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Recent eruptions from volcanoes with no previously known historical activity in Chile and Indonesia have raised the importance of the early identification of potentially active centers for the purpose of hazard assessment. Here we bring radiometric evidence (C-14,Ar-39-Ar-40) of previously unrecognized but significant magmatic activity at partly eroded Imbabura volcano (Ecuador) in late Pleistocene to early Holocene times, on whose perimeter live more than 300,000 persons. Following an effusive stage from 50 to 30 ka with the emplacement of andesitic lava flows on different flanks of its edifice, the activity became explosive with the generation of andesitic block-and-ash flows on its eastern side, beginning at similar to 35 ka cal BP. Subsequently a flank collapse associated with a volcanic blast occurred on the volcano's SW flank at similar to 30 ka cal BP. The resulting debris avalanche and blast breccias cover an area now heavily populated around San Pablo Lake and its source was later concealed by successive dome building episodes at Huarmi which produced similar to 2.8 km(3) of silicic andesite. Renewed dome activity at the edifice's Taita summit occurred at similar to 17 ka cal BP and continued intermittently into early Holocene times, as indicated by pyroclastic flow deposits overlying a palaeosoil dated at similar to 9 ka cal BP. In summary, this study reveals an eruptive behavior characterized by a low recurrence rate but with quite large eruptions, a pattern which is also observed at other silicic volcanoes of Ecuador's Western Cordillera. It is now imperative to reconsider the origin and source of the many tephra layers catalogued in Holocene lacustrine sediments in the Imbabura area. Tephra and lava volume estimates for Imbabura volcano converted to Dense Rock Equivalent values yield a minimum magmatic output rate of 0.13 km(3)/ka in the past 35,000 years, which argues for sustained magma production for this volcano in recent geological times. The lmbabura example thus raises the question of how to improve population preparedness for volcanoes with infrequent eruptions, and how to guide authorities' decisions concerning the development of urban areas and infrastructures near presently inactive but potentially highly dangerous volcanoes.

suggesting that slab melts can be responsible for the metasomatism Extensive sampling of the Antisana volcano in Ecuador (Northern of the mantle wedge beneath the NVZ in Ecuador. If mantle Volcanic Zone of the Andes) has revealed the presence of adakite-like convection can drag down this modified mantle beneath Antisana rocks throughout the edifice, i.e. rocks with geochemical characteristics volcano, destabilization of metasomatic amphibole at appropriate close, but not identical, to those of slab melts. Two main volcanic pressures in this modified garnetiferous mantle can adequately explain groups have been distinguished, characterized by two distinct evoluthe formation and the geochemical features of Antisana lavas. tionary trends. The AND group, mostly composed of andesites, shows the clearest adakitic characteristics such as high La/Yb and Sr/Y ratios and low heavy rare earth element (HREE) contents. The CAK group, composed of high-K andesites and dacites, displays

New geochemical and geochronological data on the Miocene–Pliocene Quimsacocha volcanic center (QVC) have led to the recognition of adakitic lavas generated by slab melting related to the flat slab subduction in southern Ecuador and northern Peru. The QVC, located in the presently inactive southern part of the Ecuadorian arc, was built up during three distinctive volcanic phases. The first phase generated a basal edifice with mainly andesitic lava flows, while the second phase is characterized by the emplacement of cryptodomes, domes and related outflow breccias comprised of andesites and some dacites. The last phase released rhyolitic ignimbrites associated with the formation of a large caldera, which was later partly filled by dacitic–rhyolitic domes. Geochemical data for the QVC indicate higher Al2O3, TiO2, Na2O, Zr and Sr contents and lower Fe2O3*, MgO, Y, MREE and HREE abundances, compared to other eruptive rocks of the Plio–Quaternary volcanic front of Ecuador. Such geochemical features, as well as the frequent presence of an associated epithermal gold deposit, are characteristic of the involvement of slab melts, also known as adakites [1] , [2] , in the generation of these magmas. After a calc-alkaline arc magmatism phase, slab horizontalization – in response to the subduction of a buoyant oceanic plateau – results in increased involvement of a slab melting component in the magmas produced. However, pristine adakites were generated and emplaced during a relatively short period, as indicated by zircon fission-track ages. Then volcanic activity stopped and a volcanic gap formed. The identification of these adakites, their location and age support a model of slab melting associated with flat slab subduction [M.A. Gutscher et al., Geology 28 (2000) 535–538].

L'étude des laves du volcan Antisana (Equateur) révèle la présence de laves calco-alcalines, enrichies en Sr, Nb, Ti et P par rapport à des laves calco-alcalines normales. Certaines laves montrent également un appauvrissement net en terres rares lourdes, typique des adakites. Cependant, les conditions nécessaires à la genèse d'adakites n'étant pas réunies sous l'Antisana, nous proposons que ces roches à caractère adakitique soient issues de la fusion partielle d'un manteau hydraté, préalablement métasomatisé de façon hétérogène par des liquides adakitiques issus de la plaque plongeante. (Résumé d'auteur)

