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The rapidly collapsing glacial systems of the Alps produced a large number of melt-water lakes and mires after the Last Glacial Maximum (LGM) in the Late Glacial period. The Rhone-Aare-glacier system gave rise to large moorlands and lakes in the region of the Three Lakes Region of Western Switzerland. When moorlands are formed, they are efficient sinks of atmospheric carbon, but when transformed to agricultural land they are significant C sources. In addition, mires can be used as archives for reconstructing landscape evolution. We explored in more detail the dynamics of the landscape of the Three Lakes Region with a particular focus on the formation and degradation of mires. The Bernese part of the Three Lakes Region developed to become—after the optimisation of the water-levels of the Swiss Jura—the vegetable belt of Switzerland. The situation for agriculture, however, has now become critical due to an overexploitation of the peatland. Until c. 13 ka BP the entire region was hydrologically connected. An additional lake existed at the western end of the plain receiving sediments from the Aare river. Around 13 ka BP, this lake was isolated from the Aare river and completely silted up until c. 10 ka BP when a mire started to form. In the valley floor (‘Grosses Moos’), the meandering Aare and the varying level of the nearby lake of Neuchâtel caused a spatio-temporally patchy formation of mires (start of formation: 10–3 ka BP). Strong morphodynamics having high erosion and sedimentation rates and a high variability of the chemical composition of the deposited material prevailed during the early Holocene until c. 7.5 ka BP. The situation remained relatively quiet between 5 and 2 ka BP. However, during the last 2000 years the hydrodynamic and geomorphic activities have increased again. The optimisation of the Swiss Jura water-levels during the nineteenth and twentieth centuries enabled the transformation of moorland into arable land. As a consequence, the moorland strongly degraded. Mean annual C-losses in agricultural land are c. 4.9 t ha−1 and c. 2.4 t ha−1 in forests. Because forests limit, but not stop, the degradation of mires, agroforestry might be tested and propagated in future as alternative land-use systems for such sensitive areas.

The relationship between the spatial variability of soil elements, weathering and erosion rates can be very complex. Topography, abruptly-changing elevation gradients and slopes of varying geological composition exert an important influence on weathering trajectories and erosion. This complex interconnectivity is only rarely addressed in weathering studies. The main objectives of this investigation are, therefore, to relate weathering and erosion to various and geomorphic units in a dry-alpine and threshold landscape having steep slopes (Kan catchment, Tehran Province, Iran). A number of common weathering indices were tested using a genetic algorithm. The best indices are the (K + Na)/Ti ratio, the WIP (weathering index according to Parker), and the PI (product index according to Ruxton). However, the recently suggested 4Si-M+-R2 and M-F-Wmin systems discriminate weathering trends more accurately. Our results show that these soils have a low to moderate weathering stage. Weathering trajectories point to the active formation of kaolinite and oxyhydroxides. River sediments are slightly more weathered and contain the most-weathered topsoils and suggest erosion in the catchment is predominantly due to topsoil removal. Chemical weathering is influenced by the dominant geomorphic units (unconsolidated deposits of the Quaternary and solid bedrock) and landform features (combination of altitude and slope). Aspect does not appear to have a significant impact on weathering. Denudation (~erosion) rates were determined using meteoric 10Be since the fluvial sediments did not contain enough quartz for in situ 10Be analyses. This procedure has higher uncertainties due to difficulties in estimating the depositional flux of meteoric 10Be. Due to tectonic uplift, the erosion rates are very high. To maintain a soil layer, soil production rates must be also high. Although annual precipitation is relatively low, slope and soil dynamics seem particularly high, which leads to a fast turnover of the soil material and maintains the weathering intensity at a rather low to intermediate level.

