Search

Es-Sbikhat- El-Mahmel, basin, located at the southeastern piedmont of Aures massif (Northeasten Algeria), is an area with a semi-arid climate. 39 samples were collected during May 2015, for physicochemical analysis. The interpretation of analysis data has shown a chemical facies evolution from bicarbonate-calcium waters into chloride-calcium waters, going through a transition facies marked by sulfate-calcium to sulfate-magnesium waters. The principal component analysis showed that the percentage of the variances expressed is 52.70% for the factor 1, 14.73% for the factor 2 and 11.44 for the factor 3. The binary diagrams and thermodynamic analysis corroborated that interaction water-rock is responsible for the mineralization through the geochemical process of mineral dissolution-precipitation, cationic exchange and anthropogenic pollution.

This chapter begins by examining general patterns of groundwater flow, recharge and discharge patterns, flow in layered systems, and crustal-scale flow patterns. The next topic covered is surface water hydrology and groundwater/surface water interaction, including examination of stream hydrographs and estimation of baseflow. The distribution of recharge in space and time is studied and common methods for estimating recharge are covered. The chapter has sections focused on the characteristics of groundwater flow in specific geologic environments. Case studies of many specific aquifers and hydrogeologic settings are presented: the High Plains Aquifer, New Jersey coastal plain aquifers, Western Cape Cod sand and gravel aquifers, the Dakota sandstone aquifer, karst systems near Mammoth Cave, and the Columbia Plateau basalts. The chapter closes with coverage of groundwater in permafrost environments.

This review tries to explain the effects of river infiltration and the interaction between groundwater and surface water on nitrogen (N) and phosphorus (P) distribution in riparian zones. On the basis of previous studies, this review summarized the distribution characteristics of N and P of 7 different riparian zones in China, compared the water quality of water bodies adjoining these riparian zones, proposed the distribution regularity of N and P in diverse riparian zones. The concentrations of N and P in the riparian zones with better water quality have increasing trend from riverside to upland. And those rivers with poorer water quality have decreasing trend. If the infiltrated concentration of runoff pollutant is more than river pollutant infiltration, the upland soil may obtain higher contaminants. On the contrary, if the concentration of river infiltration is more than that of the runoff, the riverside soil will show higher concentration. Similarly, if those two effects are equivalent, the concentration of N and P in the riparian zone will be low on riverside and upland, and somewhere in the middle will be higher than elsewhere. Clean rivers and polluted rivers taken with different quantity of contaminants will infiltrate diverse concentrations of N and P. It is expected that this review can provide a new theoretical basis for revealing the environmental effects of riparian zones and managing, protecting and restoring the riparian ecosystems.

It is well known that some sinkholes or subsidence takes place from time to time in areas where abandoned room-and-pillar-type mines exist. The authors have been involved in studies on the stability of abandoned mines beneath urbanised residential areas in the Tokai region, Japan, and there is a great concern about the stability of these abandoned mines during large earthquakes as well as in the long term. The 2003 Miyagi Hokubu and 2011 Great East Japan earthquakes caused great damage to abandoned mines and resulted in many collapses. Therefore, there is great concern about the stability of abandoned lignite mines in the Tokai region, particularly in Mitake Town, as the region could be affected by the anticipated successive Nankai, Tonankai and Tokai earthquake with a magnitude of 9.0. The authors give a brief summary of the geology of the Tokai region, the short-term and long-term properties of rocks surrounding the abandoned mines and their degradation characteristics. Then, some sinkhole and subsidence problems in the town due to long-term loading in abandoned lignite mines as well as earthquakes are described. The local and global stability issues of abandoned mines are described, and some procedures for estimating their stability in the long term are presented. Some discussions are made on the effect of depth and groundwater on the formation of sinkholes or ground subsidence associated with abandoned room-and-pillar lignite mines.

The quality of the groundwater in the study area was evaluated through various water quality indexes for drinking and irrigation purposes. To evaluate the water quality index, 186 groundwater samples were sampled during 2 different seasons, likely pre-monsoon (PRM) and post-monsoon (POM). The collected samples were measured for physical-chemical parameters like pH, EC, TDS, Na, K, Ca, Mg, Cl, HCO3, PO4, SO4, NO3 and H4SiO4. The research findings indicated that groundwater of the study area is approaching an alarming stage of its suitability for drinking purpose because a major percentage (i. e. 56%: PRM, 46%: POM) of samples are within poor category. Thus, the proper management strategy for water resources must be developed and a preventive management practice to address this issue must be implemented. Various water quality parameters such as electrical conductivity (EC), pH, salinity hazard, sodium hazard and permeability indexes (PI) were considered for irrigation water quality evaluation and it is inferred that the groundwater of the study area is suitable for irrigation. The PRM and POM samples with higher Na + and Cl concentrations were identified. The primary source of groundwater contamination is anthropogenic factors like domestic, agriculture effluents and mining activities. However, the groundwater of these regions is also greatly influenced by geogenic factors like weathering, rock-water interaction and precipitation which results in groundwater water level fluctuation. The research findings suggest the groundwater quality of this region is approaching an alarming stage for drinking purposes. Thus, developing a management strategy for drinking water sources and implementing preventive management practices to address this issue becomes imperative.

Lowland rivers and shallow aquifers are closely coupled and their interactions are crucial for maintaining healthy stream ecological functions. In order to explore river–aquifer interactions and lowland hydrological system in three Belgian catchments, we apply a combined approach of baseflow separation, impulse response modelling and time series analysis over a 30–year study period at catchment scale. Baseflow from hydrograph separation shows that the three catchments are groundwater-dominated. The recursive digital filter methods generate a smoother baseflow time series than the graphical methods, and yield more reliable results than the graphical ones. Impulse response modelling is applied with a two–step procedure. The first step where groundwater level response is modelled shows that groundwater level in shallow aquifers reacts fast to the system input, with most of the wells reaching their peak response during the first day. There is an overall trend of faster response time and higher response magnitude in the wet (October–March) than the dry (April–September) periods. The second step of baseflow response modelling shows that the system response is also fast and that simulated baseflow can capture some variations but not the peaks of the separated baseflow time series. The time series analysis indicates that components such as interflow and overland flow, contribute significantly to stream flow. They are somehow included as part of the separated baseflow, which is likely to be overestimated from hydrograph separation. The impulse response modelling approach from the groundwater flow perspective can be an optional method to estimate the baseflow, since it considers some level of the physical connection between river and aquifer in the subsurface. Further research is however recommended to improve the simulation, such as giving more weight to wells close to the river and adding more drainage dynamics to the model input.