Le volcanisme récent de l'arc insulaire des Nouvelles Hébrides (Vanuatu) est influencé par sa collision avec la ride d'Entrecasteaux. La géochimie des éléments en trace et l'étude des compositions isotopiques des laves de cet arc permettent de nuancer les interprétations antérieures faisant état d'un gradient de composition, au nord et au sud de la zone de collision. Les données géochimiques montrent une variation nette, évoluant de compositions calco-alcalines à l'aplomb de la zone de collision à tholéiitiques de part et d'autre. Par contre, les signatures isotopiques varient de façon progressive, définissant des sources de moins en moins enrichies à des distances croissantes de la zone de collision, évoluant vers des sourcse "normales" de type MORB. Ce gradient isotopique suggère l'existence de deux contaminations, l'une magmatique, par une lithosphère ancienne au front de la zone de collision (variation du 206Pb/204Pb), et l'autre mantellique, par un manteau de type "enrichi" (type Dupal) débordant largement cette dernière. (Résumé d'auteur)

Le Huaynaputina (Pérou méridional) comprend trois cratères au fond d'une caldeira d'avalanche éventrant un strato-volcan érodé, situé sur le rebord est d'un haut plateau. Il a été le site de la plus volumineuse éruption explosive (indice d'explosivité volcanique 6) de l'histoire dans les Andes centrales. L'épisode éruptif débuta le 19 février 1600, dura au moins 17 jours et mit en place, dans l'ordre stratigraphique : une retombée plinienne d'environ 8 km3 de lapilli ponceux et cendres dacitiques sur une zone supérieure ou égale à 85 000 km2; plusieurs retombées mineures de cendres; des déferlantes pyroclastiques précédant et intercalées dans des ignimbrites de 1 km3 environ, celles-ci étant canalisées dans toutes les vallées drainant le haut plateau; une retombée de cendres co-ignimbritiques,; une retombée très riche en cristaux, puis un dépôt cendreux. En outre, d'autres ignimbrites résultent du remaniement des téphras sur le plateau et dans les vallées; des coulées de débris ont dévasté la vallée du Tambo sur 120 km jusqu'à l'océan Pacifique. (Résumé d'auteur)

Ambrym volcano lies in the central part of the New Hebrides island arc near the latitude where the D'Entrecasteaux Zone is colliding with the arc. It is a 35 km X 50 km, mainly basaltic stratovolcano constructed in four distinct parts: (i) well-preserved remnants of an old edifice in the north; (ii) a NlOO"-aligned, oval-shaped basal Hawaiian-type shield volcano; (iii) apyroclasticcone, cut by aconcentric 12 kmwide caldera; and (iv) post-caldera basaltic suites, both intra- and extra-caldera. Considering KzO, La and Zr variations, three major trends characterize the geochemistry of Ambrym; one medium-K (MK) to high-K (HK) tholeiitic to calc-alkaline basaltic trend, and two more evolved trends, respectively MK and HK, from basaltic to dacitic and rhyodacitic compositions. These magmatic suites correspond to several volcanic phases: (1) older MK basalts forming the Tuvio-Vetlam- Dalahum edifice; (2) MK to HK basalts forming the basal shield volcano; (3) MK andesites and rhyodacites forming the first pyroclastic sequence of the Ambrym Pyroclastic Series (APS), which probably initiated the formation of the caldera; (4) MK to HK basalts and andesites forming Surtseyan then Strombolian pyroclastic sequences 2,3 and 4 of the APS; and (5) post-caldera MK to HK basalts forming the recent olivine porphyritic- and plagioclase-porphyritic suites, locally associated with more evolved HK andesitic volcanic rocks in the eastern part of the caldera. (La/Yb)n and (La/K)n ratios (2-5.9 and 1.3-2.2, respectively) and Zr contents indicate that the parental magmas originated from incremental batch melting or fractional melting (21-25%) during uplift of a single spinel lherzolite source (from at least60 to 45 km depth) in response to modifications in the tectonicenvironment due to ongoing collision with the D'Entrecasteaux Zone. However, K and La contents require prior enrichments by possible mantle metasomatism associated with subduction. Fractionation of olivine, plagioclase, clinopyroxene and Fe-Ti oxides explain most of the major and trace element variations in the resulting liquids and interaction between magmas rising from two distinct chambers combined with massive introduction of seawater into the edifice appear to be the major causes of the giant eruption leading to caldera formation. More recent activity of the volcano is principally related to shallow incremental batch melting or fractional melting and to fractionation in magma chambers associated with N100" rifting.

