to 1100 CE, was compositionally diverse, dominantly aphyric T-MORB. The second, from ∼1220 to 1300 CE, was dominantly plagioclase-phyric, more mafic N-MORB erupted mostly in the central portion of the caldera. Since ∼1400 CE, lavas have been more differentiated, and nearly aphyric T-MORB mostly erupted in the caldera's rift zones. Parental magmas vary subtly due to small coupled differences in the degree of melting and sources, but all share a uniform differentiation trend indicating pooling at similar depths. Thus, melts percolate through melt-rich lenses that remain partially isolated in space and/or time. Centennial magmatic timescales at Axial Seamount are similar to those for fast spreading ridge segments. The fluctuation between aphyric and plagioclase-phyric lava likely reflects different pathways or velocities of melt migration.

[1] Multibeam (1 m resolution) and side scan data collected from an autonomous underwater vehicle, and lava samples, radiocarbon-dated sediment cores, and observations of flow contacts collected by remotely operated vehicle were combined to reconstruct the geologic history and flow emplacement processes on Axial Seamount's summit and upper rift zones. The maps show 52 post-410 CE lava flows and 20 precaldera lava flows as old as 31.2 kyr, the inferred age of the caldera. Clastic deposits 1–2 m thick accumulated on the rims postcaldera. Between 31 ka and 410 CE, there are no known lava flows near the summit. The oldest postcaldera lava (410 CE) is a pillow cone SE of the caldera. Two flows erupted on the W rim between ∼800 and 1000 CE. From 1220 to 1300 CE, generally small eruptions of plagioclase phyric, depleted, mafic lava occurred in the central caldera and on the east rim. Larger post-1400 CE eruptions produced inflated lobate flows of aphyric, less-depleted, and less mafic lava on the upper rift zones and in the N and S caldera. All caldera floor lava flows, and most uppermost rift zone flows, postdate 1220 CE. Activity shifted from the central caldera to the upper S rift outside the caldera, to the N rift and caldera floor, and then to the S caldera and uppermost S rift, where two historical eruptions occurred in 1998 and 2011. The average recurrence interval deduced from the flows erupted over the last 800 years is statistically identical to the 13 year interval between historical eruptions.

[1] Forty-nine hydrothermal sulfide-sulfate rock samples from the Endeavour Segment of the Juan de Fuca Ridge, northeastern Pacific Ocean, were dated by measuring the decay of 226Ra (half-life of 1600 years) in hydrothermal barite to provide a history of hydrothermal venting at the site over the past 6000 years. This dating method is effective for samples ranging in age from ∼200 to 20,000 years old and effectively bridges an age gap between shorter- and longer-lived U-series dating techniques for hydrothermal deposits. Results show that hydrothermal venting at the active High Rise, Sasquatch, and Main Endeavour fields began at least 850, 1450, and 2300 years ago, respectively. Barite ages of other inactive deposits on the axial valley floor are between ∼1200 and ∼2200 years old, indicating past widespread hydrothermal venting outside of the currently active vent fields. Samples from the half-graben on the eastern slope of the axial valley range in age from ∼1700 to ∼2925 years, and a single sample from outside the axial valley, near the westernmost valley fault scarp is ∼5850 ± 205 years old. The spatial relationship between hydrothermal venting and normal faulting suggests a temporal relationship, with progressive younging of sulfide deposits from the edges of the axial valley toward the center of the rift. These relationships are consistent with the inward migration of normal faulting toward the center of the valley over time and a minimum age of onset of hydrothermal activity in this region of 5850 years.

Volcanism at mid-ocean ridges is usually effusive, but some explosive eruptions have been documented. Measurement of the carbon dioxide content of lavas erupted at the Juan de Fuca Ridge, Pacific Ocean, indicate that elevated concentrations of carbon dioxide in the upper oceanic mantle could drive these explosive eruptions.

AMS radiocarbon age dating of planktonic foraminifera in volcaniclastic deposits on Loihi Seamount yields ages ranging from 590 years before present (y BP) at 10 cm depth to 5,880 y BP at 1,007 cm depth in an 11-m-thick section exposed along inward facing, caldera-bounding faults on the eastern side of Loihi’s summit. The accumulation rate of the deposit was about 0.37 cm/y from 5,880 to 3,300 y BP and it consisted of subequal amounts of alkalic and tholeiitic fragments. The rate slowed dramatically at about 3,300 y BP to an average 0.04 cm/y and the particles that have accumulated since consist mostly of alkalic glass fragments. The decrease in accumulation rate could indicate a decrease in volcanic activity at Loihi beginning about 3,300 y BP. This lower level of activity appears to be continuing today.

Age spectra from 40Ar/39Ar incremental heating experiments yield ages of 298 ± 25 ka and 310 ± 31 ka for transitional composition lavas from two cones on submarine Mahukona Volcano, Hawaii. These ages are younger than the inferred end of the tholeiitic shield stage and indicate that the volcano had entered the postshield alkalic stage before going extinct. Previously reported elevated helium isotopic ratios of lavas from one of these cones were incorrectly interpreted to indicate eruption during a preshield alkalic stage. Consequently, high helium isotopic ratios are a poor indicator of eruptive stage, as they occur in preshield, shield, and postshield stage lavas. Loihi Seamount and Kilauea are the only known Hawaiian volcanoes where the volume of preshield alkalic stage lavas can be estimated.

Sampling of volcanic seamounts with dredges and the remotely operated vehicle Tiburon recovered erratic rocks in surprising abundance as far as 500km offshore of the US West coast. The erratics usually have continental lithologies and appear to have been weathered in nearshore environments. They are probably transported by kelp holdfasts, drift logs, and pinnipeds to the seamounts, where they accumulate over time. The erratics are concentrated as lag deposits and kept from becoming buried in sediment by currents that sweep the seamounts. The erratics often have thinner manganese-oxide crusts than rocks of the seamounts because they were delivered to the seafloor more recently and manganese-oxide crusts precipitate over time. The thinner crusts make erratics easier to collect. While most of the erratics clearly did not originate by the volcanic processes that formed the seamounts, careful evaluation of some is necessary to distinguish them as erratics. Failure to recognize the presence of erratics may result in unrealistically complex interpretations of regional geology.