Groundwater exists in underground aquifers and is largely hidden and intangible to water users. As such, groundwater models are one of the main vehicles through which groundwater is made legible. They are critical for water supply planning purposes. However, models are imperfect representations of limited data and contain much uncertainty, posing challenges for the water supply planning process. In this paper, we draw on a case from the Greater Chicago area to examine efforts by the authors and the Illinois State Water Survey to engage with local water managers to develop future water supply scenarios. Much of this area has been dependent upon the Cambrian-Ordovician Aquifer System for over 150 years. Over this period, water levels have declined by over 300 m and aquifers are expected to be unviable by 2030. Here we advance the growing field of participatory groundwater modelling (PGM) to identify forms of uncertainty and their influence on understandings of water supply and risk perceptions of depletion. Conceptually, we draw on the idea of models as world builders, where uncertainties are elucidated through knowledge production in the act of model building, while model development is simultaneously influenced by expectations, beliefs, and ambiguity surrounding those using the models. Through planning meetings and focus group discussions between groundwater modelers and water supply stakeholders, we identify four forms of interconnected uncertainty that hinder planning efforts: 1) hydrogeologic uncertainty, 2) modelling uncertainty; 3) water demand uncertainty; and 4) urban planning uncertainty. We describe our PGM efforts to reduce uncertainty and find stakeholder perceptions are as important as model uncertainties in water management decisions. Participatory modelling is effective in reducing and clarifying these four forms of uncertainty, particularly applied to short-term management decisions in a rapidly changing system. We conclude that future participatory modelling efforts need to focus on reducing communication barriers between scientists and local users.

Environmental tracers have been used to separate streamflow components for many years. They allow to quantify the contribution of water originating from different sources such as direct runoff from precipitation, subsurface stormflow or groundwater to total streamflow at variable flow conditions. Although previous studies have explored the value of incorporating experimentally derived fractions of event and pre-event water into hydrological models, a thorough analysis of the value of incorporating hydrograph separation derived information on multiple streamflow components at varying flow conditions into model parameter estimation has not yet been performed. This study explores the value of such information to achieve more realistic simulations of catchment discharge. We use a modified version of the process-oriented HBV model that simulates catchment discharge through the interplay of hillslope, riparian zone discharge and groundwater discharge at a small forested catchment which is located in the mountainous north of South Korea subject to a monsoon season between June and August. Applying a Monte Carlo based parameter estimation scheme and the Kling Gupta efficiency (KGE) to compare discharge observations and simulations across two seasons (2013 & 2014), we show that the model is able to provide accurate simulations of catchment discharge (KGE ≥ 0.8) but fails to provide robust predictions and realistic estimates of the contribution of the different streamflow components. Using a simple framework to incorporate experimental information on the contributions of hillslope, riparian zone and groundwater to total discharge during four sub-periods, we show that the precision of simulated streamflow components can be increased while remaining with accurate discharge simulations. We further show that the additional information increases the identifiability of all model parameters and results in more robust predictions. Our study shows how tracer derived information on streamflow contributions can be used to improve the simulation and predictions of streamflow at the catchment scale without adding additional complexity to the model. The complementary use of temporally resolved observations of streamflow components and modelling provides a promising direction to improve discharge prediction by representing model internal dynamics more realistically.

Aims The study of microbial inactivation rates in aquifer systems has most often been determined in aerobic and oxidized systems. This study examined the inactivation (i.e. loss of infectivity) of MS2, poliovirus type 1 (PV1) and Cryptosporidium parvum in an anaerobic and reduced groundwater system that has been identified as storage zones for aquifer storage and recovery (ASR) facilities. Methods and Results Anaerobic and reduced (ORP < −250 mV) groundwater from an artesian well was diverted to an above-ground, flow-through mesocosm that contained diffusion chambers filled with MS2, PV1 or Cryptosporidium parvum. The respective infectivity assays were performed on microorganisms recovered from the diffusion chambers during 30- to 58-day experiments. The net reduction in infectivity was 5.73 log10 over 30 days for MS2, 5.00 log10 over 58 days for PV1 and 4.07 log10 over 37 days for C. parvum. The best fit inactivation model for PV1 was the log-linear model and the Weibull model for MS2 and C. parvum, with respective inactivation rates (95% confidence interval) of 0.19 (0.17–0.21) log10 day−1, 0.31 (0.19–0.89) log10 day−1 and 0.20 (0.14–0.37) log10 day−1. Conclusions The groundwater geochemical conditions in this aquifer enhanced the inactivation of MS2, PV1, and C. parvum at rates approximately 2.0–5.3-fold, 1.2–17.0-fold, and 4.5–5.6-fold greater, respectively, than those from published studies that used diffusion chambers in aerobic-to-anoxic groundwater systems, with positive redox potentials. Significance and Impact of the Study Geochemical conditions like those in the aquifer zone in this study can naturally and significantly reduce concentrations of microbial indicators and pathogens of human health concern in injected surface water. Appropriate storage times for injected surface water could complement above-ground engineered processes for microorganism removal and inactivation (e.g. filtration, disinfection) by naturally increasing overall microorganism log-inactivation rates of ASR facilities.