A systematic compilation of the geochemical data collected during the starmer programme is presented, in addition to all published data gathered along the North Fiji Basin (NFB) spreading system. From the 194 samples selected, the geochemical variations observed along the different spreading segments can be related to uni- or multi-modal origin of distinctive magma sources. These variations are interpreted as directly linked to the geodynamical features which surround the NFB. In the southern NFB, on the N174°E segment, N-MORB are present, but the low rate (or dead) subduction along the Hunter ridge still marks its influence as several basalts show a significant subduction-related contamination with negative Nb anomaly and high LOI. Several others are marked by a weak E-MORB source contribution, that may be related to subducted-OIB seamounts from the South Fiji Basin. In the central NFB, along the N-S segment which represents the most active and morphologically regular spreading ridge of the NFB, the magma source produces only N-MORB, with depleted LILE, HFSE, and LREE patterns, except in its northernmost part where magmatic signatures similar to that of the N15° segment appear. Along the N15° segment, three distinctive sources coexist and produce a wide range of geochemical signatures on the basalts collected; (1) a N-MORB source signature; (2) a transitional towards E-MORB source signature with a negative Nb anomaly indicating that some subduction related contamination still exists beneath the NFB (the basalts derived from this source might also have been called BABB previously); and (3) a source signature transitional towards E-MORB or OIB marking the start of an influence that increases towards the northern NFB as the Rotuma-Samoan hot spot lineament is approched. Around 17°S, on the Kaiyo station 4 site explored and sampled by the Nautile deep-sea submersible, as well as in the triple junction area, the same variability derived from three distinctive mantle sources is observed. Along the N160° segment, the three sources still coexist, but the influence of the E-MORB or OIB source (hot spot-related) increases, whereas the influence of the subduction-related source decreases. Along the Pandora-Rotuma ridge, the OIB-derived lava type is the only one present, the eventual contribution from other sources being completely diluted. Thus, the geochemistry of the NFB basalts is directly influenced by (1) the regional geodynamic environment, such as subduction zones and/or hot spot trails, (2) the geodynamical regime and stability of this type of back-arc system. The influence of the New Hebrides subduction, located some 500 km west of the active spreading ridge, is still perceptible, although weak, in the whole northern half of the NFB. However, this infuence is not directly linked to the presently active subduction, but originates rather from the partial melting of an upper mantle source that suffered subduction contamination during the clockwise rotation of the New Hebrides arc leading to the opening of the NFB during the past 12 Myr. In the northern NFB, many basalts result from the mixing of an N-MORB and a OIB source, similar to transitional alkalic lavas from oceanic intra-plate magmatism. This sources mixing increases northwards from 18°20′S to 12°S.

Lagabrielle, Y., Auzende, J.-M., Eissen, J.-P., Janin, M.-C. and Cotten, J., 1994. Geology and geochemistry of a 800 m section through young upper oceanic crust in the North Fiji Basin (Southwest Pacific). In: J.-M. Auzende and T. Urabe (Editors), North Fiji Basin: STARMER French-Japanese Program. Mar. Geol., 116: 113-132. We report the results of geological and structural observations made during one dive of the French submersible Nautile during the STARMER Cruise in 1989 in the vicinity of the 16”40’S triple junction in the North Fiji Basin. This dive provided a spectacular, 800 m continuous section of oceanic crust exposed along the northern wall of a 3000 m deep basin at the eastern branch of the triple junction. A number of volcanic facies have been encountered including massive and pillowed lavas, sheeted dikes and spectacular columnar-jointed massive lavas. Pillowed lavas have been observed only at the base and at the top of the section. The ratio between massive and pillowed basalts is high suggesting that the crust in this area grew mostly during a stage of high eruptive rate. Dikes have been observed in the middle part of the section. They probably do not represent the top of a classical “dike complex” but an isolated set of sheeted dikes, possibly the feeders of overlying flows. The abundance of vertical tectonic breccias observed during the first part of the dive confirms that the basal part of the wall can be regarded as a major tectonic boundary along which occurred significant vertical and strike-slip motions. Micropaleontological data from sedimentary rocks collected during the dive bring new constraints to the evolution of the triple junction. The oceanic crust in the surveyed area is at least as old as 1.9-1.3 Ma, based on the age of sedimentary rocks collected in talus at the base of the wall and observed at the summit of the section. The collected basalts include (1) N-type MORBs, (2) E-type MORBs and (3) BABBs. This emphasizes the heterogeneous nature of the mantle beneath the central NFB. Some portions of the depleted mantle underlying the central NFB triple junction area have recorded contamination from melts or fluids from an ancient subduction zone (probably .the New Hebrides during the opening of the NFB), whereas adjacent mantle areas show the influence from an alkali-enriched source. Such alkali-enriched characters are reported from recent basalts of the northern NFB (South-Pandora ridge-Rotuma island).

International audience; The Mojanda-Fuya Fuya Volcanic Complex consists of two nearby volcanoes, Mojanda and Fuya Fuya. The older one, Mojanda volcano (0.6 to 0.2 Ma), was first constructed by andesites and high-silica andesites forming a large stratovolcano (Lower Mojanda). This edifice was capped by a basaltic andesite and andesitic cone (Upper Mojanda), which collapsed later to form a 3-km-wide summit caldera, after large phreatomagmatic eruptions. The Lower Fuya Fuya edifice was constructed by the extrusion of viscous Si-rich andesitic lavas and dacitic domes, and the emission of a thick sequence of pyroclastic-flow and fallout deposits which include two voluminous rhyolitic layers. An intermediate construction phase at Fuya Fuya is represented by a mainly effusive cone, andesitic in composition (San Bartolo edifice), the construction of which was interrupted by a major sector collapse in the Late Pleistocene. Finally, a complex of thick siliceous lavas and domes was emplaced within the avalanche amphitheatre, forming the Upper Fuya Fuya volcanic centre. This paper shows that the general evolution from an effusive to an explosive eruptive style is related to a progressive adakitic contribution to the magma source. Although all the rocks of the complex are included in the medium-K field of continental arcs, the Fuya Fuya suite (61-75 wt.% SiO2) shows depletion in Y and HREE and high Sr/Y and La/Yb values, compared to the less silicic Mojanda suite (55-66.5 wt.% SiO2). The Mojanda calc-alkaline suite was generated by partial melting of an adakite-metasomatised mantle source that left a residue with 2% garnet, followed by fractional crystallization of dominant plagioclase + pyroxene + olivine at shallow, intra-crustal depths. For Fuya Fuya, geochemical and mineralogical data suggest either (1) partial melting of a similar metasomatised mantle with more garnet in the residue (4%), followed by fractional crystallization involving plagioclase, amphibole and pyroxene, or (2) mixing of mafic mantle-derived magma from the Mojanda suite and slab melts, followed by the same fractional crystallization process.