A diverse assemblage of small mafic and ultramafic xenoliths occurs in alkalic lava from Davidson and Pioneer seamounts located at the continental margin of central California. Based on mineral compositions and textures, they form three groups: (1) mantle xenoliths of lherzolite, pyroxenite, and dunite with olivine of4Fo90; (2) ocean crust xenoliths of dunite with olivine 5Fo90, troctolite, pyroxenegabbro, and anorthosite with low-K2O plagioclase; (3) cumulates of seamount magmas of alkalic gabbro with primary amphibole and biotite and anorthosites with high-K2O plagioclase. The alkalic cumulates are genetically related to, but more evolved than, their host lavas and probably crystallized at the margins of magma reservoirs. Modeling and comparison with experimentally derived phases suggest an origin at moderate pressures ( 0 5^0 9 GPa).The high volatile contents of the alkalic host lavas may have pressurized the magma chambers and helped to propel the xenolith-bearing lavas directly from deep storage at the base of the lithosphere to the eruption site on the ocean floor, entraining fragments of the upper mantle and ocean crust cumulates from the underlyingabandoned spreadingcenter.

Lavas and volcaniclastic deposits were observed and collected from 4 submarine cones that are part of the Honolulu Volcanics on Oahu, Hawaii. The locations of these and a few additional, but unsampled, vents demonstrate that nearly all the vents are located on or very close to the shoreline of Oahu, with the most distal vent just 12 km offshore. The clastic samples and outcrops range from coarse breccias to cross-bedded ash deposits and show that explosive volcanism at depths between about 350 and 590 m depth played a part in forming these volcanic cones. The eruptive styles appear to be dominantly effusive to strombolian at greater depths, but apparently include violent phreatomagmatic explosive activity at the shallower sites along the submarine southwest extension of the Koko Rift. The compositions of the recovered samples are broadly similar to the strongly alkalic subaerial Honolulu Volcanics lavas, but the submarine lavas, erupted further from the Koolau caldera, have slightly more radiogenic Sr isotopic ratios, and trace element patterns that are distinct from either the subaerial Honolulu Volcanics or the submarine North Arch lavas. These patterns are characterized by moderate to strong positive Sr and P anomalies, and moderate to strong negative Cs, Rb, U, Th, Zr, and Hf anomalies. Most samples have strong negative K and moderate negative Ti anomalies, as do all subaerial Honolulu Volcanics and North Arch samples, but one group of samples from the Koko Rift lack this chemical signature. The data are consistent with more garnet in the source region for the off-shore samples than for either the on-shore Honolulu Volcanics lavas. New Ar–Ar ages show that eruptions at the submarine vents and Diamond Head occurred between about 0.5 Ma and 0.1 Ma, with the youngest ages from the Koko Rift. These ages are in general agreement with most published ages for the formation and suggest that some much younger ages reported previously from the Koko Rift are probably erroneously young. D 2005 Elsevier B.V. All rights reserved.

Submarine explosive eruptions are generally considered to become less likely with increasing depth due to the increasing hydrostatic pressure of the overlying water column. Volcaniclastic deposits from the North Arch volcanic field, north of Oahu, have textural characteristics of explosive fragmentation yet were erupted in water depths greater than 4,200 m. The most abundant volcaniclastic samples from North Arch are clast-supported with highly vesicular, angular pyroclasts. They are most likely near-vent pyroclastic fall deposits formed in eruption columns of limited height. Interbedded with highly vesicular pillow lava, they form low (50 to 200 m), steep-sided cones around the vents. Less common are stratified samples with graded bedding; one such sample includes a layer of roughly aligned, platy, bubble-wall glass fragments (resembling littoral limu o Pele) that may have been deposited by density currents. In addition to bubble-wall glass shards, numerous glass fragments with spherical, delicate spindle and ribbon shapes, and Pele's hair-like glass strands occur in the finer size fraction ( 0.6 wt%) alkalic basalt, basanite, and nephelinite. Sulfur and chlorine abundances are high, reaching a maximum of 1,800 and 1,300 ppm, respectively. The ubiquitous presence of limu o Pele fragments, regardless of glass composition, suggests that bursts of Strombolian-like activity accompanied most eruptions. Coalescing vesicles observed in larger pyroclasts and some pillow lava suggests accumulation of volatiles. Since the great hydrostatic pressure makes steam expansion impossible, a volatile-rich, supercritical magmatic fluid probably drove the eruptions. If these volatile-rich magmas had erupted in shallow water or subaerially, tall fountains would most likely have resulted. The great hydrostatic pressure (>40 MPa) limited fountain and eruption column heights.

Nous avons trouve des sulfures et des sulfates hydrothermaux dans les echantillons de sediment preleves lors d'une mission d'urgence au guyot Loihi a la suite d'une grande activite sismique (>4000 evenements) a l'ete de 1996. A la suite de plongees du vehicule submersible PISCES V deux mois apres le paroxysme, nous avons decouvert qu'une partie du sommet s'etait effondree pour former un nouveau cratere. L'effondrement soudain du cratere sommital a cause une decharge cataclysmique de fluide hydrothermal, avec un complement de gaz magmatiques et de cristaux de sulfures. Nous signalons la presence de wurtzite, pyrrhotite, et chalcopyrite, indications de la presence d'un fluide a temperature elevee (>250°C), le premier exemple a etre signale pres d'une ile oceanique. La composition des sulfures ressemble a celle des sulfures associees aux panaches noirs des events pres des rides oceaniques. Les echantillons d'accumulations de debris riches en barite, construits apres la decharge initiale du panache hydrothermal, ressemblent aux produits retrouves dans les panaches blancs pres des rides oceaniques. Le rapport δ 3 4 S des sulfures est inferieur a celui des mineraux des gisements de sulfures massifs associes aux basaltes oceaniques, ce qui laisse supposer que le basalte a Loihi a perdu du soufre sous forme de SO 2 magmatique. La dissolution et l'oxydation des sulfures ejectes a temperature elevee, observees au cours des deux annees suivant le cataclysme, nous poussent a croire que ces mineraux sont ephemeres. Des cristaux semblables a des profondeurs plus grandes dans le systeme hydrothermal sont probablement projetes de facon semblable et repetee lors de disruptions du systeme hydrothermal par l'activite volcanique et tectonique.