Vast areas in the Mediterranean are characterised by evaporite deposits of the Messinian crises (c. 6–5.3 Ma BP). During this period, large deposits were built up in shallow lagoon-like systems and are now found in southern Italy, Albania, Cyprus and Turkey. So far, soil formation on evaporites has been studied predominantly in subarid to arid environments. Although the formation of soils has received new significance, little is known about the evolutional trajectories on evaporites of the Mediterranean. We therefore studied soil formation in the Caltanissetta basin (Sicily) where evaporites are most widespread. The lithologies included the sequence: marine clay deposits, laminated marl (diatomite; Tripoli sediments), Calcare di Base (limestone), detritic deposits, gypsum (selenite). The chemical signature (immobile elements, rare earth elements) indicated that they all have a similar origin. Surprisingly, both an increasing Corg and carbonate content in the soils caused a decrease in the δ 13C signal in carbonates and in part in the bulk soil. The low δ 13C and δ 18O values of carbonates in the parent material indicate a high rock-water (or meteoric water) interaction that has occurred during sedimentation and diagenesis. Organic matter was oxidised into the shallow lagoon-like systems and its carbon incorporated in the limestone. Elemental leaching from silicates during pedogenesis was most intense in the soils that developed on clays and Tripoli sediments. Vertisols and Mollisols have evolved, together with a high amount of oxyhydroxides (non-crystalline and crystalline forms) and kaolinite. Only weak soil formation was recognisable at sites having gypsiferous parent material. The presence of a high amount of selenite hindered a more advanced evolution. The soils developed on detritic and gypsiferous material exhibited some palygorskite that was inherited from the parent material. At sites having selenite or limestone, shallow Aridisols or Mollisols are found. Weathering is weakly pronounced, e.g. indicated by a high proportion of trioctahedral minerals. Besides inheritance from the parent material, smectite and kaolinite are also actively formed in the soils with increasing weathering. Plagioclase and mica are the main sources of smectite and K-feldspar is a main source of kaolinite neo-formation. The evaporite deposits vary greatly within short distances causing a high spatial diversity of soils. Consequently, soil quality strongly varies, which challenges agricultural use. Well-developed soil profiles and advanced weathering stages are only possible when marine clays, Tripoli sediments or detritic deposits are the parent material. Limestone (Calcare di Base) and gypsiferous sediments (selenite) strongly limit soil formation and mineral transformation.

Soil chronosequences in Alpine areas have often been applied to trace physical, mineralogical and chemical soil properties over time. How the soil pore system of undisturbed soils evolves, however, has not yet been clarified. We therefore investigated two soil chronosequences in the Swiss Alps spanning a time period from a few decades up to the Early Holocene/Late Pleistocene. One soil sequence developed on siliceous parent material in the Sustenpass (proglacial area of the Stein glacier), with soils aged from 30a to 10 ka while the second developed on calcaric parent material in the Klausenpass, with soils aged from 110a to 14 ka (proglacial area of the Griess glacier). We hypothesised that the overall pore size of the topsoil and consequently the relative proportion of macropores decrease with increasing soil age. The pore size characteristics were determined by using X-ray computed tomography. Independent of the parent material (calcareous vs siliceous), macroporosity decreased with time. The greatest changes seemed to occur between the Little Ice Age (LIA) and about 3–4 kyr of soil evolution. Vegetation composition and the functional richness of the plant community exert an influence on soils that developed on siliceous parent material by giving rise to more small pores. Besides pore sizes, pore characteristics also changed with time. In general, the tortuous structure of the soils became more complex with time. The evolution of the pore characteristics such as tortuosity, number and length of pore networks seem also to be related to biologic factors such as root properties, plant species and soil organic matter composition. It remains, however unanswered how these time-dependent biologic factors interact with and influence in detail the pore network. This aspect certainly merits investigation in greater detail in the future.

