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[Display omitted] • Garnet LA-ICP-MS U Pb dating yielded a lower-intersect age of 268.6 ± 5.9 Ma. • The initial hydrothermal fluids are magmatic water, mixing with meteoric water. • Arqiale is classified as a distal skarn Pb Zn Cu deposit. • Arqiale underwent two stage exhumation events in the Mesozoic and Cenozoic. • The causative intrusions and Cu mineralization may occur at depth in the north. The Arqiale Pb Zn Cu deposit is located in the Wusun Range, Western Tianshan, China. Prograde and retrograde skarn minerals are abundant and associated with the Pb Zn Cu mineralization. Given that the orebodies are stratabound and hosted in limestone and causative intrusions were not identified, the genetic relationship between mineralization and magmatic hydrothermal activity remains controversial. Geology, in-situ garnet LA-ICP-MS U Pb dating and S Pb C H O isotopes were carried out in this study, aiming to constrain the mineralization age, source of ore-forming components, and examine the link between mineralization and magmatism. In-situ garnet LA-ICP-MS U Pb dating yielded a well-defined lower-intercept age of 268.6 ± 5.9 Ma, reflecting that the mineralization occurred much younger than that of ore hosting strata and formed in a post-collisional setting. In-situ δ34S values of sulfides (chalcopyrite, sphalerite and pyrite) range from −5.81‰ to −7.57‰ with an average of −6.37‰. The δ34S values of sulfide separates published previously vary from −7.1‰ to 1.3‰ (average −1.5‰). The in-situ 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios of galena vary from 18.262 to 18.269, 15.561 to 15.567 and 38.049 to 38.065, respectively. The aforementioned S-Pb isotopic compositions indicate that the metals and sulfur were sourced partially from causative intrusion and partially from hosing sedimentary rocks. The δ13C (-2.6 – −0.9‰), δ18O V-SMOW (3.2 – 7.7‰), δ18O H2O (-5.2 – −0.7‰) and δD H2O (-128.0 – −109.1‰) values of ore-bearing calcite suggest that the ore-forming fluids were initially sourced from magmatic water exsolved from the hidden causative intrusions, with increasing input of meteoric water in later time. These geological, geochemical and isotopic data confirm that Arqiale is a typical distal skarn Pb Zn Cu deposit. Considering the chalcopyrite-garnet-ilvaite contents increasing and Zn/Pb rations decreasing from the shallow part in the south to the deeper part in the north, it is inferred that the hidden causative intrusions and Cu mineralization within contact zone may occur at depth in the northern part of Arqiale. [ABSTRACT FROM AUTHOR]

[Display omitted] • The initial ore-forming fluids were magmatic water, with input of meteoric water with time. • Fluid phase separation and mixing triggered the Pb-Zn-Ag and Sb precipitation, respectively. • Keyue is the distal Pb-Zn-Sb-Ag mineralization centered on the Cuonadong leucogranites. • Pegmatite-skarn-type W-Sn-Be deposits may occur at deeper sites beneath the Keyue area. The Keyue Pb-Zn-Sb-Ag polymetallic deposit is located within the North Himalayan Metallogenic Belt (NHMB). This study aims to clarify whether the Keyue deposit has close association in time and space with magmatism, and discuss the significance for further exploration. Orebodies are hosted by the Lower Jurassic Ridang Formation black carbonaceous slate and controlled by the NE-trending faults. Keyue is characterized by multiple stages of hydrothermal veins, including Mn-Fe Carbonate-sulfide (I), quartz-sulfide-sulfosalt mineral (II) and quartz-calcite-stibnite veins (III). Hydrothermal minerals contain six types of fluid inclusions, including H 2 O-rich bi-phase aqueous (type I), pure CO 2 (type II), CO 2 -rich H 2 O-CO 2 -NaCl tri-phase (type III), H 2 O-rich H 2 O-CO 2 -NaCl tri-phase (type IV), halite-bearing tri-phase (type V) and halite-bearing H 2 O-CO 2 -NaCl multiphase inclusions (type VI). All six types of inclusions were observed in stage II quartz, whereas only types I and III inclusions in stage I siderite and sphalerite and type I inclusions in stage III quartz and calcite. Type I inclusions in stage I display