Hawaiian volcanoes, dominantly shields of tholeiitic basalt, form as the Pacific Plate migrates over a hotspot in the mantle. As these shields migrate away from the hotspot, highly alkalic lavas, forming the rejuvenated stage of volcanism, may erupt after an interval of erosion lasting for 0 25±2 5Myr. Alkalic lavas with geochemical characteristics similar to rejuvenatedstage lavas erupted on the sea floor north of Oahu along the Hawaiian Arch. The variable Tb/Yb, Sr/Ce, K/Ce, Rb/La, Ba/La, Ti/Eu and Zr/Sm ratios in lavas forming the North Arch and the rejuvenated-stage Honolulu Volcanics were controlled during partial melting by residual garnet, clinopyroxene, Fe±Ti oxides and phlogopite. However, the distinctively high Ba/Th and Sr/Nd ratios of lava forming the North Arch and Honolulu Volcanics reflect source characteristics. These characteristics are also associated with shield tholeiitic basalt; hence they arise from the Hawaiian hotspot, which is interpreted to be a mantle plume. Inversion of the batch melting equation using abundances of highly incompatible elements, such as Th and La, requires enriched sources with 10±55% clinopyroxene and 5±25% garnet for North Arch lavas. The Sr/Sr and Nd/Nd ratios in lavas forming the North Arch and Honolulu Volcanics are consistent with mixing between the Hawaiian plume and a depleted component related to midocean ridge basalts. Specifically, the enrichment of incompatible elements coupled with low Sr/Sr and high Nd/Nd relative to bulk Earth ratios is best explained by derivation from depleted lithosphere recently metasomatized by incipient melt (52% melting) from the Hawaiian plume. In this metasomatized source, the incompatible element abundances, as well as Sr and Nd isotopic ratios, are controlled by incipient melts. In contrast, the large range of published Os/Os data (0 134±0 176) reflects heterogeneity caused by various proportions of pyroxenite veins residing in a depleted peridotite matrix.

[1] New 40Ar/39Ar ages of mineral separates and whole rock samples from nine volcanic edifices in the northern Line Islands region, between latitudes 20°N and 6°N, are incompatible with single or multiple hot spot models. Instead, two major episodes of volcanism, each lasting ∼5 Ma and separated by ∼8 Ma, occurred synchronously over long distances, not just along the main chain but also at nonaligned edifices. Volcanism during the older episode (81–86 Ma) extended over a distance of at least 1200 km along the eastern part of the complex seamount chain. Volcanism during the younger episode (68–73 Ma) was concentrated in the western part of the chain and may have extended over a distance of >4000 km. Chemical analyses of 68 samples represent a compositionally diverse suite, including tholeiitic, transitional, and alkalic basalt, strongly alkalic basanite and nephelinite, and alkalic differentiates ranging from hawaiite to trachyte. The most diverse assemblage of rocks was recovered from a cross-trending seamount chain south of Johnston Atoll. Although compositions of rocks from the two volcanic episodes overlap, compositions from the younger episode generally are more alkalic and include a larger proportion of highly differentiated compositions. None of the samples from the older episode, but many from the younger one, contain hydrous mineral phases such as amphibole and biotite. Extensive coeval volcanism along major segments of the chain is compatible with decompressional melting of heterogeneous mantle due to diffuse lithospheric extension along pre-existing zones of weakness. Episodes of volcanism are probably related to broad upwarping of the Superswell region in the eastern South Pacific, where these lavas originated.

The main break-in-slope on the northern submarine flank of Molokai at −1500 to −1250 m is a shoreline feature that has been only modestly modified by the Wailau landslide. Submarine canyons above the break-in-slope, including one meandering stream, were subaerially carved. Where such canyons cross the break-in-slope, plunge pools may form by erosion from bedload sediment carried down the canyons. West Molokai Volcano continued infrequent volcanic activity that formed a series of small coastal sea cliffs, now submerged, as the island subsided. Lavas exposed at the break-in-slope are subaerially erupted and emplaced tholeiitic shield lavas. Submarine rejuvenated-stage volcanic cones formed after the landslide took place and following at least 400–500 m of subsidence after the main break-in-slope had formed. The sea cliff on east Molokai is not the headwall of the landslide, nor did it form entirely by erosion. It may mark the location of a listric fault similar to the Hilina faults on present-day Kilauea Volcano. The Wailau landslide occurred about 1.5 Ma and the Kalaupapa Peninsula most likely formed 330±5 ka. Molokai is presently stable relative to sea level and has subsided no more than 30 m in the last 330 ka. At their peak, West and East Molokai stood 1.6 and 3 km above sea level. High rainfall causes high surface runoff and formation of canyons, and increases groundwater pressure that during dike intrusions may lead to flank failure. Active shield or postshield volcanism (with dikes injected along rift zones) and high rainfall appear to be two components needed to trigger the deep-seated giant Hawaiian landslides.