Recent studies have demonstrated that soils formed on pyroclastic ash deposits are much more common in the Mediterranean area than previously assumed. These soils are an important key to understanding past volcanic events and landscape evolution. Chronological information in soils of Quaternary volcanic events, however, remains still poorly understood in southern Italy. Using a multi-method forensic approach, we explore the origin and age of volcanic deposits (soils) in Sicily and Calabria. The geochemical signature of the soil was compared to the chemical fingerprint of the magmas of potential source areas of southern Italian volcanoes. The results indicate that the investigated soils on the Nebrodi (Sicily) and Sila (Calabria) mountains were both impacted by materials having a high-K calc-alkaline series volcanism. The Aeolian Islands (in particular Lipari and Vulcano) are the most likely source of origin, but contributions also from the Etna (particularly the Biancavilla ignimbrites and Plinian eruptions) occurred. Weathering and leaching processes, along with a potential contribution from the underlying non-volcanic bedrock, has altered the main chemical composition of soils, often precluding direct relation to potential source areas. Immobile elements and their ratios (e.g. the Nb/Y vs Zr/Ti plot) or trace elements (Co, Th) and rare earth elements (laser ablation ICP-MS analyses of glass particles, volcanic clasts and pumice-like materials) gave precious hints of the origin of the volcanic deposits. Radiocarbon dating of the H2O2 resistant soil organic fraction indicates a minimum age of 8–10 ka of the soils. The weathering index WIP (weathering index according to Parker) and the chemical composition of volcanic glasses and clasts were tested as proxies for the age of the volcanic deposits and time for soil formation. The soils and landscape are characterised by multiple volcanic depositional phases for the last about 50 ka in the Sila mountains and about 70 ka or more in the Nebrodi mountains. Chemical-mineralogical analyses enabled the detection of deposition phases during the Pleistocene and also Holocene. The multi-method approach enabled the identification of potential source areas, provided a tentative age estimate of the start (and in part duration) of ash deposits and therefore improved our understanding of volcanic landscape evolution.

The importance of gradual erosion relative to landsliding depends predominantly on the slope angle. One factor of critical influence in landsliding along with slope angle and slope shape is the soil depth. Understanding soil depth development on steep topography is fundamental for understanding and predicting the occurrence of landsliding at threshold landscapes. We develop a model to predict soil depth that addresses both threshold and gradual processes. If erosion is a gradual process, soil depth increases until the soil production rate no longer exceeds the erosion rate, and steady state is reached. The predicted soil depth (x) is proportional to the ratio of the infiltration to the erosion rate. Identifying a predictive result for erosion as a function of slope angle (S) allows a test of both the erosion and soil production models with field observations. The same theoretical approach to soil production should be applicable when the principal erosion process is shallow landsliding. After landslides, soil recovery initially follows our predicted power law increase in time, though with increasing time background erosion processes become important. At a time equal to a landslide recurrence interval, the soil depth can exceed the steady state depth by as much as a factor 2. By comparing predicted and observed x(S) results, we show that the accessed result for erosion as a function of slope angle is accurate. Soils deeper than the depth predicted at the landslide recurrence interval are beyond the stability limit. This result suggests an important practical relevance of the new soil production function.

At mid-latitudes, the transition from the Pleistocene to the Holocene was characterised by distinct and partially abrupt climatic changes. Also during the Holocene, climatic perturbations, with sometimes cold-dry conditions, have occurred. How land surfaces and soil development processes in high-mountains respond to these climatic oscillations is so far only poorly known. We traced the responses of surfaces in the alpine settings of the Wind River Range (Wyoming, US) by using a large mire as natural archive. This enabled us to reconstruct environmental conditions and ecosystem changes during the Holocene in this montane area. Although adjacent moraine deposits display 10Be exposure ages from the Last Glacial Maximum up to MIS16 or even older, the accessible sediment deposits covered only the Holocene (via radiocarbon dating). By applying a geoforensic approach and deriving sedimentation rates, major climatic signals were detected. A higher deposition (and consequently erosion) rate and thus a higher rate of geomorphic activity was measured for the known cold periods 9.4–10.2 ka BP, 4.2 ka BP and 2.5 ka BP. During the LIA, especially rapid aggradation of organic matter organic matter took place here. Rates of chemical weathering and soil formation seem to have been relatively low until about 5–6 ka BP but have since increased during the Late Holocene. This would fit previous observations of increasing moisture conditions after the mid-Holocene aridity period. In contrast to several other studies, no clear signs of major disturbances (erosion, weathering) during the 8.2 ka event could be observed. Together with the low levels of chemical weathering found here, we do not see any evidence that the climate was more humid during this period. Compared to previous findings, more humid conditions seemed to have returned earlier, i.e. about 5 kyr BP. In general, this landscape displayed a patchy pattern of reaction to environmental changes, as all events were not recorded in each mire profile., Geomorphology, 371, ISSN:0169-555x, ISSN:1872-695X