Globally the land subsidence is a significant problem of the rapidly growing urban area. The factor responsible for the land subsidence caused by over-exploitation of the underground fluid such as water, petroleum, and gas respectively. In present study we present the result of detail investigation of active ground subsidance in New Delhi, National Capital Region (NCR). This area indicates a high rate of urban growth during the past decades. To analyze the land subsidence, we used multiple SAR sensor data and exploited the PS-InSAR technique. The data used for this study are Cosmo-skymed acquired between 08/06/2011 to 15/11/2017, Sentinel-1A-B (18-12-2014 to 27-11-2018), and ALOS PALSAR acquired between 19/01/2007 and 20/01/2011. These radar sensors operate in X, C, and L-band, which covers over ten years, from 2007 to 2018. The PSI results of Cosmo-skymed reveals that the Delhi NCR region has undergone an average deformation ± 15 mm/y, a maximum surface deformation observed from ALOS-PALSAR is 10 to 18 mm/y and the ground displacement observed from the SENTINAL-1A data is −2 to 16 mm/y. Groundwater level data also collected for the same period and a ground water level depletion compared with the subsidence. Monitoring land subsidence with ground-based conventional technology is time-consuming and can be carried out in a limited area due to the financial implication. PS-InSAR is an established method to detect the surface movement using the SAR sensor's time-series data. The result shows that a twenty centimeter of land subsidence is visible in some areas, validated with the collected ground evidence. The affected area is also showing resemblance to the groundwater depleting condition in those areas. This study also establish that multiple sensor data can be used to monitor the long term land subsidence.

This work presents the systematic investigation of K contents and stable K isotopic compositions of surface waters, groundwater, wastewaters, suspended particles, bed sediments, and fertilizers in the Upper Mun Rive catchment, northeast Thailand. This area is of particular interest because its abundant potash deposits and intensive agricultural activities and urbanization, therefore this will improve our understanding whether the K isotope is robust enough to resist evaporite dissolution and anthropogenic disturbances on tracing silicate weathering in the highly weathered tropical region. The dissolved loads in surface waters and shallow groundwater display the large variation in δ41Kdiss values from −0.54‰ to +0.09‰ relative to suspended particles (−0.60‰ to −0.41‰), river bed sediments (−0.54‰ to −0.47‰), the upper continental crust (UCC, −0.44 ± 0.05‰), which agrees with the fact that 39K is preferentially retained in weathering products during silicate weathering. The wet and dry seasons difference ranging from −0.05‰ to +0.10‰ δ41K, which is slightly greater than our long-term analytical uncertainty of ±0.06‰. There is likely a limited K input from evaporites dissolution due to weak correlation between δ41Kdiss values and Cl concentrations or Cl/K ratios in the UMR and world rivers, while a major tributary Takhong River is clearly influenced by the contribution of domestic sewage with lower δ41K and higher δ15N values. Based on a mass balance of K budge, the dissolved K in the UMR is mostly (>90%) derived from silicate weathering in the unpolluted area, this is consistent with previous studies of large river basins, and the evaporite dissolution and other non-silicate sources may not strongly influence dissolved K and δ41Kdiss values in rivers, even in evaporite-rich catchment. Therefore, K isotopes cannot be used as lithological tracers in catchments, rather the K isotopic fractionation mainly occurs during silicate weathering, such as the formation of secondary minerals which favor light isotope. Hence, the mechanism of K isotopic fractionation linked to secondary minerals K uptake needs further consideration. Overall, these results clearly show that K isotopes could be an ideal indicator to constrain silicate weathering processes and anthropogenic inputs at catchment scale.

Understanding soil water dynamics and their influencing factors is an important basis for formulating efficient water-use strategies aimed at alleviating water stress, especially in areas with water shortages. In this research, six plots with different densities were designed to systematically analyze the influences of Phragmites australis density and groundwater level on soil water in a semiarid wetland. (1) The Phragmites australis density had a negative influence on the soil water in the 0-40 cm profile and from April to August. (2) The Phragmites australis density had a positive effect on the annual variation degree of the soil water storage. The water replenishment could be implemented in April and June for low and high Phragmites australis densities, respectively. (3) The groundwater level had a significant influence on the soil water content of the 0-50 cm layer, and the change was positively correlated with the Phragmites australis density. The influence of groundwater level on soil water was more influential than that of Phragmites australis density. (4) The suitable average groundwater depth for the 0%, 20%, 40%, 60%, 80% and 100% densities were 76 cm, 63 cm, 50 cm, 37 cm, 23 cm and 10 cm, respectively. The suitable average densities of Phragmites australis for the groundwater depth of 35 cm, 40 cm, 45 cm and 50 cm were 62%, 55%, 47% and 40%, respectively. This research can provide a theoretical support for the management of Phragmites australis density and groundwater level in the Baiyangdian wetland.

The amount and composition of organic carbon are major controls on water quality and ecological processes in streams. In this study we explored the fate of the quantity of dissolved organic carbon (DOC) and the composition of dissolved organic matter (DOM) in an agricultural hillslope - stream network system. We conducted our study in the 66 ha HOAL (Hydrological Open Air Laboratory) in Lower Austria. We measured DOC of the soil eluates from different land use units, water samples from the stream and from seven tributaries, and estimated DOM components by fluorescent spectrophotometry and PARAFAC analyses. Soil DOC shows the highest concentrations in summer, but DOC concentrations in the tributaries are lower in summer than in winter by between 19% and 31%. DOM composition of the soil eluate differs between land use units. The forest site exhibits the largest fractions of humic-like fluorophores and less labile DOM. DOM composition in the tributaries is, in addition to DOC, controlled by soil moisture. We estimated the DOC import from the tributaries into the stream as 125 kg during base flow conditions in the period February to December 2017 and the instream DOC production as 38 kg, considering mass balance and exchange with groundwater. Six out of seven DOM components have a positive net production along the stream, only aliphatic DOM with low molecular weight is consumed (65 % of its input). These findings suggest that agricultural land use increases DOC input into streams and alters their DOM quality. Instream processes modify DOM quality over short distances.