Davidson, Guide, Pioneer, Gumdrop, and Rodriguez Seamounts, located at the continental margin offshore California between latitudes 37.5°N and 34.0°N, may represent a previously unrecognized type of intraplate oceanic volcanism. Morphologically unlike typical oceanic-island volcanoes or near-ridge seamounts, they are complex, northeast-trending ridges that reflect the ridge-parallel structure of the underlying oceanic crust. 40Ar/39Ar laser fusion ages of mineral separates indicate at least two episodes of volcanism at ca. 16 and ca. 12 Ma, younger by 7–11 m.y. than the underlying ocean crust. Volcanic rocks are predominantly differentiated alkalic basalt, hawaiite, and mugearite. The lack of coherent liquid- lines-of-descent is consistent with small batches of magma forming, fractionally crystallizing, and erupting in isolation from the previous and subsequent batches. The presence of mantle xenoliths suggests that magmas originated in the upper mantle. Xenoliths of alkalic cumulates and xenocrysts of feldspar, amphibole, and titanomagnetite are consistent with fractionation in the upper mantle as well. Sr, Nd, and Pb isotope ratios of some samples are from depleted-mantle sources like those of MORB (mid-oceanic-ridge basalt); others indicate more variably enriched mantle sources. Magmas formed by small- percentage partial melting of variably enriched MORB-source-type mantle, according to the samples' high abundances of incompatible elements such as Nb, Ta, and Th. Coeval middle Miocene basalts in onshore coastal California have a similar isotopic range, but their trace elements show a subduction-related signature. If the coeval volcanic rocks offshore originated in a slab window, as proposed for those onshore, they were not influenced by a slab component. Although a slab-window origin is plausible for the middle Miocene volcanism, later episodes of small, sporadic eruptions on- and offshore probably resulted from decompression melting of mantle rising along existing zones of weakness undergoing extension related to continued movement along transform-fault systems.

Ka‘ena and Wai‘alu Ridges form prominent submarine ridges NW of the island of O‘ahu, Hawai‘i. We evaluate whether or not either one of these ridges represents a submarine extension of Wai‘anae Volcano on O‘ahu using new bottom observations, geophysical surveys, and geochemical data acquired on new samples from the region. Wai‘alu Ridge has the morphology of a submarine rift zone but is too shallow for its distance from the O‘ahu shoreline; Ka‘ena Ridge also is unusually shallow and is surmounted by two topographic shields. Ka‘ena and Wai‘alu Ridges have similar magmatic and volcanic evolutionary histories, beginning ca. 5 Ma with a submarine, shield phase of volcanism that produced high-SiO 2 , low-FeO* tholeiites with higher 208 Pb/ 204 Pb than in the adjacent Wai‘anae Volcano. Late-shield volcanism included transitional and alkalic rock types, with lower SiO 2 and enrichment in incompatible elements, especially P 2 O 5 , Nb, Zr, Ti, and light rare earth elements. The transition from shield to late-shield stage occurred as the edifice was beginning to emerge from the sea. Geological observations and K/Ar ages indicate that Ka‘ena emerged above sea level ca. 3.5 Ma, reaching a maximum height of ∼4000 m above the abyssal ocean floor and 1000 m above sea level. Relatively weak gravity anomalies, topographic lineaments, and the orientation of dike complexes indicate a volcanic structure that is independent of Wai‘anae Volcano. Thus, volcanic structure, geochemistry, and age all indicate a precursor volcano to the island of O‘ahu, which we call Ka‘ena Volcano. After emergence, Ka‘ena Volcano tilted ∼2° to the south. We estimate a total volume of 20–27 × 10 3 km 3 for Ka‘ena Volcano, taking into account overlapping geometry of concurrently active volcanoes. Sample compositions from the Ka‘ena landslide deposit are entirely consistent with derivation from Ka‘ena, whereas most samples from the Wai‘anae slump are likely derived from Wai‘anae Volcano. Uniformly oriented dikes in the Wai‘anae NW rift zone likely reflect buttressing by a preexisting Ka‘ena Volcano. Unusual isotopic compositions of some Wai‘anae samples, including unique hydrous silicic lavas, probably reflect interaction with underlying Ka‘ena crust. A newly recognized lava flow field on the southern flank of Ka‘ena Ridge extends the previously known distribution of secondary volcanism in the Kaua‘i Channel. Putative submarine volcanic activity in the region in 1956 cannot have built a large edifice and is unlikely to have produced pumice that was found on O‘ahu shores. This eruptive activity therefore remains unconfirmed.

An important feature of 2.5 Ga, whereas the Kea-type component reflects younger subduction

New H2O, CO2 and S concentration data for basaltic glasses from ‘hotspot’, with temperature differences of 200°C or more between hotter upwelling plumes and the ambient mantle Loihi seamount, Hawaii, allow us to model degassing, assimilation, adiabat (e.g. White & McKenzie, 1989; Campbell, 1998; and the distribution of major volatiles within and around the Davies, 1998). In contrast, it has long been known that Hawaiian plume. Degassing and assimilation have affected CO2 ocean island basalts (OIB) are enriched in volatiles relative and Cl but not H2O concentrations in most Loihi glasses. Water to depleted mid-oceanic ridge basalts (MORB), leading concentrations relative to similarly incompatible elements in Hato speculation that the excess magmatism associated with waiian submarine magmas are depleted (Loihi), equivalent (Kilauea, plumes is related to a mantle ‘wet spot’ (Schilling et al., North Arch, Kauai–Oahu), or enriched (South Arch). H2O/Ce 1980) or a ‘not-so-hot-spot’ (Bonatti, 1990). Thus, there ratios are uncorrelated with major element composition or extent or is still lively debate over the relative importance of ‘hot’ depth of melting, but are related to position relative to the Hawaiian and ‘wet’ in the generation of mantle plumes. plume and mantle source region composition, consistent with a zoned The knowledge that OIB are wetter than MORB, plume model. In front of the plume core, overlying mantle is however, does little to answer the question of the origin metasomatized by hydrous partial melts derived from the Hawaiian of volatiles in plume basalts. If the enrichments of volatile plume. Downstream from the plume core, lavas tap a depleted source elements in OIB are proportional to those of nonvolatile region with H2O/Ce similar to enriched Pacific mid-ocean ridge incompatible elements, then their higher concentrations basalt. Within the plume core, mantle components, thought to can be accomplished through simple mineral–melt fracrepresent subducted oceanic lithosphere, have water enrichments tionation processes. In contrast, if the volatile elements equivalent to (KEA) or less than (KOO) that of Ce. Lower H2O/ are decoupled from major and trace elements, then more Ce in the KOO component may reflect efficient dehydration of the complex processes must take place, including involvement subducting oceanic crust and sediments during recycling into the and possible migration into or out of the plume of a deep mantle. separate C + H + O fluid phase, mixing of source regions having different volatile contents, or shallow-level processes such as assimilation or degassing. In particular