The European Alps are a geomorphologically active region and experience a number of gravity-driven hillslope processes. Soil and landscape formation in the Alps has consequently undergone several minor and major traceable changes of developmental trajectories during the Holocene. Soil development is hypothesised to be often non-linear with time and characterised by stages of progressive and regressive evolution caused by upbuilding (formation, profile deepening) and erosion (profile shallowing). Several cold and warm climate phases are identified during the Holocene but it is largely unknown which effects these might have had on slope processes. By using datable moraines ( 10 Be) and mires ( 14 C), we have constructed a temporal framework for these processes. Using the geochemical imprint of mires in the Alpine setting of the Goschener-valley of the Central Swiss Alps, we reconstructed general (mostly erosional) landscape processes for the last ca. 10 ka. As this is the type locality for the Goschener cold phase, we assumed that this phase (Goschener cold phase I and II ~ 1.5 and ~ 2.5 ka BP) should have left easily recognizable traits. After deglaciation (11–12 ka BP), soil evolution was progressive. Beginning around 8 ka BP, we detect a distinct increase in erosion here, together with a vegetation change (towards tundra vegetation) and the highest measured rates of carbon sequestration. Other phases of high geomorphic activity were recognised ca. 5–6 ka BP, 4 ka BP and, to a lesser extent, 1–3 ka ago. The cold phase at 5–6 ka BP corresponds to a less distinct change in vegetation and lessened erosion. Human impact is increasingly obvious since about 2.4 ka BP which overlaps with the Goschener cold phase. Nonetheless, erosion processes were not extraordinarily high during this period and a climate effect cannot be distinguished. We detect evidence of increasing human disturbance (regressive soil evolution) for about the last 1 ka. We also detect an increase in dust flux during the last ca. 4–5 ka, presumably due to the landscape change(s) in the Sahara during this time.

Purpose: The present work focuses on cold alpine soils of the Altai Mountains (Siberia, Russia). Permafrost is widespread and often occurs at a depth of about 100cm. The area is characterised by extremely cold winters and cool summers: the aim was consequently to find out whether weathering could be more intense on thermally less unfavoured conditions or whether the abundance of water could be a more important factor. Materials and methods: We investigated 10 soils in a very small area close to a local glacier tongue. Five of the investigated soils were south-facing and the other five north-facing. The soils have the same parent material (mica-rich till), altitude, topography and soil age. The vegetation is alpine grassland that is partially intersected with some juniper and mosses. Soil chemical properties such as organic C, N, soil organic matter quality (using DRIFT), pH value, (oxy)hydroxides, total elemental contents (XRF) and soil micromorphology and mineralogy (using diagnostic treatments and XRD) were determined. The age constraint of the site was given by geomorphic studies together with 14C dating of a nearby peat bog and the stable organic matter fraction of the soils. Results and discussion: The soils have a Holocene age. The results showed astonishingly clearly—similarly to the European Alps—that the north-facing soils have a higher weathering state. This is expressed by lower pH values, higher oxalate and dithionite extractable Fe, Al, Mn and Si contents, higher C and N concentrations and stocks when compared to the south-facing sites. No statistically significant differences with respect to weathering indexes could be detected. The geochemical evolution of the soils seems to be enhanced at north-facing sites, even though very severe climatic conditions prevail. Furthermore, biodegradation seems to be less pronounced on north-facing compared to south-facing sites as poorly degraded organic matter is accumulated. This gives rise to more organic ligands that promote metal binding and their subsequent eluviation along the soil profile. Conclusions: We consequently must assume that weathering is not limited by low temperatures in the active layer but is rather controlled by soil moisture that seems to be higher during the warmer period in the north-facing soils.

