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Quantitative mineralogical analysis of clay-bearing rocks is often a non-trivial problem because clay minerals are characterized by complex structures and are often affected by structural disorder, layer-stacking disorder, and interstratification. In the present study, internal-standard Rietveld X-ray powder diffraction (XRPD) analyses were combined with X-ray fluorescence (XRF) chemical analyses for the mineralogical characterization and quantitative analysis of heterogeneous clay-rich sedimentary rocks that are involved in a slow-moving landslide in the Termini-Nerano area, Sorrento Peninsula (Italy), in order to investigate the relationship between the mineralogy of these rocks and landslides. Slow-moving landslides are usually considered to be associated with the more weathered and surficial parts of structurally complex slopes, and mineralogical analysis can help to clarify the degree of weathering of siliciclastic rocks. XRPD quantitative analyses were conducted by combining the Rietveld and internal standard methods in order to calculate the amounts of poorly ordered phyllosilicate clays (considered amorphous phases in Rietveld refinements) by difference from 100%. The vbAffina program was used to refine the amounts of mineral phases determined with XRPD using the element compositions determined by XRF analysis. XRPD analyses indicated that the samples mainly contain several different clay minerals, quartz, mica, and feldspars. Analysis of the clay fraction identified kaolinite, chlorite, and interstratified illite-smectite (I-S) and chlorite-smectite (C-S). The mineralogy of the materials involved in the landslide in comparison with the mineralogy of the "undisturbed" rocks showed that the landslide is located in the weathered realm that overlies an arkosic bedrock. The interstratified I-S and C-S occurred at landslide activity locations and confirmed that areas more susceptible to sliding contained the most weathered parts of the rocks and perhaps represent areas of past and currently active fluid flow.

The present paper illustrates the results of an integrated study of a large landslide located on the southern slope of Mount la Civita (Molise, Southern Apennine), an E-W elongated, SSE dipping and 890-m-high monocline carbonate ridge. The upper part of the slope affected by the landslide is largely controlled by strata attitude while its basal part is marked by a strike-slip fault causing the tectonic juxtaposition of the carbonate successions against predominantly clayey flysch units. An integrated study, including geological, geomorphological and geotechnical investigations, was carried out to determine the features of the landslide and to plan further investigation and monitoring. In particular, from 2002 to 2004, Differential Global Positioning System monitoring and core drillings, coupled with inclinometer measurements, were carried out to determine the landslide's kinematics, extent, depth to the surface of rupture and rates of movement. Inclinometer data revealed the presence of the rupture surface at a depth of about 20 m. DGPS monitoring allowed rates of movement up to several tens of centimetres per year to be recorded. The nearby village of Civitanova del Sannio can still be considered at risk due to the landslide, as recent remedial works, consisting mainly of very shallow re-shaping of the slope by blasting and partial filling of trenches, did not succeed in stopping its movement. © 2012 Springer-Verlag.

An integrated geomorphological, geological-structural and stratigraphic approach was applied to the Sessano intra-montane basin (Molise, Central-Southern Apennines) to understand the Quaternary environmental and sedimentary evolution of the basin and the surrounding areas. The morpho-evolutionary and sedimentary changes were mainly controlled by tectonics and strongly influenced by the huge amount of volcaniclastic input from the Roccamonfina volcano (located ca. 50km to the south-west) as well as by climatic changes. Chronological constraints, supported by Ar/Ar ages of tephra layers, archaeo-tephro-stratigraphy and pollen analysis, permit identification of the main phases of the geological-geomorphologic evolution of the Sessano basin from the Middle Pleistocene onwards. The sedimentation within the basin was controlled by NE-SW extensional tectonics and occurred from the end of Oxygen Isotope Stage (OIS) 15 to the beginning of OIS 11 allowing the deposition of ca. 85m of fluvial to lacustrine sediments, mainly made up of reworked volcaniclastic material. The first phase of sedimentation was lacustrine, while an important sedimentary change from lacustrine to fluvial-marshy environment occurred during OIS 14. After this phase, the variable input of volcaniclastic material from the Roccamonfina volcano together with climatic influences caused repeated changes from palustrine to fluvial sedimentation, and the formation of various palaeosols present mainly in the upper portion of the infill. Towards the end of OIS 11, NNW-SSE extensional tectonics caused the tilting of the fill succession and the drying up of the basin. The fill succession was then affected by fluvial erosion and denudation that generated an erosion surface nowadays hanging at 700-720m asl. This surface can be related to the limbs of a palaeo-surface at about 600m asl present in the adjacent Carpino-Le Piane intra-montane basin and referred to a fourth order, Tyrrhenian-ward oriented palaeo-landscape. This palaeo-landscape can be dated to ca. 350-300ky and, therefore, represents an important morpho-chronological stage. It provides a robust maximum and minimum age framework for reconstructing the geological and geomorphological evolution of the study area and, in general, of the Molise Apennines including the Boiano, Carpino-Le Piane and Sessano intra-montane basins. In particular, the morpho-chronological data from the Sessano basin allow us to date more precisely the main tectonic phases that occurred during the Middle Pleistocene in this sector of the Apennine chain. Finally, the multi-proxy data derived from the Sessano basin can be compared and integrated with those referring to other proximal intra-montane basins in order to improve our knowledge on the relationships between tectonics, volcanism and climate and the stratigraphic-sedimentary features, geomorphologic evolution and palaeoenvironmental changes that characterized the Central-Southern Apennines during Middle Pleistocene. © 2010 Elsevier B.V.

New morphostratigraphic and chronological constraints for the Quaternary paleosurfaces of the Molise Apennine (southern Italy)The Molise Apennines feature numerous relicts of paleosurfaces, mostly of erosional origin, which represent the remnants of gently-rolling ancient landscapes now hanging at different altitudes above the local base-levels of erosion. Their genesis can be related to prolonged periods of relative tectonic stability alternating with periods of uplift, or to the interplay between steady tectonic uplift and climatic fluctuations. Four orders of paleosurfaces were recognized: I (> 1,100 m a.s.l.), II (900-1,000 m a.s.l.), III (750-850 m a.s.l.), IV (600-720 m a.s.l.). The most ancient orders (I and II) are cut into the bedrock and are located at the top of the Matese and Montagnola di Frosolone massifs. The youngest paleosurfaces (III—IV), partially cut into Quaternary deposits, are found along the valley flanks of the main river systems and within the Boiano, Carpino, Isernia and Sessano intramontane basins. The present study deals with the dating of the Sessano Basin Paleosurface (SBP) which is related to the IV order and is cut into the basin infill. The40Ar/39Ar age of a tephra layer (437 ± 1.9 ka), intercalated at the top of the succession, supported by archaeo-stratigraphic, palynological and paleopedological data, allowed the SBP surface to be constrained to 350-300 ka. The SBP chronological position represents an important morphostratigraphic marker: it is the firstante quemandpost quemdate that allows the chronological position of the other orders of paleosurfaces to be better constrained.