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Kilauea Volcano's 2018 lower East Rift Zone (LERZ) eruption produced exceptionally high lava effusion rates and record-setting SO2 emissions. The eruption involved a diverse range of magmas, including primitive basalts sourced from Kilauea's summit reservoirs. We analyzed LERZ matrix glasses, melt inclusions, and host minerals to identify melt volatile contents and magma storage depths. The LERZ glasses and melt inclusions span nearly the entire compositional range previously recognized at Kilauea. Melt inclusions in Fo(86-89) olivine from the main eruptive vent (fissure 8) underwent 70-170 degrees C cooling during transport in LERZ carrier melts, causing extensive post-entrapment crystallization and sulfide precipitation. Many of these melt inclusions have low sulfur (400-900 ppm) even after correction for sulfide formation. CO2 and H2O vapor saturation pressures indicate shallow melt inclusion trapping depths (1-5 km), consistent with formation within Kilauea's Halema'uma'u and South Caldera reservoirs. Many of these inclusions also have degassed delta S-34 values (1.5 to -0.5%). Collectively, these results indicate that some primitive melts experienced near-surface degassing before being trapped into melt inclusions. We propose that decades-to-centuries of repeated lava lake activity and lava drain-back during eruptions (e.g., 1959 Kilauea Iki) recycled substantial volumes of degassed magma into Kilauea's shallow reservoir system. Degassing and magma recycling from the 2008-2018 Halema'uma'u lava lake likely reduced the volatile contents of LERZ fissure 8 magmas, resulting in lower fountain heights compared to many prior Kilauea eruptions. The eruption's extreme SO2 emissions were due to high lava effusion rates rather than particularly volatile-rich melts. U.S. Geological Survey (USGS) Volcano Science Center; Hawaiian Volcano Observatory (HVO); University of Hawaii-Hilo; HVO volunteer program; Department of Earth Sciences at the University of Oregon; Mineralogical Society of America; Geological Society of America; Mazamas student research grant program; National Science Foundation (NSF) Graduate Research Fellowship ProgramNational Science Foundation (NSF); NSF Graduate Research Internship Program (GRIP) Published version The authors would like to thank Matthew Loewen, Nicole Metrich, and Matt Patrick for constructive input that significantly improved this manuscript. The authors also thank the U.S. Geological Survey (USGS) Volcano Science Center, Hawaiian Volcano Observatory (HVO), University of Hawaii-Hilo, partner agencies, and the residents of Hawaii for support, field access, data sharing, and for their great care in documenting and responding to the 2018 LERZ eruption crisis. AHL thanks Tina Neal and the HVO volunteer program for support, Mike Zoeller for map assistance, and Carolyn Parcheta for collecting and sharing samples. Geochemical analyses were conducted with the help of John Donovan and Julie Chouinard (EPMA), and Brian Monteleone and Glenn Gaetani (SIMS and MI rehomogenization). AHL thanks Michelle Muth and Madison Myers for discussions on methodology and melt inclusion interpretation. AHL acknowledges funding support from Department of Earth Sciences at the University of Oregon, the Mineralogical Society of America, the Geological Society of America, the Mazamas student research grant program, the National Science Foundation (NSF) Graduate Research Fellowship Program, and the NSF Graduate Research Internship Program (GRIP). Coordination of GRIP at the USGS is through the Youth and Education in Science programs within the Office of Science Quality and Integrity. Public domain – authored by a U.S. government employee

Multiphase and multicomponent fluid flow in the shallow continental crust plays a significant role in a variety of processes over a broad range of temperatures and pressures. The presence of dissolved gases in aqueous fluids reduces the liquid stability field toward lower temperatures and enhances the explosivity potential with respect to pure water. Therefore, in areas where magma is actively degassing into a hydrothermal system, gas-rich aqueous fluids can exert a major control on geothermal energy production, can be propellants in hazardous hydrothermal (phreatic) eruptions, and can modulate the dynamics of geyser eruptions. We collected pressurized samples of thermal water that preserved dissolved gases in conjunction with precise temperature measurements with depth in research well Y-7 (maximum depth of 70.1 m; casing to 31 m) and five thermal pools (maximum depth of 11.3 m) in the Upper Geyser Basin of Yellowstone National Park, USA. Based on the dissolved gas concentrations, we demonstrate that CO 2 mainly derived from magma and N 2 from air-saturated meteoric water reduce the near-surface saturation temperature, consistent with some previous observations in geyser conduits. Thermodynamic calculations suggest that the dissolved CO 2 and N 2 modulate the dynamics of geyser eruptions and are likely triggers of hydrothermal eruptions when recharged into shallow reservoirs at high concentrations. Therefore, monitoring changes in gas emission rate and composition in areas with neutral and alkaline chlorine thermal features could provide important information on the natural resources (geysers) and hazards (eruptions) in these areas.

Magma movement, fault structures and hydrothermal systems influence volatile emissions at rift volcanoes. Longonot is a Quaternary caldera volcano located in the southern Kenyan Rift, where regional extension controls recent shallow magma ascent. Here we report the results of a soil carbon dioxide (CO2) survey in the vicinity of Longonot volcano, as well as fumarolic gas compositions and carbon isotope data. The total non-biogenic CO2 degassing is estimated at − 1, and is largely controlled by crater faults and fractures close to the summit. Thus, recent volcanic structures, rather than regional tectonics, control fluid pathways and degassing. Fumarolic gases are characterised by a narrow range in carbon isotope ratios (δ13C), from − 4.7‰ to − 6.4‰ (vs. PDB) suggesting a magmatic origin with minor contributions from biogenic CO2. Comparison with other degassing measurements in the East African Rift shows that records of historical eruptions or unrest do not correspond directly to the magnitude of CO2 flux from volcanic centres, which may instead reflect the current size and characteristics of the subsurface magma reservoir. Interestingly, the integrated CO2 flux from faulted rift basins is reported to be an order of magnitude higher than that from any of the volcanic centres for which CO2 surveys have so far been reported.

[1] Volcanic gases are sensitive indicators of subduction processes and are used to evaluate the contributions from various source components. Nitrogen isotope systematics in particular are a valuable tool for determining the fate of organic matter in subduction zones. We present the first arc-wide survey of trace gas chemistry and nitrogen isotope variations from the Sangihe Arc of northeastern Indonesia, where the narrow Molucca Sea Plate subducts beneath the Sangihe Arc to the west and the Halmahera Arc to the east. Relative volatile abundances and N isotopic compositions of volcanic gases show systematic along-arc variations. Northern volcanoes exhibit low N2/He ratios and δ15N values (northern minima 542 and −7.3‰, respectively), indicating minimal addition of sediment to source magmas. In contrast, the southern part of the arc is characterized by high N2/He and δ15N values (southern maxima 2000 and +2.1‰, respectively), consistent with greater sediment contributions in the formation of the magmas. These observations can be correlated with the complex tectonic setting of the region whereby oblique collision between the two arcs has caused sediment obduction, decoupling the accretionary wedges from the underlying oceanic plate. In the north, where the collision is more developed, the lack of trace gas and N isotope evidence of sedimentary inputs to the source of arc magmas is consistent with enhanced sediment decoupling. In the south, where collision and accretionary wedge decoupling are not yet taking place, sediments would presumably subduct normally, in agreement with higher N2/He and δ15N values. Awu volcano, at the northernmost extension of the arc, is anomalous and exhibits high N2/He (2852) coupled with low δ15N (−3.3‰). These values are suggestive of increased slab contribution in the northernmost arc, possibly by slab melting as collision stalls the progress of the subducting plate and allows it to become superheated.