The aim of this work was to detect imprints on soil properties from former Islamic land use (9th to 11th century) using a multi-method, soil-chemical approach. Four soil profiles (with buried horizons) found in the vicinities of former Islamic settlements in Sicily were analysed for phosphorus (total, organic and inorganic), nitrogen (total, NO 3 − and NH 4 + ), carbon compounds (δ 13 C, lipids, polycyclic aromatic hydrocarbons (PAH) and functional groups), physical and chemical C-fractions and the state of soil weathering. Two soil profiles contained ceramic sherds from the Islamic period. Inorganic nitrogen forms, phosphorous and the PAH content indicated strong impacts from traditional agriculture and/or burning. Radiocarbon dating of soil organic carbon (SOC) fractions from buried horizons showed that distinct changes must have occurred during the Islamic epoch. The isotopic composition of SOC indicated that land use was probably different in earlier times. C 4 plant cultivation was expected but surprisingly lipid analyses did not confirm this. A high amount of aliphates and low C/N ratio indicated a good, long-term SOC stabilisation under the native conditions combined with Islamic land use. The irrigation of the soils probably increased the production of weakly-crystalline Fe forms that helped to stabilise SOC. The multi-method approach was very helpful in deciphering human-induced processes. Although a full proof for each parameter is not given, former Islamic land-use seems to have distinctly affected the soils – not only locally but probably also in other areas of Sicily, Northern Africa, Near East and Iberian Peninsula.

An important result of the past few decades of soil–geomorphic research is the awareness of the major role of dust and related carbonate precipitates in arid soils. The temporal evolution of soils developed on outwash terraces is still a matter of debate particularly regarding the type of evolution: progressive evolution and constant rates vs complex and/or interval-accumulation rates (progressive or regressive evolution possible). Soils on a chronosequence of outwash terraces just outside and downstream of canyon mouths of the Wind River Range (USA) were analysed for carbonate accumulation, organic carbon and poorly-crystalline pedogenetic oxyhydroxides stocks and pathways of chemical weathering. The soils and their carbonate stocks in the fine earth fraction (< 2 mm) can be used as a relative dating tool and appear to correlate with regional glacial chronostratigraphy [Pinedale (c. 20 ky), Bull Lake (with two different units around 160 and 260 ky) and Sacagawea Ridge (c. 660 ky)]. Carbonate stocks of soils on these terraces increase with increasing soil age, but at generally decreasing rates. A quasi-steady state situation, however, was not reached before 1 My. The time-split approach showed that CaCO3 accumulation rates were the highest during marine isotope (MIS) cold stages (2.13 g CaCO3/m2/y), presumably due to a sparse vegetation cover during MIS2 (Pinedale) and 8 (lower Bull lake). Compared to organic carbon (c. 8–10 kg Corg/m2), the inorganic carbon stocks of the fine earth fraction were much higher (c. 60 kg Cinorg/m2). Although the dominant pedogenic process here appears to be carbonate accumulation, chemical weathering and elemental leaching also are significant. Weathering data were obtained using immobile elements and rare earth elements (REE) as tracers. Chemical weathering and related leaching were particularly notable for Na originating from plagioclase. In addition, pedogenetic Al and Mn oxyhydroxides accumulate (220 and 32 g/m2, respectively, after 660 ky). These form at relatively low rates, however, when compared to moister and cooler conditions at higher altitudes in the Wind River Range. Due to the dry climate under which the terrace soils formed (annual precipitation 32 cm/yr− 1), weakly crystalline and amorphous Fe-oxyhydroxide is rapidly transformed into crystalline forms (hematite) over time. Consequently, the stocks of weakly crystalline and amorphous Fe-oxyhydroxide was significantly lower in the ~ 660 ky soils (50 g/m2) than in the Holocene soils (1000 g/m2). The development of soils on Quaternary outwash terraces in this region is controlled through the rates of aeolian influx over time as modified by glacial/interglacial climate variations rather than by moisture availability. Consequently, carbonate accumulation rates in these soils are ‘influx limited’ rather than ‘moisture limited’.