Thermal water discharge within the gravity-driven groundwater flow system in the Alps and other similar areas around the world may be hidden in Quaternary deposits which, in these regions, often cover the regional aquifer. When thermal water drains into Quaternary deposits, the mixing of the deep thermal component and the cold shallow groundwater forms a thermal plume that extends parallel to the main groundwater flow in shallow system. In the Bled case study in Slovenia, the thermal water discharges from carbonate rocks into Quaternary glaciofluvial sediments, and as the Toplice spring at a rate of 5 l/s at an average temperature of 21.5 °C. Knowing the spatial extent and intensity of thermal outflow is essential to decision making related to the development and protection of this renewable resource. By approximating the thermal water outflow from a discharge zone as a planar source, a planar advective heat transport model can be used to evaluate its geometry and quantify rates. An analytical procedure follows rough assumptions leading to conservative results. Moreover, a numerical model using the FEFLOW code was applied for comparison with the simulations of the analytical model. The heat transport model was based on measured hydraulic parameters (e.g. groundwater levels) and borehole temperatures as well as on-site and international literature (e.g. dispersivity, thermal conductivity). Nine scenarios were applied accounting for different dimensions of the heat source and compared to the results of numerical simulations. Each scenario was verified by calculating the relative error between the analytical models and the measured borehole temperatures. The results confirm that the main outflow of thermal water can be determined using planar geometry, and is 200–300 m wide. The height of the thermal outflow zone is approximately 25 m, corresponding to the expected thickness of the direct contact between the fractured dolomite and the shallower Quaternary aquifer. Using the proposed widths and depths, the hidden natural thermal outflow rates are estimated at 57–86 l/s.

Aquifer compaction due to excessive withdrawal of groundwater has led to land subsidence in many regions worldwide. Aquifer-System compaction is a function of the piezometric head, the depth of the total aquifer system and the hydrogeological characteristics of the aquifer. The present work is an attempt to characterize the land subsidence caused due to aquifer system compaction in parts of Mehsana city, Gujarat during two individual study periods of 2007 to 2011 and 2012 to 2017. Studies were undertaken for an observation well for which complete time series piezometric water level data was available for both pre and post-monsoon seasons. Elastic and Inelastic compaction were calculated from the piezometric data. The thickness of the aquifers and confining layers were taken from secondary data sources. The results show that there has been a considerable cumulative subsidence in the region during the period 2007 to 2011 with an average rate of 1.18 cm/yr. which declined to an average rate of 0.68 cm/yr. during 2012–2017. Such studies prove useful for monitoring land deformations due to excessive pumping as well as administration of groundwater resources especially in regions facing heavy declines of ground water.

Improving our understanding of hydrogeological processes on the western flank of the central Andes is critical to communities living in this arid region. Groundwater emerging as springs at low elevations provides water for drinking, agriculture, and baseflow. However, the high-elevation sources of recharge and groundwater flow paths that convey groundwater to lower elevations where the springs emerge remain poorly quantified in the volcanic mountain terrain of southern Peru. In this study, we identified recharge zones and groundwater flow paths supporting springs east of the city of Arequipa and the potential for recharge within the high-elevation closed-basin Lagunas Salinas salar. We used general chemistry and isotopic tracers (δ18O, δ2H, and 3H) in springs, surface waters (rivers and the salar), and precipitation (rain and snow) sampled from March 2019 through February 2020 to investigate these processes. We obtained monthly samples from six springs, bimonthly samples from four rivers, and various samples from high-elevation springs during the dry season. The monthly isotopic composition of spring water was invariable seasonally in this study and compared to published values from a decade prior, suggesting that the source of recharge and groundwater flow paths that support spring flow is relatively stable with time. The chemistry of springs in the low-elevations and mid-elevations (2500 to 2900 m a.s.l.) point towards a mix of recharge from the salar basin (4300 m a.s.l.) and mountain-block recharge (MBR) in or above a queñuales forest ecosystem at ∼4000 m a.s.l. on the adjacent Pichu Pichu volcano. Springs that clustered along the Río Andamayo, including those at 2900 m a.s.l., had higher chloride concentrations, indicating higher proportions of interbasin groundwater flow from the salar basin likely facilitated by a high degree of faulting along the Río Andamayo valley compared to springs further away from that fault network. A separate groundwater flow path was identified by higher sulfate concentrations (and lower Cl-/SO4-2 ratios) within the Pichu Pichu volcanic mountain range separating the city from the salar. We conclude that the salar basin is not a hydrologic dead end. Instead, it is a local topographic low where surface runoff during the wet season, groundwater from springs, and subsurface groundwater flow paths from the surrounding mountains converge in the basin, and some mixture of this water supports groundwater flow out of the salar basin via interbasin groundwater flow. In this arid location, high-elevation forests and the closed-basin salar are important sources of recharge supporting low-elevation springs. These features should be carefully managed to prevent impacts on the down-valley water quality and quantity.

La Trobe University Faculty of Science, Technology and Engineering Murray Darling Freshwater Research CentreMDFRC item.Despite the critical role of water movement in the nutrient dynamics of wetlands, few wetland studies of nutrient imports, exports and cycling have been based on comprehensive water balance studies. In particular, many investigations have underestimated the importance and role of groundwater movement. Nutrient loads entering and leaving a 2 ha reed swamp in the Kiewa Valley, North-east Victoria showed the swamp to be a nutrient source within the landscape under both base flow and storm flow conditions. During a dry period between February 1994 and January 1995 the wetland itself exported 230 kg of Total Nitrogen (115 kg ha−1 yr−1) and 24 kg of Total Phosphorus (12 kg−1 ha−1 yr−1). Investigations confirmed that the wetland was a significant discharge area, and that groundwater accounted for 97% of the surface water and 50% of the Total Nitrogen and Total Phosphorus load leaving the system. A further 30% of Total Nitrogen and 26% of Total Phosphorus leaving the wetland was not attributable to rain/dust, surface water inputs or groundwater, and most likely resulted from the flushing of previously stored nitrogen and phosphorus. A fire which burnt most of the wetland area in September 1994 had little immediate impact on nutrient loads leaving the system. The study illustrates the complexity of assessing the nutrient dynamics and hydrology of natural wetlands, and raises questions with respect to the use of such systems for the interception of diffuse source nutrient loads within rural catchments.

The subsurface environment includes soils that support the world's forests, grasslands, and agricultural crops, and water-saturated aquifers that supply water for drinking, farming, and industry. This chapter covers the fundamental chemical, biological, and transport processes of natural subsurface systems, and the behavior of both organic and inorganic contaminants that enter the subsurface environment. The chapter builds on material presented in Chapter 2 for the many processes that are common to both surface waters and groundwaters. In addition, this chapter covers tools and topics that become especially important in soils and aquifers, such as models for flow in both saturated and unsaturated porous media, well design and analysis, retardation of both organic and inorganic chemicals, biofilms, and remediation techniques for contaminated soils and groundwaters.

