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Purpose Adsorbent amendment to contaminated sediments is one in situ remediation method to decrease the bioaccessibility of pollutants from the sediments. In this work, alkali-activated blast furnace slag (BFS) granules were used in a field experiment at Lake Kivijärvi (Finland). The lake was heavily affected by a mining accident in 2012, which released a significant peak load of metals and sulfate. The purpose of this work was to evaluate the performance of the novel amendment material for in situ remediation in real conditions with a preliminary cost estimation. Methods Alkali-activated BFS granules were prepared and characterized for composition, microstructure, and surface properties. Two mesocosms were placed in the lake: one with granule dosing and another without. Sediment and pore water samples were collected after a two-week period. Similar small-scale experiment was performed in laboratory with a three-month duration. Bioaccessibility of metals from sediments was assessed with a three-stage leaching procedure. Results The granules were effective in decreasing the mobility of Fe, Zn, Ni, and Cr in all leaching stages by approximately 50–90% in comparison with unamended sediment in the mesocosm experiment. Laboratory-scale incubation experiments also indicated decreased release of Ba, Co, Ni, Al, Fe, Mg, Mn and S. The estimated material costs were lower than the removal of the contaminated sediments with dredging and off-site treatment. Conclusion The results showed preliminarily the effectiveness of alkaline-activated BFS in the remediation of metal-contaminated sediments in a field experiment. However, topics requiring further study are the leaching of trace elements from the material and impact on the sediment pH.

Peracetic acid (PAA) in combination with transition metals has recently gained increasing attention for organic micropollutant abatement. In this study, aqueous Co(II), Cu(II), and Ag(I) were compared for their capacity to activate PAA. Co(II) outperformed Cu(II) or Ag(I) and the optimum conditions were 0.05 mM of Co(II), 0.4 mM of PAA, and pH 3. However, due to a wider applicability in water treatment, pH 7 (i.e., bicarbonate buffer) was selected for detailed investigations. The abatement of different micropollutant surrogates could be described with a second-order rate equation (observed second-order rate constants, kobs were in the range of 42–132 M⁻¹ s⁻¹). For the para-substituted phenols, there was a correlation between the observed second-order rate constants of the corresponding phenolates and the Hammett constants (R² = 0.949). In all oxidation experiments, the reaction rate decreased significantly after 1–2 min, which coincided with the depletion of PAA but also with the deactivation of the Co(II) catalyst by oxidation to Co(III) and subsequent precipitation. It was demonstrated that Co(II) immobilized on a geopolymer-foam performed approximately similarly as aqueous Co(II) but without deactivation due to Co(III) precipitation. This provides a potential option for the further development of heterogeneous catalytic Co(II)/PAA advanced oxidation processes utilizing geopolymers as a catalyst support material.

In this work, we compared the main characteristics of highly porous geopolymer components for water treatment applications manufactured by 3D printing, direct foaming, or granulation. Furthermore, different approaches to impregnate the materials with Ag or Cu were evaluated to obtain filters with disinfecting or catalytic properties. The results revealed that all of the investigated manufacturing methods enabled the fabrication of components that possessed mesoporosity, suitable mechanical strength, and water permeability, even though their morphologies were completely different. Total porosity and compressive strength values were 28 vol% and 16 MPa for 3D-printed, 70–79 vol% and 1 MPa for direct-foamed, and 27 vol% and 10 MPa for granule samples. Both the filter preparation and the metal impregnation method affected the amount, oxidation state, and stability of Ag and Cu in the filters. However, it was possible to prepare filters with low metal leaching between a pH of 3–7, so that the released Ag and Cu concentrations were within drinking water standards.

Alkali-activation (or geopolymer) technology has gained a great deal of interest for its potential applications in water and wastewater treatment during the last decade. Alkali-activated materials can be prepared via a relatively simple and low-energy process, most commonly by treating aluminosilicate precursors with concentrated alkali hydroxide and/or silicate solutions at (near) ambient conditions. The resulting materials are, in general, amorphous, have good physical and chemical stability, ion-exchange properties, and a porous structure. Several of the precursors are industrial by-products or other readily available low-cost materials, which further enhances the environmental and economic feasibility. The application areas of alkali-activated materials in water and wastewater treatment are adsorbents/ion-exchangers, photocatalysts, high-pressure membranes, filter media, anti-microbial materials, pH buffers, carrier media in bioreactors, and solidification/stabilization of water treatment residues. The purpose of this review is to present a comprehensive evaluation of the rapidly growing prospects of alkali-activation technology in water and wastewater treatment.