In this study we compare newly-developed chemical weathering data with previously published data from soils developed along two chronosequences of glacial deposits in the European Alps and the Rocky Mountains (Wind River Range, USA). By combining these chronosequences, we are able to present a comprehensive dataset that represents a time period of > 1 Ma. We describe weathering trends of important elements using a number of weathering indices (e.g., K + Ca/Ti ratio, the weathering ‘index B’ of Kronberg and Nesbitt (1981) and the open mass transport function). Further, we describe the accumulation of Al, Fe, Si and Mn oxyhydroxides (including partially organic phases) as a function of time, and derive the corresponding accumulation rates. We calculated pedogenetically formed oxyhydroxides using an approach based on immobile elements. Our study represents one of only a few studies that describe rates of soil chemical weathering over a period as long as ~ 1 Ma. Results show that rates of chemical weathering clearly decrease along the chronosequences with increasing age of the soils. We find weathering rates are nearly four orders of magnitude lower in the 1 Ma-old soils than in the young soils. Our results suggest that the older soils may be reaching a steady state for these chemical properties in their present environments. A power function best explains the measured time-trends of the ‘index B’ and (K + Ca)/Ti) ratios in the soils. The best time-trend model for pedogenic weakly- to poorly crystalline phases and the relative losses/gains (based on the open-system mass transport function) were obtained with an exponential decay model function. In terms of the soil system, the decreases in the accumulation rate of the oxyhydroxides appears to be influenced not only by the factor of time but by climate as well (increased precipitation at higher altitudes slows the decrease in weathering rate over time). Thus, our ~ 1 Ma chronosequences also become pedogenic gradients since we describe variations in soil properties along biogenic gradients.

Peat and lake sediments as well as a nearby soil catena were sampled to reconstruct the environmental history of a small infilled lake basin (mire) in the central alpine foreland of Switzerland. Soil evolution is best regarded as discontinuous over time and conceptualised by ‘progressive’ or ‘regressive’ process phases. We analysed the surrounding soils and used corresponding pedosignatures in the mire sediments to characterise notable phases of erosion and deposition. We assumed that the mire sediments would reflect these phases, that elemental composition (major and minor compounds) and rare earth elements (REEs) would allow us to differentiate past processes and that progressive and regressive phases of soil development can be discerned. Although radiocarbon ages are equivocal, it appears from pollen analyses that a lake was present here by c. 45 ka BP. After the retreat of the glacier from this area following the LGM, continuous sedimentation occurred until a mire developed during Pleistocene–Holocene transition. This transition period was accompanied by more intense erosion, as characterised by chemical signatures. A stable phase developed between c. 10–5 ka BP giving rise to progressive soil evolution. Between 5 and 4 ka BP, evidence appears for several erosional phases, predominantly detectable at the margin of the mire. These erosion phases, coupled with accumulation in the mire, are even more evident after 4 ka BP and especially after 2.1 ka BP. Based on soil investigations, elemental fluxes are detected along the slopes with distinct accumulations at the footslope. Evidence for anthropogenic influences and subsequent regressive soil formation phases appear in this pre-alpine landscape about 5 ka BP (Neolithic/Early Bronze Age), which appears to intensify after 2.1 ka BP (Roman period to present). Multi-elemental signatures enabled us to identify the important geochemical processes that have occurred here. Together with radiocarbon and pollen analyses, we placed these processes in a logical temporal context. The use of lacustrine (lake or mire) sediments has great potential to decipher and detail the surrounding landscape history and soil evolution of this region of Switzerland.

At middle to high latitudes, many alpine valleys have been shaped by glaciers associated with periods of Pleistocene glaciation. Present glaciated valleys are characterised by broadened valley floors and U-shaped cross sections, continuously formed by glacial activity from initially V-shaped, fluvial cross sections. Sinks Canyon (Wind River Range, USA) is a glaciated valley characterised by a typical U-shaped cross section, containing till from several glacial advances over a range of at least 1 Ma. The morphostratigraphic records indicate a fourfold difference in ice surface elevation between the youngest and oldest glacial periods, which is not easily explained by the present-day valley topography. To assess possible evolution scenarios of Sinks Canyon, we modelled the palaeovalley topography using a geographic information system (GIS) filtering technique in combination with temporal reference points from relative and numerically dated glacial deposits. Ice thicknesses were calculated using the shallow ice approximation. In our model, the valley became shallower and the topography smoother with increasing years back in time. The results suggest that valley topography with ages between 640 and 1000 ka can clearly be distinguished from the present-day topography. Surfaces with ages of 130–200 ka (attributable to MIS 6; Bull Lake glaciation) still could be discerned from present-day topography, but with relatively high uncertainties. The method did not work for topography less than ~ 100 ka or older than ~ 1 Ma. Erosion depths were calculated using the differences between present-day elevation and the modelled surfaces. Calculated erosion rates were within the range of reference values for glacial erosion (0.001 to 1 mm a− 1). Glacial erosion appears to have removed 0.52 to 0.72 mm a− 1 of rock within a time frame of 1 Ma, assuming 200 ka of aggregated glacial flow. If the glacial occupation was longer or the impact of fluvial erosion was not negligible (as assumed), then the calculated rate is lower. If the model assumes a less extended time of glacial flow (< 100 ka), the rate exceeds 1 mm a− 1. The method used for surface reconstruction and erosion rates calculation is highly dependent on (i) the reliability of the temporal anchor points and (ii) the assumption of physical glacier conditions (basal shear stress).