The North Fiji Basin (NFB) is a 12 m.y. old back-arc basin that has a complex multi-stage history. The presently active spreading system can be divided into four segments between 16°S and 22°S, which from north to south trend N160, N15 and N-S (the fourth segment is the N-S trending segment located near 174E). The main N-S segment is morphologically similar to other medium-rate oceanic ridges, whereas the other segments have rougher morphologies which have been severely disturbed by a triple junction at 16°45′S and several instability features such as overlapping spreading centres (OSCs) and propagating rifts. The spreading rate seems to diminish from 7.8 cm/yr near 20°S to 4.6 cm/yr near 18°S. Mineralogical, pertological and geochemical data were obtained on 24 new stations located along all the four segments. The petrogenesis of the basalts collected is essentially controlled by low-pressure crystal fractionation of plagioclase±olivine±clinopyroxene (plagioclase>olivine>clinopyroxene) with 52% of the NFB basalts reaching the four-phase cotectic. Locally, some magma mixing occurs, but this is limited to magma batches of closely related composition, as might be expected to occur inside a magma reservoir. The N-S segment, which, since 3 m.y., is the only steady-state segment, is also petrologically and geochemically very comparable to other medium-rate oceanic spreading centres, producing moderately evolved LILE and LREE-depleted N-MORB. In contrast, the three other segments produce basalts of much more variable petrology and geochemistry characterized by LILE and slightly LREE-enriched magmas cf back-arc basin basalt (BABB) affinity (but not as enriched as, for example, the Mariana BABB); MORB is, however, also found on the N160, N15 and 174E segments. Diagrams using Ba, Rb, K/P and (K/Ti)N (Normalized to the chondrites) plotted against latitude clearly show along-strike variations. Beneath the recently formed segments, the mantle source is heterogeneous, and locally has some BABB affinities, whereas beneath the more steady-state N-S segment the magma source is more homogeneous, being generally depleted in LILE and REE as is the case for classical N-MORB mantle sources. Simple evolution from an early stage of BABB production to MORB described in the Lau basin and proposed for the NFB does not seem to occur. Present-day activity still produces large amounts of BABB along the less-stable and more recently created segments, and MORB was produced in the earlier stages of the development of the NFB.

The Atacazo-Ninahuilca Volcanic Complex (ANVC) is located in the Western Cordillera of Ecuador, 10 km southwest of Quito. At least six periods of Pleistocene to Holocene activity (N1 to N6) have been preserved in the geologic record as tephra fallouts and pyroclastic flow deposits. New field data, including petrographic and whole-rock geochemical analyses of over forty soil and tephra sections, 100 pumice and lithic samples, and 10 new C-14 ages allow us to constrain: (1) the tephra fall isopachs and detailed characteristics of the last two events (N5-N6) including volume estimates of the tephra and pyroclastic flow deposits and the corresponding volcanic explosivity index (VEI); (2) the petrographical and geochemical correlations between domes, tephras, and pyroclastic flow deposits; and, (3) the timing of the last 4 eruptive events and a period of quiescence that endured a few thousand years (1000-4000).The last two eruptive events (N5 and N6) took place at around 4400 +/- 35 yr BP and 2270 +/- 15 yr BP, producing huge plinian and pyroclastic flow deposits. Taking into account the widely spread deposits of these VEI 5 eruptions, the present population of about 70000 people, and the current infrastructure; the development of mitigation plans and deployment of monitoring systems at ANVC is highly recommended. (C) 2008 Elsevier B.V. All rights reserved.

International audience; The Puyo scoria cones and the Mera lava flows, two newly recognized volcanic formations dated between Late Pliocene to Middle Pleistocene, extend the limits of the Ecuadorian rear-arc volcanic province some 100 km to the south. The Puyo scoria cones have erupted K-rich absarokites containing olivine, diopside and phlogopite, whereas the Mera lava flows display a basic andesite composition, with olivine and minor augite phenocrysts. In addition to high contents in LILE, LREE and HFSE, the Puyo absarokites exhibit many characteristics of primitive melts, namely high Cr (590–310 ppm) and Ni (330–154 ppm) contents, high Mg# (64–70) and they contain forsteritic olivine (Fo82–89). The composition of the most primary Puyo absarokite was used in petrogenetic models, in order to constrain the genesis of these high-K magmas. Major and trace elements models, as well as isotopic data, indicate that the source of Puyo magmas is a hydrated phlogopite- and garnet-bearing lherzolite. Phlogopite crystallization in the mantle wedge is triggered by the metasomatism by 3–5% of a SiO2-, H2O-rich liquid generated by slab melting. Partial melting of the subducted oceanic crust beneath Ecuador is allowed by the subduction of the young and warm Carnegie Ridge, which modifies the thermal regime of the Benioff zone. A low degree (1–4%) of partial melting of the metasomatized mantle wedge, leaving a variable garnet (4–7%) ± phlogopite (0–4%) lherzolitic residual assemblage, leads to the compositions of the entire Puyo absarokite series and is consistent with previous petrogenetic models developed for the Ecuadorian volcanic arc. Indeed, the homogeneity of isotopic data across the arc suggests a similar source for the whole Ecuadorian magmas.

