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Carbonate minerals have been detected in Jezero crater, an ancient lake basin that is the landing site of the Mars 2020 Perseverance rover, and within the regional olivine‐bearing (ROB) unit in the Nili Fossae region surrounding this crater. It has been suggested that some carbonates in the margin fractured unit, a rock unit within Jezero crater, formed in a fluviolacustrine environment, which would be conducive to preservation of biosignatures from paleolake‐inhabiting lifeforms. Here, we show that carbonate‐bearing rocks within and outside of Jezero crater have the same range of visible‐to‐near‐infrared carbonate absorption strengths, carbonate absorption band positions, thermal inertias, and morphologies. Thicknesses of exposed carbonate‐bearing rock cross‐sections in Jezero crater are ∼75–90 m thicker than typical ROB unit cross‐sections in the Nili Fossae region, but have similar thicknesses to ROB unit exposures in Libya Montes. These similarities in carbonate properties within and outside of Jezero crater is consistent with a shared origin for all of the carbonates in the Nili Fossae region. Carbonate absorption minima positions indicate that both Mg‐ and more Fe‐rich carbonates are present in the Nili Fossae region, consistent with the expected products of olivine carbonation. These estimated carbonate chemistries are similar to those in martian meteorites and the Comanche carbonates investigated by the Spirit rover in Columbia Hills. Our results indicate that hydrothermal alteration is the most likely formation mechanism for non‐deltaic carbonates within and outside of Jezero crater., Key Points Carbonates within and outside of Jezero crater have similar spectra, thermal inertias, morphologies, and thicknessesCarbonates within and outside of Jezero crater likely formed via the same processesHydrothermal alteration and evaporation are the most likely processes for carbonate formation within and outside of Jezero crater

The high computational cost of Global Climate Models (GCMs) is a problem that limits their use in many areas. Recently an inverse climate modeling (InvCM) method, which fixes the global mean sea surface temperature (SST) and evolves the CO2 mixing ratio to equilibrate climate, has been implemented in a cloud‐resolving model. In this article, we apply InvCM to ExoCAM GCM aquaplanet simulations, allowing the SST pattern to evolve while maintaining a fixed global‐mean SST. We find that InvCM produces the same climate as normal slab‐ocean simulations but converges an order of magnitude faster. We then use InvCM to calculate the equilibrium CO2 for SSTs ranging from 290 to 340 K at 1 K intervals and reproduce the large increase in climate sensitivity at an SST of about 315 K at much higher temperature resolution. The speedup provided by InvCM could be used to equilibrate GCMs at higher spatial resolution or to perform broader parameter space exploration in order to gain new insight into the climate system. Additionally, InvCM could be used to find unstable and hidden climate states, and to find climate states close to bifurcations such as the runaway greenhouse transition., Key Points We converge a GCM by varying the CO2 while keeping the global‐mean surface temperature fixed (the inverse climate modeling method)Inverse climate modeling converges about 10 times faster than normal slab‐ocean simulationsThe SST gradient response timescale is the bottleneck on the convergence rate of inverse climate modeling

Jezero crater is the landing site for the Mars 2020 Perseverance rover. The Noachian‐aged crater has undergone several periods of fluvial and lacustrine activity and phyllosilicate‐ and carbonate‐bearing rocks were formed and emplaced as a result. It also contains a portion of the regional Nili Fossae olivine‐carbonate unit. In this work, we performed spectral mixture analysis of visible/near‐infrared hyperspectral imagery over Jezero. We modeled carbonate abundances up to ∼35% and identified three distinct units containing different carbonate phases. Our work also shows that the olivine in Jezero is predominantly restricted to aeolian deposits overlying the carbonate rocks. The diversity of carbonate phases in Jezero points to multiple periods of carbonate formation under varying conditions., Key Points Unmixing of near‐infrared spectra in Jezero crater suggests carbonate abundances up to ∼35% per pixelStrong olivine spectral signatures are correlated to sand deposits overlying light‐toned carbonate‐bearing rocksFe‐carbonate is the dominant phase throughout the study area; Mg‐carbonate is present along the Jezero paleolake rim