High-mountain soils develop in particularly sensitive environments. Consequently, deciphering and predicting what drives the rates of soil formation in such environments are a major challenge. In terms of soil production or formation from chemical weathering, the predominating perception for high-mountain soils and cold environments is often that the chemical weathering ‘portion’ of soil development is temperature-inhibited, often to the point of non-occurrence. Several concepts exist to determine long-term rates of soil formation and development. We present three different approaches: (1) quantification of soil formation from minimally eroded soils of known age using chronosequences (known surface age and soil thickness — SAST), (2) determination of soil residence times (SRT) and production rates through chemical weathering using (un)stable isotopes (e.g. 230 Th/ 234 U activity ratios), and (3) a steady state approach using cosmogenic isotopes (e.g. 10 Be). For each method, data from different climate zones, and particularly from high-mountaINS (alpine environment), are compared. The SAST and steady state approach give quite similar results for alpine environments (European Alps and the Wind River Range (Rocky Mountains, USA)). Using the SRT approach, soil formation rates in mountain areas (but having a temperate climate) do not differ greatly from the SAST and steady state approaches. Independent of the chosen approach, the results seem moderately comparable. Soil formation rates in high-mountain areas (alpine climate) range from very low to extremely high values and show a clear decreasing tendency with time. Very young soils have up to 3–4 orders of magnitude higher rates of development than old soils (10 5 to 10 6 yr). This apparently is a result of kinetic limits on weathering in regions having young surfaces and supply limits to weathering on old surfaces. Due to the requirement for chemical weathering to occur, soil production rates cannot be infinitely high. Consequently, a speed limit must exist. In the literature, this limit has been set at about 320 to 450 t/km 2 /a. Our results from the SAST approach show, however, that in alpine areas soil formation easily reaches rates of up to 800–2000 t/km 2 /a. These data are consistent with previous studies in mountain regions demonstrating that particularly young soils intensively weather, even under continuous seasonal snowpack and, thus, that the concept of ‘temperature-controlled’ soil development (soil-forming intervals) in alpine regions must be reconsidered.

Current climatic conditions and the occurrence of discontinuous and sporadic permafrost in the Alps result in a low turnover rate and therefore accumulation of organic matter (OM) in soils. Alpine soils are thus highly sensitive to global warming that potentially promotes the mineralisation of soil organic matter (SOM). This process might increase the release of CO2 to the atmosphere. Our aim was to investigate the potential effect of permafrost thawing by the analysis of the physical–chemical soil properties of permafrost versus non-permafrost sites. Specifically, we i) quantified the SOM stocks at such sites, ii) characterised SOM and its physical and chemical fractions and iii) estimated the age range of the bulk soil and stable C-fraction (radiocarbon dating). In south-eastern Switzerland, two areas above the timberline and one below the timberline (where isolated permafrost was verified) were investigated in detail. At each site, the experimental set-up consisted in the comparison of nearby soils that were either influenced or not by permafrost. The C-stocks (down to the C horizon or rock surface) did not show a significant difference between permafrost and non-permafrost soils and were in the same range of 10–15 kg/m2 in alpine (grassland) and subalpine (forest) sites. Above the timberline, the bulk SOM showed a distinct higher age at permafrost sites compared to non-permafrost sites. This higher age was even more evident in the stable C-fraction (resistant to an H2O2 treatment), where ages of up to 11 ky in permafrost soils were recorded. The highest age obtained in the stable C-fraction in non-permafrost soils was around 4 ky. Consequently, climatic conditions and the occurrence of discontinuous permafrost resulted in a very low turnover rate of SOM. At the subalpine site, the difference between permafrost and non-permafrost sites was less. At both sites (alpine and subalpine), DRIFT (Diffuse Reflection Infrared Fourier Transform) was used to determine the functional groups in the bulk soil and in the stable C-fraction. In general, the stable C-fraction had a different composition compared to the bulk SOM at non-permafrost sites; this was mostly not the case at the permafrost sites. This confirms that different decomposition processes occur between permafrost and non-permafrost sites. Furthermore, permafrost sites accumulated more the low-density physical fractions of SOM that are potentially easily degradable. The obtained results suggest that a warmer climate may not necessarily lead to an increased CO2 release from SOM-degradation in permafrost soils compared to non-permafrost soils. High-alpine soils and OM furthermore integrate a multi-facetted response to the past and ongoing surrounding conditions. The melting of permafrost will most likely enhance vegetation growth, which to a certain degree will probably compensate for carbon losses on the long-term.