A petrological study of the eruptive products of El Reventador allowed us to infer the magmatic processes related to the 2002 and 2004-05 eruptions of this andesitic stratovolcano. On November 3, 2002, El Reventador experienced a highly explosive event, which was followed by emplacement of two lava flows in November-December 2002. Silica contents range from 62 to 58 wt.% SiO2 for the November 3 pyroclastic deposits to 58-56 and 54-53 wt.% SiO2 for the successive lava flows. In November 2004 eruptive activity resumed supplying four new lava flows (56-54 wt.% SiO2) between November 2004 and August 2005. Volatile contents in matrix glasses and glass inclusions from the November 3 pyroclastic deposits allow us to estimate the total amount of SO2 and HCl released into the atmosphere during the paroxysmal phase (i.e. 80 kT of SO2 and 280 kT of HCl). Pre-eruptive pressure-temperature conditions of the magmas range from 300 to 150 MPa and similar to 1000 degrees C with high water contents (similar to 5 wt.%). We propose the existence of an andesitic magma body located at similar to 7-12 km depth that is frequently intruded by more primitive, hydrous magmas from a deeper source. The initial crystallization of amphibole from the hydrous primitive magma seems typical of El Reventador, as well as the historically recurrent and regular periods of eruptive activity lasting several years. This eruptive behaviour coupled with the fractionation and mixing processes inferred from the 2002 and 2004-05 petrologic data suggest that deep magmatic recharge at El Reventador is frequent, and is probably responsible for the high frequency of eruptions.

Ice-capped Chimborazo is one of the large composite Ecuadorian volcanoes whose recent eruptive activity is poorly known. This paper presents the characteristics and the ages of a newly discovered Holocene sequence of pyroclastic deposits on the east and north sides of the cone. Lying upon a moraine of the Late-Glacial period, the most complete section of similar to 4.5 m in thickness is located 5 km from the present summit crater. It consists of seven massive or diffusely stratified ash flow layers and four fallout layers interbedded with seven paleosoils. Based on held study, most flow deposits were assessed as surge layers, and six radiocarbon analyses obtained from charcoal fragments and paleosoils indicate that eruptions occurred at quite regular intervals between about 8000 and 1000 years ago. The first two and most potent events generated thick lahars over the north and west flanks of the cone. Surface textures of volcanic clasts were analysed by scanning electron microscopy. Blocky and blocky/fluidal vitric clasts indicate fragmentation during vulcanian explosions of a quite solidified shallow magma body. In addition, aggregates either cemented at a cooling stage (with surface fluidal textures), or consisting of fine particles (moss-looking aggregates), form a large part of the surge deposits. These characteristics indicate powerful explosions and intense fragmentation due to phreatic water reaching the conduit, probably from the ice-cap. Since the last eruption occurred between the early part of the 5th century (similar to AD 420) and the end of the 7th century, these results highlight that Chimborazo is a potentially active volcano. Given its dominating presence over the densely populated Ambato and Riobamba basins, and owing its large ice-cap, Chimborazo should be considered a dangerous volcano.

International audience; The Iliniza Volcanic Complex (IVC) is a poorly known volcanic complex located 60 kin SSW of Quito in the Western Cordillera of Ecuador. It comprises twin peaks, North Iliniza and South Iliniza, and two satellite domes, Pilongo and Tishigcuchi. The study of the IVC was undertaken in order to better constrain the role of adakitic magmas in the Ecuadorian arc evolution. The presence of volcanic rocks with an adakitic imprint or even pristine adakites in the Ecuadorian volcanic arc is known since the late 1990s. Adakitic magmas are produced by the partial melting of a basaltic source leaving a gamet rich residue. This process can be related to the melting of an overthickened crust or a subducting oceanic crust. For the last case a special geodynamic context is required, like the subduction of a young lithosphere or when the subduction angle is not very steep; both cases are possible in Ecuador. The products of the IVC, made up of medium-K basaltic andesites, andesites and dacites, have been divided in different geochemical series whose origin requires various interactions between the different magma sources involved in this subduction zone. North Iliniza is a classic calc-alkaline series that we interpret as resulting from the partial melting of the mantle wedge. For South Iliniza, a simple evolution with fractional crystallization of amphibole, plagioclase, clinopyroxene, magnetite, apatite and zircon from a parental magma, being itself the product of the mixing of 36% adakitic and 64% calc-alkaline magma, has been quantified. For the Santa Rosa rhyolites, a slab melting origin with little mantle interactions during the ascent of magmas has been established. The Pilongo series magma is the product of a moderate to high degree (26%) of partial melting of the subducting oceanic crust, which reached the surface without interaction with the mantle wedge. The Tishigcuchi series shows two stages of evolution: (1) metasomatism of the mantle wedge peridotite by slab melts, and (2) partial melting (10%) of this metasomatized source. Therefore, the relative ages of the edifices show a geochemical evolution from cale-alkaline to adakitic magmas, as is observed for several volcanoes of the Ecuadorian arc.