We present the first investigation and quantification of the photoionization loss process to Mercury's sodium exosphere from spacecraft and ground‐based observations. We analyze plasma and neutral sodium measurements from NASA's MESSENGER spacecraft and the THEMIS telescope. We find that the sodium ion (Na+) content and therefore the significance of photoionization varies with Mercury's orbit around the Sun (i.e., true anomaly angle: TAA). Na+ production is affected by the neutral sodium solar‐radiation acceleration loss process. More Na+ was measured on the inbound leg of Mercury's orbit at 180°–360° TAA because less neutral sodium is lost downtail from radiation acceleration. Calculations using results from observations show that the photoionization loss process removes ∼1024 atoms/s from the sodium exosphere (maxima of 4 × 1024 atoms/s), showing that modeling efforts underestimate this loss process. This is an important result as it shows that photoionization is a significant loss process and larger than loss from radiation acceleration., Key Points Photoionization can be a significant loss process to the sodium exosphere with peak loss estimates of 4 × 1024 atoms/sThe photoionization loss process of Mercury's sodium exosphere varies throughout the planet's orbit around the SunMore sodium is lost due to photoionization on the inbound leg (true anomaly angle of 180°–360°) of Mercury's orbit than the outbound leg

We present a re‐examination of mass spectral data obtained from the Pioneer Venus Large Probe Neutral Mass Spectrometer. Our interpretations of differing trace chemical species are suggestive of redox disequilibria in Venus' middle clouds. Assignments to the data (at 51.3 km) include phosphine, hydrogen sulfide, nitrous acid, nitric acid, carbon monoxide, hydrochloric acid, hydrogen cyanide, ethane, and potentially ammonia, chlorous acid, and several tentative PxOy species. All parent ions were predicated upon assignment of corresponding fragmentation products, isotopologues, and atomic species. The data reveal parent ions at varying oxidation states, implying the presence of reducing power in the clouds, and illuminating the potential for chemistries yet to be discovered. When considering the hypothetical habitability of Venus' clouds, the assignments reveal a potential signature of anaerobic phosphorus metabolism (phosphine), an electron donor for anoxygenic photosynthesis (nitrite), and major constituents of the nitrogen cycle (nitrate, nitrite, ammonia, and N2)., Key Points Mass data from the Pioneer Venus Large Probe Neutral Mass Spectrometer reveals several trace chemical species suggestive of disequilibriaTrace species in the middle clouds include phosphine, hydrogen sulfide, nitrous acid, nitric acid, hydrogen cyanide, and carbon monoxideData reveal chemicals related to anaerobic phosphorus metabolism (phosphine), anoxygenic photosynthesis (nitrite), and the nitrogen cycle

We describe the capabilities, radiometric stability, and calibration of a custom vacuum environment chamber capable of simulating the near‐surface conditions of airless bodies. Here we demonstrate the collection of spectral measurements of a suite of fine particulate asteroid analogs made using the Planetary Analogue Surface Chamber for Asteroid and Lunar Environments (PASCALE) under conditions like those found on Earth and on airless bodies. The sample suite includes anhydrous and hydrated physical mixtures, and chondritic meteorites (CM, CI, CV, CR, and L5) previously characterized under Earth‐ and asteroid‐like conditions. And for the first time, we measure the terrestrial and extra‐terrestrial mineral end members used in the olivine‐ and phyllosilicate‐dominated physical mixtures under the same conditions as the mixtures and meteorites allowing us better understand how minerals combine spectrally when mixed intimately. Our measurements highlight the sensitivity of thermal infrared emissivity spectra to small amounts of low albedo materials and the composition of the sample materials. As the albedo of the sample decreases, we observe smaller differences between Earth‐ and asteroid‐like spectra, which results from a reduced thermal gradient in the upper hundreds of microns in the sample. These spectral measurements can be compared to thermal infrared emissivity spectra of asteroid (101955) Bennu's surface in regions where similarly fine particulate materials may be observed to infer surface compositions., Key Points Thermal infrared spectra of fine particulate minerals, physical mixtures of those minerals, and meteorites were measured under simulated Bennu conditionsComparisons of mineral, physical mixture, and meteorite spectra highlight the spectral behavior when materials are mixed in increasing complexityAs albedo decreases the spectral effects due to thermal gradients due to the vacuum environment of airless bodies are reduced