The lowland floodplains of the Lao People’s Democratic Republic (PDR) experience prolonged dry seasons characterized by pronounced and common water scarcity, with water supplies increasingly offset with groundwater. Groundwater assessment is still at a very rudimentary stage in Laos, making it difficult to ensure that new water supplies are developed successfully and managed sustainably. The goal of this study is to apply a variety of field hydrogeophysical techniques to this problem and in the process help build and strengthen human and institutional capacity with various stakeholder groups from the government, the university, and the community. The study area focuses on a cross section of the Vientiane Plain (VP) in the Lower Mekong Basin in central Lao PDR to identify and characterize the hydrogeology and groundwater quality. The research collaboration has built and strengthened stakeholder capacity by developing and progressing the hydrogeologic field mapping of the VP. It has provided local undergraduate and postgraduate training opportunities using several different near-surface geophysical and hydrogeologic techniques, some previously untested in Lao PDR. At one of the survey sites, the geophysics has indicated the spatial extent of the shallow aquifer and in the process identified an extensive conductive zone, interpreted as more saline groundwater. Any groundwater development within this or similar zones is likely to be unsuitable as sources for drinking and irrigation water. Engagement with the local village authorities has supported local community members and government to expand groundwater development for rural water supplies. Access to groundwater as a reliable, safe, and secure resource provides an opportunity for strengthening the resilience of farmers to changing climatic conditions. Participatory research collaboration of this kind can positively enhance data and build capacity, which is a required precursor for improving knowledge and management of poorly understood groundwater resources.

Observation of dispersion in field situations has left three issues that may be better understood by applying advective transport phenomena. (1) In some experiments, the longitudinal dispersivity becomes constant with increasing pathlength and in other cases it remains growing. (2) Dispersivities reported from multiple comprehensive observations at a single site differ at similar pathlength in some cases more than a factor two. (3) The observed difference between the plume fronts and plume tails is not represented in the reported parameters. The analytic equations for advective transport phenomena at macro-scale of (De Lange 2019) describe the thickness of the affected flow-tube and the spread of the plume front and tail. The scale factor defines the size of the averaging domain and so of the initial phase. The new macro-scale correlation coefficient relates the growth of the longitudinal dispersivity beyond the initial phase to the aquifer heterogeneity. Using stochastic parameters for the aquifer heterogeneity, the parameters are quantified at fourteen field experiments in the USA, Canada and Europe enabling the comparison of calculated and reported final dispersivities. Using the quantified parameters, 146 reported and calculated dispersivities along the traveled paths show a good match. A dispersivity derived from the local plume growth may differ a factor of two from the aquifer-representative value. The growths of plume fronts and tails between two plume stages are assessed in fourteen cases and compared to calculated values. Distinctive parameters for the plume front and tail support better understanding of field situations. A user-ready spreadsheet is provided.

High-Temperature Aquifer Thermal Energy Storage (HT-ATES) is a sustainable approach for integrating thermal energy from various sources into complex energy systems. Temperatures ≥45°C, which are relevant in impact zones of HT-ATES systems, may dramatically influence the structure and activities of indigenous aquifer microbial communities. Here, we characterized an acetate-mineralizing, sulfate-reducing microbial community derived from an aquifer and adapted to 45°C. Acetate mineralization was strongly inhibited at temperatures ≤25°C and 60°C. Prolonged incubation at 12°C and 25°C resulted in acetate mineralization recovery after 40-80 days whereas acetate was not mineralized at 60°C within 100 days. Cultures pre-grown at 45°C and inhibited for 28 days by incubation at 12°C, 25°C, or 60°C recovered quickly after changing the temperature back to 45°C. Phylotypes affiliated to the order Spirochaetales and to endospore-forming sulfate reducers of the order Clostridiales were highly abundant in microcosms being active at 45°C highlighting their key role. In summary, prolonged incubation at 45°C resulted in active microbial communities mainly consisting of organisms adapted to temperatures between the typical temperature range of mesophiles and thermophiles and being resilient to temporary heat changes.

In the present study, an attempt is made to delineate groundwater potential zones in Lower Rihand River Basin using remote sensing, GIS, and Analytical Hierarchical Process (AHP). Multiple data, viz. lithology, lineament density, geomorphology, slope, soil, rainfall, drainage density, relief, landuse/landcover were considered for delineating the groundwater potential zones. All nine thematic layers were prepared using remote sensing data on GIS platform. After that, weights were assigned to different layers and the features within them using a pairwise comparison matrix through the Analytical Hierarchical Process. The weights obtained were tested for their consistency using the consistency index and consistency ratio. A final weighted map was then obtained by multiplying each thematic layer’s weights with the weights of features within them and adding them. Based on this final weighted layer, the basin was categorized into very poor, poor, moderate, good, very good groundwater potential zones. The maximum area (49.22%) is under poor groundwater potential zone followed by moderate zone (26.17%), very poor (12.53%), good (11.77%), very good (0.31%). Results obtained have been validated using pre-monsoon and post-monsoon 10 years average water depth and seasonal fluctuation of various observation wells. Sensitivity analysis using map removal method is performed to assess the most influential parameters, geology, geomorphology, lineament density are the most influential. Overall results prove the efficacy of the use of geospatial technology in combination with AHP in the delineation of underground water potential zones.

The study area is located in the eastern part of the Diyala Governorate close to the Iraqi-Iranian border. This study was set to investigate the hydrogeological calculations of northeast of Qazaniyah wells where the groundwater moves in directions of from the northeastern parts towards the southwestern par, that is, the same direction of the topography and the same direction of the tendency of the layers t. The study‘s region is characterized by visible geological layers or those that can be penetrated to a reasonable depth by wells which are sedimentary rocks deposited in continental or semi-continental conditions in the bays. From the study of the hydraulic properties of the two hydrogeological and exemplary systems, the values of transmissivity, permeability and storage coefficient are ranged between 1.94- 5.73 m2/day, 1.02- 3.92 m/day and1.40 x 10-5- 2.62 x 10-4, respectively. While the estimated value of transmissivities, which are obtained from specific capacity, ranged between 6.27- 8.62 m2/day. This variance in the values indicates the broad differences in the values Lithology of aquifers, which seems to be influenced by the strength and the number of fractures and joints.