In the Northern Volcanic Zone of the Andes, the Cayambe Volcanic Complex consists of: (1) a basal, mostly effusive volcano, the Viejo Cayambe, whose lavas (andesites and subordinate dacites and rhyolites) are typically calc-alkaline; and (2) a younger, essentially dacitic, composite edifice, the Nevado Cayambe, characterized by lavas with adakitic signatures and explosive eruptive styles. The construction of Viejo Cayambe began > 1.1 Myr ago and ended at similar to 1.0 Ma. The young and still active Nevado Cayambe grew after a period of quiescence of about 0.6 Myr, from similar to 0.4 Ma to Holocene. Its complex history is divided into at least three large construction phases (Angureal cone, Main Summit cone and Secondary Summit cone) and comprises large pyroclastic events, debris avalanches, as well as periods of dome activity. Geochemical data indicate that fractional crystallization and crustal assimilation processes have a limited role in the genesis of each suite. On the contrary, field observations, and mineralogical and geochemical data show the increasing importance of magma mixing during the evolution of the volcanic complex. The adakitic signature of Nevado Cayambe magmas is related to partial melting of a basaltic source, which could be the lower crust or the subducted slab. However, reliable geophysical and geochemical evidence indicates that the source of adakitic component is the subducted slab. Thus, the Viejo Cayambe magmas are inferred to come from a mantle wedge source metasomatized by slab-derived melts (adakites), whereas the Nevado Cayambe magmas indicate a greater involvement of adakitic melts in their petrogenesis. This temporal evolution can be related to the presence of the subducted Carnegie Ridge, modifying the geothermal gradient along the Wadati-Benioff zone and favouring slab partial melting.

Extensive scoriaceous volcaniclastic deposits were observed and sampled by submersible and dredging on three segments of the Mid-Atlantic Ridge (MAR) south of the Azores islands between 550 and 1750 mbsl. The deposits arerestricted to axial volcanoes at the central part of each of the segments, in close association with zones of major volcanic and hydrothermal activity. The extent and volume of the volcaniclastic deposits decrease significantly with increasing water depth. The deposits generally are composed of well-stratified mm- to cm-scale layers, mainly un-reworked. The layers consist dominantly of juvenile, highly vesicular, scoriaceous, glassy clasts. Accessory lithic clasts are angular non-vesicular and more altered fragments. Thin calcareous sedimentary interlayers are found throughout the deposits, and reach a combined thickness of hundreds of meters. Such a thickness indicates that the deposits formed over long periods of time. The juvenile clasts have E-MORB to alkali basalt geochemistry, and are enriched relative to N-MORBs found elsewhere along the MAR. The primitive volatile content (dominantly CO 2 ) of this enriched magma remained in solution until magma eruption by dominantly explosive hydrovolcanic activity on the seafloor. The morphology of individual clasts shows that the main mechanism of fragmentation was magmatic (volatile driven) explosivity, followed by quench granulation, bulk magma-water interaction, and accessory surface magma-water interaction. The grain size characteristics of the deposits indicate that the resulting clasts were mainly emplaced by settling of suspended fragments from the water column. Accessory lateral-flowing density currents may have occurred during collapse of convective-settling suspensions. The studied area represents an excellent natural laboratory for additional studies of the fundamental controls of submarine volcaniclastic eruptions.

The largest explosive eruption (volcanic explosivity index of 6) in historical times in the Andes took place in a.d. 1600 at Huaynaputina volcano in southern Peru. According to chronicles, the eruption began on February 19 with a Plinian phase and lasted until March 6. Repeated tephra falls, pyroclastic flows, and surges devastated an area 70 × 40 km2 west of the vent and affected all of southern Peru, and earthquakes shook the city of Arequipa 75 km away. Eight deposits, totaling 10.2–13.1 km3 in bulk volume, are attributed to this eruption: (1) a widespread, ∼8.1 km3 pumice-fall deposit; (2) channeled ignimbrites (1.6–2 km3) with (3) ground-surge and ash-cloud-surge deposits; (4) widespread co-ignimbrite ash layers; (5) base-surge deposits; (6) unconfined ash-flow deposits; (7) crystal-rich deposits; and (8) late ash-fall and surge deposits. Disruption of a hydrothermal system and hydromagmatic interactions are thought to have fueled the large-volume explosive eruption. Although the event triggered no caldera collapse, ring fractures that cut the vent area point to the onset of a funnel-type caldera collapse.