Previous estimates of crustal storage time of magmas at Kilauea Volcano, Hawaii, range from a few years to a few thousand years, leading to considerable uncertainty in the time scales of processes of magmatic storage and differentiation. We present a new approach for determining minimum magma residence times which involves dating phenocrysts in a magma using 226Ra–230Th disequilibria, and apply this approach to the early phase of the 1955 east rift eruption at Kilauea. When fractionation of Ra from Ba (a proxy for initial Ra in the crystals) during crystal growth is considered along with the effects of inclusions in the minerals, the data are consistent with co-precipitation of plagioclase and clinopyroxene from a melt represented by the groundmass at a mean age of 1000+300−400 a. Unless a significant fraction (>30%) of the crystals are remnants from an earlier batch of evolved magma in the system, these data constrain the minimum magmatic residence time to be ∼550 yr, considerably longer than most previous estimates of storage time at Kilauea as well as those for some other basaltic systems. For the temperature interval of augite+plagioclase growth in the early 1955 magma, a maximum constant cooling rate of 0.1°C/yr (1×10−5°C/h) is derived from the minimum magmatic residence time of 550 yr. The total magma storage time would be >2500 yr if this cooling rate applied to the entire thermal history of the magma, although a more complex cooling history where cooling rates were more rapid early in the storage history is permissive of a total residence time which is not much longer than 550 yr. The disparate estimates of magma residence at Kilauea may reflect the uncertainties in the methods of estimation in addition to true variations in storage time for different batches of magma. More work is necessary in order to determine whether a long residence time is characteristic of rift zone lavas and/or of Kilauean lavas in general.

Basaltic lavas and hyaloclastites dredged from the President Jackson Seamounts, a 65-km-long, linear volcanic chain starting near latitude 42°20'N west of the northern Gorda Ridge, are normal mid-ocean ridge basalt (MORB), with compositions ranging from highly depleted (0.07% K 2 O, 0.54 La/Sm N ) to moderately enriched in incompatible elements (0.24% K 2 O, 0.86 La/Sm N ). The seamount lavas are similar in many respects to those erupted at the adjacent ridge but have some important geochemical differences. Seamount lavas are concentrated toward primitive compositions with higher MgO contents (to 9.3%, Mg number 69.5) than most of the nearby ridge lavas. They also have systematically lower TiO 2 and FeO and higher CaO, Na 2 O, and Sr at comparable MgO content than adjacent ridge basalts. Seamount basalts contain phenocrysts in equilibrium with the melt and lack compositionally diverse glass inclusions and compositional zoning common in phenocrysts of most ridge basalt. Minor and trace element variability at a given MgO content indicates complex petrogenetic processes. Radiogenic isotopic ratios indicate somewhat less depleted sources than for basalt from the adjacent ridge axis. The higher Pb isotopic ratios of some lavas trend toward enriched MORB. The seamounts typically have multiple, nested calderas or pit craters, stepping downward toward the ridge axis, indicating formation in the active, near-ridge, extensional environment. The predominantly primitive nature of the lavas suggests that they pass through crustal magma reservoirs, presumably underlying the calderas, very rapidly. The lack of evidence for magma mixing suggests that batches of magma are delivered to the seamounts episodically and either solidify or are drained into ridge-parallel faults before the next batch arrives. In contrast, lavas from the ridge axis show evidence for magma mixing involving more fractionated melts that show evidence for clinopyroxene fractionation. Despite a lack of seismic evidence for magma chambers under slow spreading centers, continuous melt zones must be present under the Gorda Ridge axis to give the ubiquitous imprint of magma mixing.

Measurements of 238U-230Th-226Ra and 235U-231Pa disequilibria in a suite of tholeiitic-to-basanitic lavas provide estimates of porosity, solid mantle upwelling rate and melt transport times beneath Hawaii. The observation that (230Th/238U) > 1 indicates that garnet is required as a residual phase in the magma sources for all of the lavas. Both chromatographic porous flow and dynamic melting of a garnet peridotite source can adequately explain the combined U-Th-Ra and U-Pa data for these Hawaiian basalts. For chromatographic porous flow, the calculated maximum porosity in the melting zone ranges from 0.3–3% for tholeiites and 0.1–1% for alkali basalts and basanites, and solid mantle upwelling rates range from 40 to 100 cm yr−1 for tholeiites and from 1 to 3 cm yr−1 for basanites. For dynamic melting, the escape or threshold porosity is 0.5–2% for tholeiites and 0.1–0.8% for alkali basalts and basanites, and solid mantle upwelling rates range from 10 to 30 cm yr−1 for tholeiites and from 0.1 to 1 cm yr−1 for basanites. Assuming a constant melt productivity, calculated total melt fractions range from 15% for the tholeiitic basalts to 3% for alkali basalts and basanites.