Forest degradation is a worldwide problem, although its causes vary due to geographical and climatic differences and man-made causes. In recent years, the Robinia pseudoacacia forest in the Yellow River Delta has suffered severe degradation. The causative mechanisms were investigated in the field over two years, and the results show that increased forest degradation was reflected by increased tree mortality, high leaf and soil sodium salt levels and groundwater depth. Average tree diameters decreased, and leaf chlorophyll and soil microbial contents decreased. Redundancy discriminate analysis (RDA) showed that degradation of the forest was correlated positively with soil salt content, but negatively with groundwater depth. Correlation analysis showed that 0.79%–0.95% soil salt content and above 1.20 m groundwater depth caused the death of R. pseudoacacia trees due to localized anthropogenic economic activities, such as rice farming, that disrupted the original water–salt balance. Measures are recommended to prevent further degradation and restore degraded forests.

Groundwater accounts for 30% of the world drinking water resources and is rarely taken into account in climate assessments. Climate change affects groundwater levels and regimes, but there is very little specific research on the future impacts of climate change on groundwater. This study examines data from 15 groundwater wells of various ages for the period from 1965 to 2015. To obtain reliable data, an analysis was made of the groundwater level changes in the upper hydrodynamic zone, which is not disturbed by anthropogenic activity. A statistically significant increase in the average annual groundwater levels in the study area was observed, in agreement with data indicating an increase in groundwater runoff in the winter season for large and medium rivers in the region. To explain the revealed changes in the groundwater levels, an analysis of the characteristic climatic changes (air temperature and amount of precipitation) and the groundwater runoff was performed. In winter, the unfrozen moisture content in the soil has increased; accordingly, groundwater recharge and groundwater levels have increased. Meanwhile, in summer, an increase in evaporation from the drainage basin has occurred as a result of the increasing air temperature. To some extent, this compensates for the changes in the annual runoff and groundwater levels that are hydraulically connected to the rivers.

Export of dissolved organic carbon (DOC) from riparian zones (RZs) is an important component of temperate catchment carbon budgets, but export mechanisms are still poorly understood. Here we show that DOC export is predominantly controlled by the microtopography of the RZ (lateral variability) and by riparian groundwater level dynamics (temporal variability). From February 2017 until July 2019 we studied topography, DOC quality and water fluxes and pathways in the RZ of a small forested catchment and the receiving stream in central Germany. The chemical classification of the riparian groundwater and surface water samples (n=66) by Fourier transform ion cyclotron resonance mass spectrometry revealed a cluster of plant-derived, aromatic and oxygen-rich DOC with high concentrations (DOCI) and a cluster of microbially processed, saturated and heteroatom-enriched DOC with lower concentrations (DOCII). The two DOC clusters were connected to locations with distinctly different values of the high-resolution topographic wetness index (TWIHR; at 1 m resolution) within the study area. Numerical water flow modeling using the integrated surface–subsurface model HydroGeoSphere revealed that surface runoff from high-TWIHR zones associated with the DOCI cluster (DOCI source zones) dominated overall discharge generation and therefore DOC export. Although corresponding to only 15 % of the area in the studied RZ, the DOCI source zones contributed 1.5 times the DOC export of the remaining 85 % of the area associated with DOCII source zones. Accordingly, DOC quality in stream water sampled under five event flow conditions (n=73) was closely reflecting the DOCI quality. Our results suggest that DOC export by surface runoff along dynamically evolving surface flow networks can play a dominant role for DOC exports from RZs with overall low topographic relief and should consequently be considered in catchment-scale DOC export models. We propose that proxies of spatial heterogeneity such as the TWIHR can help to delineate the most active source zones and provide a mechanistic basis for improved model conceptualization of DOC exports.

An effective framework for groundwater modelling is a precursor for sustainable management of regional water resources. Owing to the coexistence of contrasting hydrogeological units, modelling of groundwater flow through multi-layered fractured aquifers such as the granitic aquifers found in the Deccan region of India, requires an accurate estimation of hydraulic parameters and delineation of preferential flow-paths. There are several approaches towards this goal. This study compares seven methods by evaluating their abilities to reconstruct the hydraulic parameter distributions of a synthetic two-dimensional multi-layered aquifer analogue whose construction is based on pre-existing field data. The methods studied are (1) a homogeneous parameter model; (2) a single-hole equivalent model that provides an average of local-scale estimates; (3) a geostatistical single-hole model that involves kriging of the single-hole local-scale estimates; (4) a uniformly placed pilot-point model; (5) the sequential successive linear estimator (SSLE) algorithm; (6) a geostatistical-guided pilot-point model; and (7) a new approach that involves a pilot-point model guided by the results of the SSLE algorithm. The results of the inversions are compared visually using tomograms and by a statistical analysis of the time-drawdown datasets obtained from validation wells that were not used for calibrating the models. The uniform pilot-point model performed significantly better than the other methods. The SSLE algorithm recovered the fracture connectivity pattern with significant fidelity. Using the SSLE algorithm as a guide improved the parameter estimation at the cost of the fracture connectivity pattern.

In this article, a part of Wadi Al-Sahba, Saudi Arabia, is tested for revealing and modelling potential area of groundwater using integrated data derived from remote-sensing, geology and hydrology ...

Nitrogen (N) legacies have built up in anthropogenic landscapes over decades of agricultural intensification, and these legacies lead to time lags in water quality change measurable even beyond the moment of application of N. It is important to understand these legacies to quantify the relationship between N inputs and N concentrations in streams and implement best management practices for water quality improvement; however, little is known about the magnitude of legacies in various landscape elements like soils and groundwater. Here, we have used the ELEMeNT (Exploration of Long-tErM Nutrient Trajectories) model to explore the buildup and depletion of N legacies over a 216-year period, across the Mondego River Basin, a 6645-km2 watershed in Portugal, where human interventions have considerably changed the characteristics of the basin to prevent floods and improve farming conditions in recent decades. The results show that the increase in the amount of inorganic fertilizer applied was the main driver for the anthropogenic N loads in the watershed from 1950 until the beginning of the 1990s. The N inputs have been decreasing since then, but N loads in the river did not document any decrease till the 1990s; after which there was a decline. This time lag between the N inputs to the watershed and the N loads in the river (about two decades) is a function of accumulation of N legacy.