Compositional variations (major- and trace-element) of Pleistocene to Present rocks along the volcanic New Hebrides Central Chain (Southwest Pacific) are presented and discussed, using a new set of analyses. We focus in particular on the anomalous Mg-, K-, LILE- and LREE-rich and Al and Si-poor character of the basalts from Aoba and Santa Maria volcanoes (and, to a lesser extent, from Ambrym volcano), all located in the area where the D'Entrecasteaux Zone collides with the arc. In addition, we note a compositional transition from 'normal' arc basalts to boninite-related high-Mg andesites at the southern termination of the NHCC. The peculiar composition of the rocks of the volcanoes facing the D'Entrecasteaux Zone has traditionally been related, more or less directly, to the collision-subduction occurring in this area. We present an alternative hypothesis, of a strong geochmeical anomaly under Santa Maria and Aoba volcanoes, unrelated to this collision. In this model, a westward and upward invasion of DUPAL-type enriched mantle, corroborated by the pattern of intermediate seismicity, occurs under this part of the arc, in strong contrast to the usual Pacific-type MORB mantle source present under all other volcanoes of the NHCC. Such a DUPAL-type source may explain the anomalous geochemistry of the resulting volcanic products. (Résumé d'auteur)

Recently, [Garrison and Davidson (2003)][1] questioned the possibility that the adakites of the Northern volcanic zone of the Andes were generated by slab melting. The conclusions of the authors, involving a lower-crustal source for adakites, are in clear contradiction with ideas already proposed

At Santa Maria Volcano (New Hebrides island arc), extensive ash and scoria flow deposits overlie the mainly effusive, pre-caldera cone. Hydromagmatic features characterize these deposits, the composition of juvenile clasts ranges from basalt to acid andesite/dacite (SiO2= 51–63.6%) with a dominant basaltic composition. The stratigraphic position of this pyroclastic series and its spatial distribution around a 8.5 km × 6 km wide caldera provide evidence of a relationship between this series and the caldera formation. In addition, these pyroclastic deposits are co-genetic to parasitic cones and lava flows developed along faults concentric to the caldera. Both series result from a compositionally layered magma reservoir, the subordinate differentiated magmas being the result of fractional crystallization from the basalts. A model of caldera formation which implies a large hydromagmatic eruption at the central vent and minor magma withdrawal by flank eruptions is proposed. This model emphasizes the importance of mafic hydroclastic eruptions in the caldera forming event and contradicts a model implying only quiet subsidence, a process often proposed for the formation of calderas in island are volcanoes of mainly mafic composition.

As the result of intensive studies conducted by U.S., French, and Japanese scientific teams, the North Fiji Basin ridge, poorly known 10 years ago, is one of the most exhaustively investigated ridge axes of the world’s oceans. Today, a ridge segment more than 800 km long and 100 km wide has been fully mapped with the Sea Beam and Furono echo sounders. This ridge axis shows four main segments characterized by the same morphostructural aspect and limits that characterize mid-oceanic ridges. Along the whole length of the axis, a water-column sample has been taken every 20 km and rock samples every 10 km. Different types of hydrothermal activity have been discovered and explored either during the Nautile cruise in 1989 or during the Shinkai 6500 cruise in 1992. The most famous site is the “White Lady,” located around 17°S; it is characterized by 285°C shimmering hot water, which is very poor in metallic elements, expelled through an anhydrite chimney. This water probably represents the low salinity end-member resulting from phase separation in the deep levels of the oceanic crust. Other active sites have been observed all along the axis showing different characteristics such as low-temperature diffusion zones. Even though some parts of the North Fiji Basin remain poorly investigated, the newly acquired data from the ridge axis and from the eastern and northwestern parts allow us to develop a new tectonic model of basin evolution since its creation 12 m.y. ago.

Tanna island is part of a large volcanic complex mainly subsided below sea-level. On-land, two series of hydroclastic deposits and ignimbrites overlie the subaerial remains of a basal, mainly effusive volcano. The ‘Older’ Tanna Ignimbrite series (OTI), Late Pliocene or Pleistocene in age, consists of ash flows and ash- and scoria-flow deposits associated with fallout tephra layers, overlain by indurated pumice-flow deposits. Phreatomagmatic features are a constant characteristic of these tuffs. The ‘younger’ Late Pleistocene pyroclastics, the Siwi sequence, show basal phreatomagmatic deposits overlain by two successive flow units, each comprising a densely welded layer and a nonwelded ash-flow deposit. Whole-rock analyses of 17 juvenile clasts from the two sequences (vitric blocks from the phreatomagmatic deposits, welded blocks, scoriaceous bombs and pumices from the ignimbrites) show basaltic andesite and andesite compositions (SiO2=53–60%). In addition, 296 microprobe analyses of glasses in these clasts show a wide compositional range from 51 to 69% SiO2. Dominant compositions at ∼54, 56, 58.5 and 61–62% SiO2 characterize the glass from the OTI. Glass compositions in the lower — phreatomagmatic — deposits from the Siwi sequence also show multimodal distribution, with peaks at SiO2=55, 57.5, 61–62 and 64% whereas the upper ignimbrite has a predominant composition at 61–62% SiO2. In both cases, mineralogical data and crystal fractionation models suggest that these compositions represent the magmatic signature of a voluminous layered chamber, the compositional gradient of which is the result of fractional crystallization. During two major eruptive stages, probably related to two caldera collapses, the OTI and Siwi ignimbrites represent large outpourings from these magmatic reservoirs. The successive eruptive dynamics, from phreatomagmatic to Plinian, emphasize the role of water in initiating the eruptions, without which the mafic and intermediate magmas probably would not have erupted.