Many tholeiitic and transitional pillow-rim and fragmental glasses from Loihi seamount, Hawaii, have high Cl contents and Cl/K_2O ratios (and ratios of Cl to other incompatible components, such as P_2O_5, H_2O, etc.) relative to other Hawaiian subaerial volcanoes (e.g., Mauna Loa, Mauna Kea, and Kilauea). We suggest that this results from widespread contamination of Loihi magmas by a Cl-rich, seawater-derived component. Assimilation of high-Cl phases such as saline brine or Cl-rich minerals (halite or iron–hydroxychlorides) with high Cl/H_2O ratios can explain the range and magnitude of Cl contents in Loihi glasses, as well as the variations in the ratios of Cl to other incompatible elements. Brines and Cl-rich minerals are thought to form from seawater within the hydrothermal systems associated with submarine volcanoes, and Loihi magmas could plausibly have assimilated such materials from the hydrothermal envelope adjacent to the magma chamber. Our model can also explain semiquantitatively the observed contamination of Loihi glasses with atmospheric-derived noble gases, provided the assimilant has concentrations of Ne and Ar comparable to or slightly less than seawater. This is more likely for brines than for Cl-rich minerals, leading us to favor brines as the major assimilant. Cl/Br ratios for a limited number of Loihi samples are also seawater-like, and show no indication of the higher values expected to be associated with the assimilation of Cl-rich hydrothermal minerals. Although Cl enrichment is a common feature of lavas from Loihi, submarine glasses from other Hawaiian volcanoes show little (Kilauea) or no (Mauna Loa, Mauna Kea) evidence of this process, suggesting that assimilation of seawater-derived components is more likely to occur in the early stages of growth of oceanic volcanoes. Summit collapse events such as the one observed at Loihi in October 1996 provide a ready mechanism for depositing brine-bearing rocks from the volcanic edifice into the top of a submarine summit magma chamber.

The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts with similar reverse zonation.

Mid-ocean ridge basalts (MORBs) erupted in Escanaba Trough, INTRODUCTION the southernmost segment of the Gorda Ridge, have greater isotopic Crustal contamination of basaltic magmas is generally and geochemical variability than those from the remainder of the recognized for continental volcanoes (e.g. Taylor, 1980; ridge. Samples from the sediment-free northern sites in the trough Leeman & Hawkesworth, 1986; Glazner et al., 1991). The are depleted normal-MORB similar to those from the northern composition, thickness, and low melting temperatures of Gorda Ridge. However, samples from the sediment-covered portion continental crustal rocks facilitate assimilation that can of the trough are significantly enriched in incompatible elements, be easily identified. However, the extent to which basaltic and Sr, Nd and Pb isotopic ratios are shifted toward the composition magmas are contaminated by oceanic crust is a topic of of local sediments. Pb isotopic ratios, in particular, lie on a mixing intense debate (e.g. Bohrson & Reid, 1995; Clague et al., line with local sediments. Assimilation–fractional crystallization 1995; Eiler et al., 1996; Bohrson et al., 1996, and references (AFC) calculations suggest that 25–40% fractional crystallization therein; Thirlwall et al., 1997). The debate has focused coupled with assimilation of 1–2% of local sediments can produce on distinguishing the chemical characteristics magmas the enrichment observed for some Escanaba basalts. Variations in acquire during ascent, crustal storage, and emplacement the amount of enrichment of elements with similar incompatibility from those that have been used to identify heterogeneous for comparably differentiated basalts, and uncorrelated isotopic mantle sources. For most ocean island volcanoes, the ratios suggest variable amounts of assimilation of compositionally crustal components available to serve as contaminants heterogeneous assimilants by parental magmas. Assimilation of are poorly characterized, but include the underlying sediment by MORB magmas probably resulted when laccolithic altered oceanic crust, pelagic to hemipelagic sediment, intrusions ponded at the sediment–basement interface beneath the and the hydrothermally altered volcanic edifice. thick sediment cover in the southern part of Escanaba Trough. Mid-ocean ridge basalts (MORBs) are relatively uniGeochemical and isotopic evidence for contamination can be detected form geochemically with depleted incompatible element in these lavas because of the strong compositional contrast between and radiogenic isotope compositions compared with lavas the parental magma and assimilant. The depleted MORB magma from ocean island or continental volcanoes. However, and highly enriched sediment assimilant are end-member comexcess chlorine content and Cl/K ratios in fresh MORB positions that provide a sensitive indicator for the smallest amount glasses support the idea that MORB magmas may also of contamination of oceanic magma by crustal processes. be affected by assimilation of hydrothermally altered oceanic crust (e.g. Michael & Schilling, 1988; Michael & Cornell, 1996). Chlorine, like other incompatible elements, shows the greatest enrichment in strongly frac

We performed an ion-microprobe study of eleven high-MgO (6.7–14.8 wt%) tholeiite glasses from the Hawaiian volcanoes Kilauea, Mauna Loa and Haleakala. We determined the rare earth (RE), high field strength, and other selected trace element abundances of these glasses, and used the data to establish their relationship to typical Hawaiian shield tholeiite and to infer characteristics of their source. The glasses have trace element abundance characteristics generally similar to those of typical shield tholeiites, e.g. L(light)REE/H(heavy)REEC1