total homogenization temperatures (T h, total) ranging from 250.1 to 289.3 °C, with salinities of 9.6–16.3 wt% NaCleq. Types I, III, IV and V inclusions in stage II yield T h, total of 175.5–282.7 °C, 188.8–286.3 °C, 214.3–287.5 °C and 198.3–266.0 °C, with corresponding salinities of 4.0–21.5 wt% NaCleq, 0.6–2.9 wt% NaCleq, 0.0–11.0 wt% NaCleq and 30.1–33.2 wt% NaCleq, respectively. Type I inclusions in stage III have T h,total values of 172.3–240.7 °C and salinities of 3.1–12.6 wt% NaCleq. Fluid phase separation occurred in stages I and II, resulting in CO 2 and H 2 S release, pH increase and rapid Pb-Zn-Ag precipitation, whereas mixing of magmatic fluids and meteoric water in stage III caused the cooling, dilution and stibnite precipitation. Fluid inclusion analysis and C-H-O isotopic compositions indicate that the initial hydrothermal fluids were magmatic water, with increasing input of meteoric water with time. The δ34S CDT values of sulfides from three stages are similar and range from 4.8 to 10.3 ‰ (average 7.7 ‰), showing characteristics of mixture of magmatic and sedimentary sulfur. The Pb isotopic compositions of sulfides are closely consistent with those of Cenozoic leucogranite and Precambrian metamorphic crystalline basement in the NHMB, suggesting that the ore-forming metals were sourced from the hidden causative Himalayan leucogranite formed by the decompression melting of metamorphic crystalline domains. Combining evidence from geochronology, fluid inclusions, isotopes suggest that the Keyue Pb-Zn-Sb-Ag and Cuonadong W-Sn-Be mineralization at different locations around the Cuonadong Dome constitute an integrated magmatic-hydrothermal system, with the distal end-member Pb-Zn-Sb-Ag veins centered on the Cuonadong leucogranites-related W-Sn-Be mineralization. Pegmatite-skarn-type W-Sn-Be polymetallic mineralization may occur at deeper sites beneath the Keyue area, and the distal Pb-Zn-Sb-Ag veins controlled by faults within strata also need more attention around these leucogranite domes in the NHMB. [ABSTRACT FROM AUTHOR]

• The Lailisigao'er and Qixing deposits are coeval and both related to the granodiorite porphyries. • Fluid immiscibility and mixing were the precipitation mechanism for Mo and Pb-Zn, respectively. • The Qixing Pb-Zn deposit represents a distal end-member centered on Mo-mineralized porphyries. • Concealed porphyry Cu-Mo mineralization may be developed underneath No. 3571 and Qixing areas. The Nailenggele orefield, located in the northwestern Chinese Tianshan Orogenic Belt, is composed of the Lailisigao'er Mo deposit, No. 3571 Cu prospect and Qixing Pb-Zn deposit. Lailisigao'er is a typical porphyry deposit with characteristic veinlet-disseminated ores and potassic, phyllic and propylitic alterations. No. 3571, situated in the peripheral of Lailisigao'er, is characterized by large amounts of oxidized ores at surface with limited intrusions outcropped. Qixing, about 3 km from Lailisigao'er, is characterized by quartz-sulfide veins controlled by fractures. This study aims to examine the genetic relationships between these deposits and/or occurrences, and discuss the significance for further exploration in the orefield and elsewhere in the region. LA-ICP-MS U-Pb dating on zircons from the ore-bearing porphyry in the Lailisigao'er deposit yielded an age of 367.5 ± 4.8 Ma. The molybdenite Re-Os and sphalerite Rb-Sr isochron ages recalculated from previously published data are 365.9 ± 2.1 Ma for Lailisigao'er and 362.0 ± 5.7 Ma for Qixing, respectively, suggesting that they are coeval and both related to the granodiorite porphyries. Three types of fluid inclusions occur in the Mo-bearing quartz from Lailisigao'er, including two-phase aqueous inclusions (Type I), solid mineral-bearing aqueous inclusions (Type II) and CO 2 -H 2 O inclusions (Type III). The total homogenization (T h) temperatures cluster from 260 to 320 °C (to liquid) for type I inclusions, 310 to 332 °C (to liquid) for type II inclusions, and 268 to 324 °C (to CO 2 phase) for type III inclusions. The salinities are mainly in the ranges of 2.0–8.0, 32.9–42.0, and 1.4–5.5 wt% NaCleq for types I, II and III