Global warming, which has been observed in the world and Ukraine in particular in recent decades, may lead to a decrease in surface and groundwater. In addition, the high level of groundwater pollution and the policy of water purification is a matter of concern. Thus, the question of finding additional and alternative sources of drinking water today is highly urgent. A significant percentage of prospecting works of the last century was devoted to discovering the groundwater fields in fractured crystalline rocks of the Ukrainian Shield. As a rule, the productivity of wells of these formations did not have high flow rates, so even now, mostly the aquifers in sedimentary deposits have been exploited. The low productivity of most wells in water-bearing fractured rocks is associated with the unknown degree of fracturing of the crystalline massif: it is difficult to determine the pathways of groundwater inflow into the fracture system and, accordingly, it is not easy to justify the exploitable groundwater reserves. In this paper, using the groundwater flow model of the Zhashkiv groundwater deposit, it is considered an increase of the productivity of water intake wells in the water-bearing crystalline rocks due to the increasing degree of their fracturing by an explosion. Thus, in hydrogeology, this technique is known when trying to increase the permeability in the near-borehole space, but as a method of artificial recharge of aquiferous crystalline rocks is used very rarely. The paper also examines typical water intakes conditions in fractured crystalline water-bearing rocks, which can be recommended for increasing their productivity by the blasting method. The results indicate that an artificial increase in fracturing degree can have a significant effect on increasing the productivity of water intakes. The basic methods of using explosives, as an example of an artificial increase in fracturing degree, in solving hydrogeological problems and the mechanisms of fractures’ formation during the action of blasting are considered.

Freshwater wetlands located in dryland environments are characterised by high evapotranspiration rates and frequent periods of desiccation, which strongly influence the water chemistry and solute budgets of these systems. The transpiration of groundwater, especially by trees, is an important mechanism through which dryland wetlands can lose water. This process can lead to groundwater salinization and the precipitation of substantial quantities of minerals within the soil, the accumulation of which can have profound consequences for wetland structure and function. This paper aims to bring together current knowledge on the processes that result in solute accumulation and chemical sedimentation which assist in maintaining freshwater conditions in many seasonal dryland wetlands. Examples from central and southern Africa, Australia and South America are presented to illustrate the geomorphically diverse settings under which chemical sedimentation can occur, and the importance of these processes for the resilience and longevity of dryland wetlands. We show that the localised development of saline groundwater and subsurface precipitation of minerals within soils can play a key role in creating and maintaining the habitat diversity of dryland wetlands. Wetland vegetation localises the accumulation of deleterious constituents, thereby preventing widespread salinization and playa-lake formation, and thus ensuring that the bulk of the surface water remains fresh. Although such processes remain widely understudied, we suggest that chemical sedimentation could be a common phenomenon in many dryland wetlands and have important implications for the future management of these ecosystems.

Undergraduate students may possess underdeveloped knowledge about water systems, particularly groundwater. The use of models and modeling have been employed in undergraduate classrooms to support s...

Detailed investigation on hydrogeochemistry of hard rock terrains is important to identify the major geochemical processes and the source of ionic constituents in groundwater. The present study is carried out to understand the hydrogeochemistry of groundwater resources and the major hydrogeochemical processes, controlling the concentration of major ions in groundwater in the Kallada River Basin (KRB), South India. About 166 groundwater samples were collected from KRB during pre- and post-monsoon of 2016 for hydrogeochemical analysis. Most of the groundwater samples in KRB were within permissible limits of drinking water quality. The dominant groundwater types during pre-monsoon were Ca2+-Mg2+-Cl− which was changed to Na+-Cl− during post-monsoon. This is supported by the inverse relationship of depth of wells and change in EC during pre- and post-monsoon periods. Rock-water interaction processes such as reverse ion exchange and silicate weathering are major geochemical processes responsible for the hydrogeochemical signatures of KRB. The shallower wells (< 10 m) show strongest relation with the water types Na+-HCO3− and Ca2+-Mg2+-Cl− which have been changed to Na+-Cl− and Ca2+-Mg2+-HCO3− during post-monsoon. However, in deeper wells, Na+-Cl− is the dominant type of water during both seasons. The hierarchical cluster analysis displays different hydrogeochemical associations representing diverse physicochemical parameters both spatially and temporally. This study could shed light on diverse hydrogeochemical processes which are responsible for the hydrogeochemistry in KRB. Major hydrogeochemical processes in the Kallada River Basi

Seawater intrusion in coastal aquifers is a major concern due to geogenic and anthropogenic activities leading to declining groundwater quality. The present study focuses on deciphering the sea water intruded zones and its extent in the Quaternary alluvial aquifer system in the coastal belt of Digha, West Bengal, India. In this study, 36 groundwater samples were collected during pre-monsoon (2020). Subsequently, an integrated approach of hydrogeological, hydrogeochemistry, bulk magnetic susceptibility, isotopic, multivariate statistical, and geochemical modeling is adopted. Spatial distribution maps of hydrological parameters (salinity, conductivity, TDS) and major ion concentration (Na+, K+, Ca2+, Mg2+, Cl−, SO42−, F−, and Br−) suggest that the northern, south-west, and eastern parts of the study area are largely affected by saltwater intrusion and are corroborated with seawater mixing index (SMI). Based on sodium adsorption ratio (SAR), sodium percentage (Na%), and Permeability index (PI) distribution maps, the same locations are identified under critical condition for the suitability of groundwater for irrigation. The order of concentration of cations and anions in the water samples are Na+ > Ca2+ > Mg2+ > K+ and HCO3− > SO4− > Cl− > Br− > F− respectively. Piper diagram shows three principal hydrochemical water types with water composition changes from fresh (86%) to saline water mix (14%). The hydrochemical facies evolution diagram depicts 81% of water samples are in the freshening phase, and 19% are in the intrusion phase. The various bivariate plots revealed that ion exchange, reverse ion exchange, silicate weathering, seawater mixing, and anthropogenic inputs are the governing factors that control groundwater evolution. R-mode factor analysis, principal component analysis (PCA), and agglomerative hierarchical cluster (AHC) also indicate the influence on groundwater from seawater mixing and/or seawater intrusion. The superlativeness of bulk magnetic susceptibility (χ) analysis of water samples in delineating seawater intruded zones is elaborated. Saturation index (SI) shows that groundwater is saturated (> 0) with calcite, dolomite, and aragonite, plausibly due to seawater ingression. Stable isotopic analysis of δ2H (− 53.979 to − 16.9578‰) and δ18O (− 7.00183 to − 1.37 ‰) suggests precipitation recharge/paleo-water at some locations and evaporation enrichment of groundwater. It is recommended to increase groundwater recharge, reduce groundwater extraction at critically affected locations, and have regular monitoring and management to control seawater intrusion.