In the Late Noachian to Early Hesperian period, rivers transported detritus from igneous source terrains to a downstream lake within Gale crater, creating a stratified stack of fluviolacustrine rocks that is currently exposed along the slopes of Mount Sharp. Controversy exists regarding the paleoclimate that supported overland flow of liquid water at Gale crater, in large part because little is known about how chemical and mineralogical paleoclimate indicators from mafic‐rock dominated source‐to‐sink systems are translated into the rock record. Here, we compile data from basaltic terrains with varying climates on Earth in order to provide a reference frame for the conditions that may have prevailed during the formation of the sedimentary strata in Gale crater, particularly focusing on the Sheepbed and Pahrump Hills members. We calculate the chemical index of alteration for weathering profiles and fluvial sediments to better constrain the relationship between climate and chemical weathering in mafic terrains, a method that best estimates the cooler limit of climate conditions averaged over time. We also compare X‐ray diffraction patterns and mineral abundances from fluvial sediments in varying terrestrial climates and martian mudstones to better understand the influence of climate on secondary mineral assemblages in basaltic terrains. We show that the geochemistry and mineralogy of most of the fine‐grained sedimentary rocks in Gale crater display first‐order similarities with sediments generated in climates that resemble those of present‐day Iceland, while other parts of the stratigraphy indicate even colder baseline climate conditions. None of the lithologies examined at Gale crater resemble fluvial sediments or weathering profiles from warm (temperate to tropical) terrestrial climates., Key Points Terrestrial sediments and weathering profiles from basaltic terrains display first‐order similarities with mudstones from Gale crater, MarsThe chemical index of alteration can be used as paleoclimate proxy and places constraints on the ancient climate of Gale crater, MarsThe paleoclimate of Gale crater, Mars, was variable and ranged from Icelandic‐like conditions to colder climates

Planets intermediate in size between the Earth and Neptune, and orbiting closer to their host stars than Mercury does the Sun, are the most common type of planet revealed by exoplanet surveys over the last quarter century. Results from NASA's Kepler mission have revealed a bimodality in the radius distribution of these objects, with a relative underabundance of planets between 1.5 and 2.0 $R_{\oplus}$. This bimodality suggests that sub-Neptunes are mostly rocky planets that were born with primary atmospheres a few percent by mass accreted from the protoplanetary nebula. Planets above the radius gap were able to retain their atmospheres ("gas-rich super-Earths"), while planets below the radius gap lost their atmospheres and are stripped cores ("true super-Earths"). The mechanism that drives atmospheric loss for these planets remains an outstanding question, with photoevaporation and core-powered mass loss being the prime candidates. As with the mass-loss mechanism, there are two contenders for the origins of the solids in sub-Neptune planets: the migration model involves the growth and migration of embryos from beyond the ice line, while the drift model involves inward-drifting pebbles that coagulate to form planets close-in. Atmospheric studies have the potential to break degeneracies in interior structure models and place additional constraints on the origins of these planets. However, most atmospheric characterization efforts have been confounded by aerosols. Observations with upcoming facilities are expected to finally reveal the atmospheric compositions of these worlds, which are arguably the first fundamentally new type of planetary object identified from the study of exoplanets., Comment: Invited review in press in JGR: Planets special edition on exoplanets

Wind‐formed features are abundant in Oxia Planum (Mars), the landing site of the 2022 ExoMars mission, which shows geological evidence for a past wet environment. Studies of aeolian bedforms at the landing site were focused on assessing the risk for rover trafficability, however their potential in recording climatic fluctuations has not been explored. Here we show that the landing site experienced multiple climatic changes in the Amazonian, which are recorded by an intriguing set of ridges that we interpret as Periodic Bedrock Ridges (PBRs). Clues for a PBR origin result from ridge regularity, defect terminations, and the presence of preserved megaripples detaching from the PBRs. PBR orientation differs from superimposed transverse aeolian ridges pointing toward a major change in wind regime. Our results provide constrains on PBR formation mechanisms and offer indications on paleo winds that will be crucial for understanding the landing site geology., Key Points We present the first evidence for a periodic bedrock ridge (PBRs) pattern from the ExoMars 2022 landing siteFormative paleowind directions are extrapolated from PBRs and transverse aeolian ridgesEvidence for an Amazonian change in the wind regime are provided