inclusions, respectively. By contrast, only type I inclusions were identified in the Pb-Zn-bearing quartz from Qixing, with T h values of 149–261 °C and salinities of 1.7–5.3 wt% NaCleq. The δ34S CDT values of hydrothermal sulfides from Lailisigao'er, No. 3571 and Qixing range from 2.8‰ to 4.0‰, 4.0‰ to 4.6‰ and 0.7‰ to 4.9‰, respectively. Sulfides from these three locations have uniform Pb isotopic compositions. The (87Sr/86Sr) 0 ratios of fluid inclusions (average 0.70971) in Mo-bearing quartz at Lailisigao'er and sphalerite (average 0.71020) at Qixing are similar to those of Mo-mineralized porphyries (average of 0.70886) from Lailisigao'er. The δ18O H2O and δD H2O values of Pb-Zn-bearing quartz from Qixing are similar to those of Mo-bearing quartz from Lailisigao'er, both plotting close to the field of magmatic water but shifted toward the meteoric line. These geochronological, fluid inclusions and isotopic data suggest that the mineralization at different localities in the Nailenggele orefield constitutes part of an integrated magmatic-hydrothermal system centered on the Lailisigao'er porphyry Mo deposit, with the Qixing Pb-Zn polymetallic deposit representing a distal end-member. Both metals and sulfur were dominantly derived from porphyritic intrusions, whereas the ore-forming fluids were initially derived from the magmatic intrusions, with increasing involvement of meteoric water in time and distance from magmatic-hydrothermal center. Fluid immiscibility in the early stage and fluid mixing in the later stage, together with cooling, were responsible for ore precipitation. Based on this mineralization model, it is inferred that concealed porphyry Cu-Mo mineralization may be developed underneath the No. 3571 and Qixing. [ABSTRACT FROM AUTHOR]

The 'green-bean rock' (GBR) is a greenish or yellowish green Triassic potassium-rich felsic tuff containing prominent bean-like quartz grains, which is widespread in the Yangtze platform and Nanpanjiang basin, South China. This paper studies the age, origin and tectonic setting of the GBR from the western margin of the Yangtze platform through whole-rock geochemistry and zircon U--Pb geochronology and Hf isotopes. In contrast to the Nanpanjiang basin, where multiple GBR layers are developed and encompass the Olenekian-Anisian boundary (OAB), which is constrained to be at 247.1–247.3 Ma, the age of the single GBR layer in the western margin of the Yangtze platform and its relationship with the OAB have not been determined. U--Pb dating on zircons from the GBR in this study yielded an age of 247.49 ± 0.68 Ma, which is considered to be comparable to that of the OAB, and thus the GBR may be used as a marker for regional stratigraphic correlation. The volcanic ashes of the GBR have been previously suggested to be derived from the Siberian Traps Large Igneous Province or from the Shiwandashan-Qingfang suture zone to the south of the Nanpanjiang basin. However, the whole-rock geochemistry of the GBR, especially enrichment in LREE, Th and U and depletion in Nb, Ta, Sr, Ba, K, Rb and Ti, and strong to moderate negative Eu anomalies (δ Eu = 0.16–0.20), suggest that the volcanic ashes are more likely derived from the adjacent Sanjiang Orogen to the southwest. The zircon geochemistry, especially the negative ε Hf (t) values (−16.4 to −5.1) and old two-stage Hf model (T DM2) ages (1.60–2.30 Ga), are also similar to those from the Early-Middle Triassic felsic volcanic rocks in the Sanjiang Orogen. The subduction of the Paleo-Tethys Ocean was previously inferred to have started between Early Permian and Middle Triassic. The data obtained in this study, in combination with those compiled for igneous rocks and volcanic ashes from Middle Permian to Late Triassic from the region, suggest that the subduction initiation of the Paleo-Tethys Ocean began no later than ~254 Ma, in middle Late Permian. • The new zircon U--Pb age of 247.49 ± 0.68 Ma was obtained for the GBR. • The GBR can be used as a marker for the Olenekian-Anisian boundary (OAB). • The GBR are derived from the Sanjiang Orogen. • The subduction of the Paleo-Tethys Ocean started at 254.8 Ma. [ABSTRACT FROM AUTHOR]