Groundwater is the biggest freshwater reservoir in the world. More than 95% of the unfrozen water comes from groundwater. Factors responsible for groundwater consumption by rice growers have been included in the study. For the study, Purba Barddhaman district was selected purposively considering the pattern of agriculture and extent groundwater use in the state. One community development block from the district has selected based on crop diversity, type of irrigation, amount of water extraction for irrigation purposes. From the selected block a big parcel of cultivating land (Math) were again selected randomly keeping the consideration of homogeneity in lad type, soil type, type of crops, variety and seasons. Farmers’ knowledge level, farmers’ attitude towards irrigation, economic motivation, improved water extraction mechanism and method of irrigation are the major contributing factors in predicting the amount of groundwater consumption when crop and land situation are constant.

Shared groundwater resources between Mexico and the United States are facing unprecedented stressors. We reflect on how to improve water security for groundwater systems in the border region. Our reflection begins with the state of groundwater knowledge, and the challenges groundwater resources face from a physical, societal and institutional perspective. We conclude that the extent of ongoing cooperation frameworks, joint and remaining research efforts, from which alternative strategies can emerge, still need to be developed. The way forward offers a variety of cooperation models as the future offers rather complex, shared and multidisciplinary water challenges to the Mexico–US borderlands.

Geoelectrical data was acquired using Wenner array over 23 sites with constant electrode separation of 70 m over Chikotra Basin, Dist. Kolhapur, Maharashtra (India). The spatial variation maps of resistivity at depths from 2 to 70 m were plotted using Inverse Distance Weighted (IDW) technique for interpolation in ArcGIS 10.5 to obtain a comprehensive subsurface hydrogeological representation of the study area. High resistivity (>140 Ωm) up to 20m depth, indicative of massive basalts is deciphered towards the NE part of the study area, while the NW sector reveal low resistive (up to 40 Ωm) feature at shallow depths due to fractured basalts, thus conducive for groundwater exploration. Alluvium deposits and columnar jointed basalts in the central part depicts as EW trending conductive (< 30 Ωm) feature suggesting prospective groundwater zone. Low resistivity (6-50 Ωm) from shallow to deeper depths (up to 70m), in the southern region can be identified as potential aquifer system. Longitudinal geoelectric cross-sections are generated over four profiles to identify the lateral and vertical variation in geology and groundwater potential zones. The western and central part of the northern profile (A-A') is highly resistive with resistivity of the order of 80-140 Ωm constituting compact basalts and thus devoid of water. Low resistive zone (30 Ωm) in the eastern part suggests groundwater at shallow depths. Low resistivity zones ranging from 10-50 Ωm is observed at different depth levels over the central profile (B-B') which can be tapped for groundwater exploitation. Several sites over profiles C-C' and the southern-most D-D' suggest promising aquifer zones. Because defining prospective groundwater zones in hard rock terrain is difficult, it’s crucial to look into a river basin’s hydrogeological arrangement early on in the planning process.

The Schlumberger and Wenner Electrical Resistivity Survey techniques have been used in comparison for the determination of groundwater potential in District Rawalakot, Azad Jammu and Kashmir. The terameter SAS4000 with accessories was used for data acquisition. The data were processed by employing IPI2WIN software to determine the depth, thickness and true resistivity of the subsurface layers. The present study indicated the subsurface depth coverage of Schlumberger configuration is greater than Wenner configuration. The apparent resistivity maps using both Wenner and Schlumberger techniques at the same locations have been prepared at 3m, 4m, 9m, 10m, 27m, 30m, 50m, 51m, 100m, and 150m depths respectively for groundwater assessment. The differences in resistivity contour closures, in both types of maps, arise due to lateral variations of subsurface lithology. Longitudinal conductance, transverse resistance and anisotropic maps were also prepared. The different contour closures in the Wenner map were due to mixed lithology of alluvium with variable water contents. The subsurface geology i.e. clay, sandstone boulder clay, and dry sandy soil were interpreted which are in close agreement with the surface geology of the area. The aquifers of the project area are designated as confined and unconfined good water potential indicated by low values of resistivity. The water-bearing strata consist of sand, gravel, boulder clay and sandy clay.

The establishment of reliable age in the lake sediment profile mainly depends on the AMS 14C dating technique. However, the presence of the 14C lake reservoir effects (LREs) restricted for using radiocarbon dating in lake sediment, especially in dry and cold areas with a scarce plant cover in the Qinghai-Tibet Plateau. Hence, the discussion of influence factors of LREs is crucial. This paper selected 15 lakes (17 sediment and 3 plant samples) in the Qinghai-Tibet Plateau to examine the distribution characteristics of the modern LREs and their main influencing factors. In our study area, 14 lakes were all affected by the LREs. The minimum 14C year is 5900 a BP towards the deep water area, whereas the maximum 14C year is up to 7185 a BP in the margins of Lake Heihai. The maximum 14C year is up to 7750 a BP, and the minimum 14C year is present-day carbon in the 15 lakes. One further study indicated that the LRE differences in individual lake are mostly owing to the contribution of exogenous carbonate. The results displayed that the LREs tended to increase with the increase of the salinity, moreover, the LREs of saltwater lakes or salt lakes were significantly larger than freshwater lakes due to the possible supply of old total dissolved inorganic carbon with a long residence time in the lakes. Moreover, the contribution of calcite played a significant role on the LREs. Additionally, the LREs differences are affected by the source of organic matter. The lake with groundwater supply shows large LRE due to likely being influenced by crustal and ancient CO2 uprising.