The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between different chemical reservoirs that subsequently evolve via geological cycles. Current theoretical techniques are limited in exploring the anticipated range of compositional and thermal scenarios of early planetary evolution, even though these are of prime importance to aid astronomical inferences on the environmental context and geological history of extrasolar planets. Here, we present a coupled numerical framework that links an evolutionary, vertically resolved model of the planetary silicate mantle with a radiative‐convective model of the atmosphere. Using this method, we investigate the early evolution of idealized Earth‐sized rocky planets with end‐member, clear‐sky atmospheres dominated by either H2, H2O, CO2, CH4, CO, O2, or N2. We find central metrics of early planetary evolution, such as energy gradient, sequence of mantle solidification, surface pressure, or vertical stratification of the atmosphere, to be intimately controlled by the dominant volatile and outgassing history of the planet. Thermal sequences fall into three general classes with increasing cooling timescale: CO, N2, and O2 with minimal effect, H2O, CO2, and CH4 with intermediate influence, and H2 with several orders of magnitude increase in solidification time and atmosphere vertical stratification. Our numerical experiments exemplify the capabilities of the presented modeling framework and link the interior and atmospheric evolution of rocky exoplanets with multiwavelength astronomical observations., Key Points Magma oceans with different volatiles display varying timescales of solidification, outgassing, and atmospheric stratificationAtmospheric blanketing and cooling time increase in three principle classes from N2, CO, O2 to H2O, CO2, CH4 to H2 Coupled mantle–atmosphere systems display distinctive features that link the interior and surface state to atmospheric spectrum and climate

The Mars Atmosphere and Volatile EvolutioN (MAVEN) Neutral Gas and Ion Mass Spectrometer (NGIMS) provides sensitive detections of neutral gas and ambient ion composition. NGIMS measurements of nine atomic and molecular neutral species, and their variation with altitude, latitude, and solar zenith angle are reported over several months of operation of the MAVEN mission. Sampling NGIMS signals from multiple neutral species every several seconds reveals persistent and unexpectedly large amplitude density structures. The scale height temperatures are mapped over the course of the first few months of the mission from high down to midlatitudes. NGIMS measurements near the homopause of 40Ar/N2 ratios agree with those reported by the Sample Analysis at Mars investigation and allow the altitude of the homopause for the most abundant gases to be established., Key Points Neutral density structure measured with high temporal resolutionScale height temperature of the upper atmosphere reportedHomopause altitude identified

Recent observations of the Martian surface by the Phoenix lander and the Sample Analysis at Mars indicate the presence of perchlorate (ClO4 –). The abundance and isotopic composition of these perchlorates suggest that the mechanisms responsible for their formation in the Martian environment may be unique in our solar system. With this in mind, we propose a potential mechanism for the production of Martian perchlorate: the radiolysis of the Martian surface by galactic cosmic rays, followed by the sublimation of chlorine oxides into the atmosphere and their subsequent synthesis to form perchloric acid (HClO4) in the atmosphere, and the surface deposition and subsequent mineralization of HClO4 in the regolith to form surface perchlorates. To evaluate the viability of this mechanism, we employ a one‐dimensional chemical model, examining chlorine chemistry in the context of Martian atmospheric chemistry. Considering the chlorine oxide, OClO, we find that an OClO flux as low as 3.2 × 107 molecules cm–2 s–1 sublimated into the atmosphere from the surface could produce sufficient HClO4 to explain the perchlorate concentration on Mars, assuming an accumulation depth of 30 cm and integrated over the Amazonian period. Radiolysis provides an efficient pathway for the oxidation of chlorine, bypassing the efficient Cl/HCl recycling mechanism that characterizes HClO4 formation mechanisms proposed for the Earth but not Mars., Key Points Mechanism initiated by radiolysis in the surface can potentially account for observed Martian perchlorate concentrationsInjection of oxides of chlorine from the surface into the atmosphere is potentially an effective way of forming perchloric acidMartian perchlorate is an important oxidant but poorly characterized