As a consequence of global warming, additional areas will become ice-free and subject to weathering and soil formation. The most evident soil changes in the Alps will occur in proglacial areas where young soils will continuously develop due to glacier retreat. Little is known about the initial stages of weathering and soil formation, i.e. during the first decades of soil genesis. In this study, we investigated clay minerals formation during a time span 0–150 years in the proglacial area of Morteratsch (Swiss Alps). The soils developed on granitic till and were Lithic Leptosols. Mineralogical measurements of the clay ( The detected clay mineral formation and transformation mechanisms within this short time span confirmed the high reactivity of freshly exposed sediments, even in a cryic environment.

Many soils in southern Switzerland have a black color, contain a large amount of soil organic matter (SOM) and seem to have some andic properties although they did not develop on volcanic parent material. We investigated three typical 'black' soils to determine the mechanisms of (clay) mineral formation and transformation. We measured total element pools as well as the dithionite-, pyrophosphate-and oxalate-extractable fractions (Fe, Al, Si). The clay fraction (

A comparison was made between two soil climosequences on north- and south-facing slopes in northern Italy to determine the influence of slope aspect on soil processes. The climosequences span an elevational gradient ranging from moderate (1200 m a.s.l.) to high alpine (2420 m a.s.l.) climate zones on surfaces having an age of about 15 000 years. The soils were investigated with respect to organic C, oxalate and dithionite extractable Fe, Al and Si, elemental losses (Ca, Mg, K, Na, Fe, Al, Si, Mn) and clay minerals. The stocks of soil org. C as well as of oxalate-extractable Fe and Al was greatest in the subalpine zone near the timberline. There are no clear differences in organic C content between the soils on north- and south-facing sites. Fe-oxalate and to a lesser extent Alo-stocks were, however, greater on north-facing sites, indicating that weathering is greater there. Eluviation and illuviation of Al and Fe within the soil profile, typical for podzolisation, was more distinctly expressed on the N slopes. The probability of ITM (Imogolite-type-material) formation in the soil seemed to be greater on south-facing sites. On the north-facing sites, element leaching was most intense in the subalpine zone close to the timberline while on the south-facing sites this was only the case for the base cations. The N slopes exhibited higher leaching of elements which generally indicates a higher weathering intensity. On south-facing sites, typical podzolisation processes were measurable only above 2000 m a.s.l. The development of smectites is also a reflection of the weathering intensity; smectite was discernible in the surface horizon at all sites on N slopes but the highest amount was detected in the sub-alpine climate zone. For the south-facing sites only in the alpine climate zone could smectite be detected. Higher temperatures and an increased number of freeze-thaw cycles on south-facing slopes should theoretically enhance rates of chemical weathering. This could, however, not be confirmed with our measurements. The degree of chemical weathering increases from the south- to the north-facing sites that are characterised by lower temperatures, lower evapotranspiration and consequently by a higher humidity. Although precipitation in Alpine regions is abundant, the availability and flux of water through the soil is the prime factor in weathering intensity.