Volcaniclastic units cored at depths of about 87, 164, 178, 226, and 246 m below sea level and carbonate units located between depths of 27 and 53 m below sea level in the Hilo drill core were found to be deposited at or near sea level. Four of these units are hydroclastic deposits, formed when subaerially erupted Mauna Loa lava flows entered the ocean and fragmented to produce quenched, glassy fragments during hydrovolcanic explosions. Ash units 24 and 26, at 178 m depth, accumulated at sea level in a freshwater bog. They contain pyroxenes crystallized from tholeiitic magma that we infer erupted explosively at the summit of Kilauea volcano. Two carbon-rich layers from these ashes have a weighted average radiocarbon age of 38.6 ± 0.9 ka; the ashes probably correlate with the oldest and thickest part of the Pahala ash. Ash unit 44, at the transition from Mauna Kea to Mauna Loa lava flows, was probably nearly 3.2 m thick and is inferred to be equivalent to the lower thick part of the composite Homelani ash mapped in Hilo and on the flanks of Mauna Kea. The age of this part of Homelani ash is between 128 ± 33 and 200 ± 10 ka; it may have erupted subglacially during the Pohakuloa glacial maxima on Mauna Kea. Beach sand units 12 and 22 were derived from nearby Mauna Loa and Mauna Kea lava flows. The middle of beach sand unit 38 was derived mainly from lava erupted near the distal end of the subaerial east rift zone of Kilauea volcano; these sands were transported about 33 km northwest to Hilo Bay by prevailing longshore currents. Combined age, depth, and sea level markers in the core allow us to determine that lava flow recurrence intervals averaged one flow every 4 kyr during the past 86 kyr and one flow every 16 kyr between 86 and 200 ka at the drill site and that major explosive eruptions that deposit thick ash in Hilo have occurred only twice in the last 400 kyr. These recurrence intervals support the moderate lava flow hazard zonation (zone 3) for coastal Hilo previously determined from surficial mapping.

This is the first article to describe mineralization of midplate submarine rift zones and hydrothermal manganese oxide mineralization of midplate volcanic edifices. Hydrothermal Mn oxides were recovered from submarine extensions of two Hawaiian rift zones, along Haleakala and Puna Ridges. These Mn oxides form two types of deposits, metallic stratiform layers in volcaniclastic rocks and cement for clastic rocks; both deposit types are composed of todorokite and bimessite. Thin Fe‐Mn crusts that coat some rocks formed by a combination of hydrogenetic and hydrothermal processes and are composed of δ‐MnO2. The stratiform layers have high Mn contents (mean 40%) and a large fractionation between Mn and Fe (Fe/Mn = 0.04). Unlike most other hydrothermal Mn oxide deposits, those from Hawaiian rift zones are enriched in the trace metals Zn, Co, Ba, Mo, Sr, V, and especially Ni (mean 0.16%). Metals are derived from three sources: mafic and ultramafic rocks leached by circulating hydrothermal fluids, clastic material...

The south flank of Kilauea Volcano is unstable and has the structure of a huge landslide; it is one of at least 17 enormous catastrophic landslides shed from the Hawaiian Islands. Mechanisms previously proposed for movement of the south flank invoke slip of the volcanic pile over seafloor sediments. Slip on a low friction decollement alone cannot explain why the thickest and widest sector of the flank moves more rapidly than the rest, or why this section contains a 300 km3 aseismic volume above the seismically defined decollement. It is proposed that this aseismic volume, adjacent to the caldera in the direction of flank slip, consists of olivine cumulates that creep outward, pushing the south flank seawards. Average primary Kilauea tholeiitic magma contains about 16.5 wt.% MgO compared with an average 10 wt.% MgO for erupted subaerial and submarine basalts. This difference requires fractionation of 17 wt.% (14 vol.%) olivine phenocrysts that accumulate near the base of the magma reservoir where they form cumulates. Submarine-erupted Kilauea lavas contain abundant deformed olivine xenocrysts derived from these cumulates. Deformed dunite formed during the tholeiitic shield stage is also erupted as xenoliths in subsequent alkalic lavas. The deformation structures in olivine xenocrysts suggest that the cumulus olivine was densely packed, probably with as little as 5–10 vol.% intercumulus liquid, before entrainment of the xenocrysts. The olivine cumulates were at magmatic temperatures (>1100°C) when the xenocrysts were entrained. Olivine at 1100°C has a rheology similar to ice, and the olivine cumulates should flow down and away from the summit of the volcano. Flow of the olivine cumulates places constant pressure on the unbuttressed seaward flank, leading to an extensional region that localizes deep intrusions behind the flank; these intrusions add to the seaward push. This mechanism ties the source of gravitational instability to the caldera complex and deep rift systems and, therefore, limits catastrophic sector failure of Hawaiian volcanoes to their active growth phase, when the core of olivine cumulates is still hot enough to flow.

Subduction of oceanic crust and the formation of volcanic arcs above the subduction zone are important components in Earth’s geological and geochemical cycles. Subduction consumes and recycles material from the oceanic plates, releasing fluids and gases that enhance magmatic activity, feed hydrothermal systems, generate ore deposits and nurture chemosynthetic biological communities. Among the first lavas to erupt at the surface from a nascent subduction zone are a type classified as boninites. These lavas contain information about the early stages of subduction, yet because most subduction systems on Earth are old and well-established, boninite lavas have previously only been observed in the ancient geological record. Here we observe and sample an active boninite eruption occurring at 1,200 m depth at the West Mata submarine volcano in the northeast Lau Basin, southwest Pacific Ocean. We find that large volumes of H2O, CO2 and sulphur are emitted, which we suggest are derived from the subducting slab. These volatiles drive explosive eruptions that fragment rocks and generate abundant incandescent magma-skinned bubbles and pillow lavas. The eruption has been ongoing for at least 2.5 years and we conclude that this boninite eruption is a multi-year, low-mass-transfer-rate eruption. Thus the Lau Basin may provide an important site for the long-term study of submarine volcanic eruptions related to the early stages of subduction. Boninite lavas are erupted during the early stages of subduction, however they have previously been found only in the ancient geological record. Discovery of an active boninite eruption shows that abundant volatile gases derived from the subducting slab drive this violent eruptive activity, even in the deep sea.