Ambrym, in the New Hebrides arc, has been considered as an effusive, basaltic volcano. The present paper discusses the general structure of this edifice, which consists of a basal shield volcano topped by an exceptionally large tuff cone surrounding a 12-km-wide summit caldera. Dacitic pyroclastic flow deposits are exposed in the lower part of the tuff series; they grade upward into composite sequences of bedded surtseyan-type hyaloclastites, ash flow deposits, and fallout tephra which are essentially basaltic in composition, in such a way that the tuff cone may be considered as mainly basaltic. The relationship between the eruption of pyroclastics and the collapse event precludes a classical model of caldera formation at a basaltic volcano in which “quiet” subsidence (i.e. Kilauea type) is the dominant mechanism. Interpretation of the tuff series implies intervention of external water and suggests both explosive and collapse mechanisms. A model of caldera formation which assumes an enlargement of the ring fracture during a first plinian and dacitic, then essentially hydrobasaltic eruption is proposed.

In June 1989 a diving cruise by the submersibleNautile was carried out on the North Fiji Basin spreading ridge. The objective of the cruise was a geological and geochemical study of the active spreading axis and associated hydrothermal processes. This operation was the third cruise of the French-Japanese Starmer project following the two cruises of the R.V.Kaiyo in 1987 and 1988. Six dives along the spreading axis between 16°58′S and 17°00S show that the axial graben consists of alternating N15—trending horsts and grabens. Extinct hydrothermal sites have been observed all along the graben. These consist of fossil chimneys, oxide staining and dead shells. At 16°59′S an active chimney has been discovered and called the “White Lady” because of its almost exclusively anhydrite composition. This chimney expels a peculiar water characterized by low chlorinity and a 285°C maximum temperature. In the northern extremity of the N15 axis a wide fossil hydrothermal site has been explored and sampled. It is located in an area cut by N15, N140 and N60-trending faults and fissures.

Slab melting has been suggested as a likely source of adakitic arc magmas (i.e., andesitic and dacitic magmas strongly depleted in Y and heavy rare earth elements). Existing numerical and petrologic models, however, restrict partial melting to very young (≤ 5 Ma) oceanic crust (typically at 60–80 km depth). Paradoxically, most of the known Pliocene-Quaternary adakite occurrences are related to subduction of 10–45 Ma lithosphere, which should not be able to melt under normal subduction-zone thermal gradients. We propose an unusual mode of subduction known as flat subduction, occurring in ∼10% of the world's convergent margins, that can produce the temperature and pressure conditions necessary for fusion of moderately old oceanic crust. Of the 10 known flat subduction regions worldwide, eight are linked to present or recent (

Detailed studies by submersible were carried out in the axial zone of the Red Sea Rift near 18"N during the Soviet Red Sea expedition of the Oceanological Institute of the Academy of Sciences (December 1979-March 1980). The initial bathymetric, magnetic and seismic surveys established the general organization of the symmetric tectonic steps (1-3) descending towards the axial rift. The 45 km wide inner floor of the rift was explored during 21 dives. It is occupied by 100-300 m high, young pillowed volcanoes, isolated or grouped to form elongated hills, frequently cut by open fissures except in the zone of most recent extrusion. The 42 samples collected are typical plagioclase k olivine 5 clinopyroxene & spinel, more or less porphyritic mid-ocean ridge basalts whose compositions were mainly controlled by polybaric fractionation of plagioclase, olivine and minor clinopyroxene. They have been separated into porphyritic and sub-alfhyric groups using modes andmineralogical criteria. Mineral-liquid equilibria, crystal zonation, andmodal proportions indicate some magma mixing but probably only of closely related magma batches within each described group, as can occur inside a single magma chamber. Crystal accumulation is believed to have played a significant role in only a few porphyritic samples. Three sub-groups (from less to more evolved; (a) FeO*/MgO 1.49) were distinguished on the basis of glass and whole-rock major element chemistry. Glass compositions follow the multisaturated cotectic-like curve for MORB-type basalts and show a general evolution very comparable to what is observed on the Mid-Atlantic Ridge near 36"N, but are less diverse than in the FAMOUS area. 87Sr/86Sr, 143Nd/144Nd, and zo6Pb/204Pb data for 4 samples show strong similarities to those from the Mid-Atlantic and East Pacific Ridges, and indicate no continental contamination despite the fact that they have been produced during recent continental break-up and ocean opening. 206Pb/204Pb values, Th/Ta vs. Th/Tb correlations, and rare earth element patterns allow recognition of three different groups of samples, indicating that the Red Sea Rift near 18"N is fed by a heterogeneous mantle source. The chondrite-normalized LREE

Geologic field relationships observed in the axial valley of the southern Juan de Fuca Ridge suggest that high-effusion-rate sheet-flow volcanism has been active for a maximum of about 16,000 yr. Similar observations in the axial region of the East Pacific Rise near lat 21° N suggest that the duration of the pillow-flow-dominant phase may be 5 × 10 4 yr. Geochemical evidence from axial and off-axis basalt samples from both the Juan de Fuca Ridge and East Pacific Rise 21° N indicates that surficial geologic cycles of volcanism, tectonism, and hydrothermal activity are an expression of changes in the locus of replenishment within the magma chamber that take place with a periodicity of 10 4 −10 5+ yr. Anomalously high rates of spreading due to magmatic replenishment and inflation during the first phases of a volcanic cycle may cause the southern Juan de Fuca Ridge to display a morphology more commonly associated with fast-rate spreading centers.