High-resolution (1.5 m) mapping from the autonomous underwater vehicle (AUV) D. Allan B. of West Mata Volcano in the northern Lau Basin is used to identify the processes that construct and modify the volcano. The surface consists largely of volcaniclastic debris that forms smooth slopes to the NW and SE, with smaller lava flows forming gently sloping plateaus concentrated along the ENE and WSW rift zones, and more elongate flows radiating from the summit. Two active volcanic vents, Prometheus and Hades, are located ∼50 and ∼150 m WSW of the 1159 m summit, respectively, and are slightly NW of the ridgeline so the most abundant clastic deposits are emplaced on the NW flank. This eruptive activity and the location of vents appears to have been persistent for more than a decade, based on comparison of ship-based bathymetric surveys in 1996 and 2008–2010, which show positive depth changes up to 96 m on the summit and north flank of the volcano. The widespread distribution of clastic deposits downslope from the rift zones, as well as from the current vents, suggests that pyroclastic activity occurs at least as deep as 2200 m. The similar morphology of additional nearby volcanoes suggests that they too have abundant pyroclastic deposits.

Noble gas elemental and isotopic abundances have been analysed in twenty-two samples of basaltic glass dredged from the submarine flanks of two currently active Hawaiian volcanoes, Loihi Seamount and Kilauea. Neon isotopic ratios are enriched in 20Ne and 21Ne by as much as 16% with respect to atmospheric ratios. All the Hawaiian basalt glass samples show relatively high 3He4He ratios. The high 20Ne22Ne values in some of the Hawaiian samples, together with correlations between neon and helium systematics, suggest the presence of a solar component in the source regions of the Hawaiian mantle plume. The solar hypothesis for the Earth's primordial noble gas composition can account for helium and neon isotopic ratios observed in basaltic glasses from both plume and spreading systems, in fluids in continental hydrothermal systems, in CO2 well gases, and in ancient diamonds. These results provide new insights into the origin and evolution of the Earth's atmosphere.

Volcanic samples collected with the Monterey Bay Aquarium Research Institute's ROV Tiburon from eight seamounts at the continental margin offshore central to southern California comprise a diverse suite of mainly alkalic basalt to trachyte but also include rare tholeiitic basalt and basanite. All samples experienced complex crystal fractionation probably near the crust/mantle boundary, based on the presence in some of mantle xenoliths. Incompatible trace elements, poorly correlated with isotopic compositions, suggest variable degrees of partial melting of compositionally heterogeneous mantle sources, ranging from MORB-like to relatively enriched OIB. High-precision 40Ar/39Ar ages indicate episodes of volcanic activity mainly from 16 to 7 Ma but document one eruption as recent as 2.8 Ma at San Juan Seamount. Synchronous episodes of volcanism occurred at geographically widely separated locations offshore and within the continental borderland. Collectively, the samples from these seamounts have age ranges and chemical compositions similar to those from Davidson Seamount, identified as being located atop an abandoned spreading center. These seamounts appear to have a common origin ultimately related to abandonment and partial subduction of spreading center segments when the plate boundary changed from subduction-dominated to a transform margin. They differ in composition, age, and origin from other more widespread near-ridge seamounts, which commonly have circular plans with nested calderas, and from age progressive volcanoes in linear arrays, such as the Fieberling-Guadalupe chain, that occur in the same region. Each volcanic episode represents decompression melting of discrete enriched material in the suboceanic mantle with melts rising along zones of weakness in the oceanic crust fabric. The process may be aided by transtensional tectonics related to continued faulting along the continental margin.

A lava pillar formed during the 1998 eruption at Axial Seamount exhibits compositional and textural evidence for contamination by seawater under magmatic conditions. Glass immediately adjacent to anastomosing microfractures within 1 cm of the inner pillar wall is oxidized and significantly enriched in Na and Cl and depleted in Fe and K with respect to that in glassy selvages from the unaffected outer pillar wall. The affected glass contains up to 1 wt % Cl and is enriched by ∼2 wt % Na2O relative to unaffected glass, consistent with a nearly 1:1 (molar) incorporation of NaCl. Glass bordering the Cl-enriched glass in the inner pillar wall is depleted in Na but enriched in K. The presence of tiny (

Seafloor spreading causes abundant magmatism along active ocean spreading centers, but the cause of magmatism along fossil spreading centers is enigmatic. Samples collected from Davidson Seamount, a typical volcanic ridge along an abandoned spreading center in the eastern Pacific, consist of an alkalic basalt to trachyte lava series; transitional basalts were sampled from another part of the abandoned axis, 20 km from the seamount. All samples experienced complex fractional crystallization prior to eruption, but they all share a common, compositionally heterogeneous mantle source. The parental magmas of the transitional basalts were produced from this source at higher degree of melting than those of the alkalic lava series. The composition of Davidson lavas overlaps with those of ridges along other fossil spreading centers and isolated near- and off-ridge seamounts in the eastern Pacific. Together they define a compositional continuum ranging from tholeiitic, normal mid-ocean ridge basalt (MORB)-like to alkalic, ocean island basalt (OIB)-like, similar to lavas that form linear island chains and ridges. We propose that this entire compositional spectrum of intraplate lavas that do not form linear volcanic chains in the eastern Pacific results from variations in the degree of partial melting of a common, compositionally heterogeneous mantle source. This source consists of more easily melted, geochemically enriched components of varying sizes and amounts embedded in a depleted lherzolitic matrix. Large degree of partial melting produces normal MORB–like melts represented by some near-ridge seamount lavas, whereas small degree of melting produces OIB-like fossil spreading center lavas. The small degree of partial melting beneath recently abandoned spreading centers results from either buoyancy-driven decompression melting of the hot lithospheric and asthenospheric mantle material beneath active spreading centers or rapid motion, with respect to the underlying asthenosphere, of abandoned spreading axes that are thickening over a fertile mantle. Mid-Tertiary volcanic rocks in coastal California, which are compositionally akin to intraplate lavas, are interpreted to be small degree partial melts of the same compositionally heterogeneous sub-Pacific mantle that has upwelled through windows in a subducted slab.