Geopolymers have been recently explored as sorbents for wastewater treatment, thanks to their mechanical and chemical stability and to their low-energy manufacturing process. One specific application could be the removal of ammonium (NH4+) through exchange with Na+ ions. Additive manufacturing (AM) represents an especially interesting option for fabrication, as it allows to tailor the size, distribution, shape, and interconnectivity of pores, and therefore the access to charge-bearing sites. The present study provides a proof of concept for NH4+ removal from wastewater using porous geopolymer components fabricated via direct ink writing (DIW) AM approach. A metakaolin-based ink was employed for the fabrication of a log-pile structure with 45° rotation between layers, producing continuous yet tortuous macropores which are responsible for the high permeability of the sorbents. The ink consolidates in an amorphous, mesoporous network, with the mesopores acting as preferential sites for ion exchange. The printed sorbents were characterized for their physicochemical and mechanical properties and the NH4+ removal capacity in continuous-flow column experiments by using a model effluent. The lattices present high permeability and high cation exchange capacity and maintained a high amount of active ions after four cycles, allowing to reuse them multiple times.

Geopolymers resemble conventional ceramics but can be manufactured at near-ambient temperatures. In this work, geopolymer–bentonite composite foam with silver nanoparticles was prepared and applied for water disinfection, inspired by point-of-use ceramic water filters. The inactivation efficiency against Escherichia coli and intestinal enterococci bacteria was found to be promising (0.6–2.4 and 0.3–1.4 log₁₀ reductions, respectively) for ∼1 d. However, the inactivation efficiency against somatic coliphage viruses was poor (

The aim of this study was the valorization of paper sludge waste from paper industry in designing one-part geopolymer cement using ground granulated blast furnace slag as main precursor. The effects of increasing the amount of paper sludge pretreated with a constant amount of sodium hydroxide (2% of slag) on mechanical strength, heat evolution, setting time and durability were analyzed. The reaction products were characterized using X-ray diffraction and thermogravimetric analysis. The findings showed that paper sludge can successfully be used as a secondary source of calcium carbonate in the one-part (“just add water”) geopolymer. The compressive strength of the cured geopolymer increased with increasing the amount of paper sludge, and the non-reacted sludge acted as a filler. The maximum strength (42 MPa, 28 d) was reached at 18 wt-% paper sludge addition. The main reaction products were calcium aluminate silicate hydrate and hydrotalcite-like cementitious gels. From the perspective of its blast-furnace slag content, strength properties, water absorption and setting time, the one-part geopolymer cement could be classified as a CEM IIIC and Type 32.5N class cement under the European standard EN-197.

Alkali-activated materials (AAM) are recognized as potential alternatives to ordinary Portland cement (OPC) in order to limit CO2 emissions as well as beneficiate several wastes into useful products. However, the alkali activation process involves concentrated aqueous alkali solutions, which are corrosive, viscous, and, as such, difficult to handle and not user friendly. Consequently, the development of so-called one-part or “just add water” AAM may have greater potential than the conventional two-part AAM, especially in cast-in-situ applications. One-part AAM involves a dry mix that consists of a solid aluminosilicate precursor, a solid alkali source, and possible admixtures to which water is added, similar to the preparation of OPC. The dry mix can be prepared at elevated temperatures to facilitate the reactivity of certain raw materials. This review discusses current studies of one-part AAMs in terms of raw materials, activators, additives, mechanical and physical properties, curing mechanisms, hydration products, and environmental impacts.

Geopolymers are functional materials that can be used in various environmental applications such as adsorbents in pollutant removal from wastewaters. Metakaolin geopolymer (MK-GP) has been proven to be especially suitable for ammonium (NH4 +) removal. In this research, the optimal reagent and raw material ratios in the preparation of MK-GP in terms of NH4 + adsorption capacity were investigated. The response surface methodology based on the face-centered central composite design was used to optimize the levels of three factors: the amounts of hydroxide, silicate, and metakaolin. In addition, the effect of Na or K as the charge-balancing cation was studied. Empirical models were fitted to the experimental data using multiple linear regression. The significance of the models was confirmed by means of analysis of variance. Optimal NH4 + removal efficiency was achieved when the amounts of hydroxide and silicate were maximized, the amount of metakaolin was minimized, and Na-based reagents were used. These trends are most likely a result of optimized conversion of metakaolin into MK-GP.

Soapstone is a soft, magnesium-rich mineral widely used in the production of carved objects and architectural elements, for instance. The processing of soapstone causes the formation of significant amounts of waste powder, which is largely landfilled at the moment. The aim of the present study is to evaluate the suitability of soapstone waste as the main binder for the alkali-activation process using sodium silicate and hydroxide solutions as activators. The results demonstrate that soapstone alone reacts to some extent (compressive strength of 13 MPa at 28 day age), but mechanical properties are improved significantly after replacing 20% of soapstone by metakaolin (compressive strength of 31 MPa at 28 d age). The obtained mechanical properties are closely similar to those of virgin soapstone. Durability properties of the developed alkali-activated binders were similar or better than typical Portland cement-based binders in terms of high temperature, acid, and freeze-thaw resistance, and sorptivity. The material costs alkali-activated soapstone mortar were estimated as approximately 70 €/t. Thus, the results enable utilizing currently underexploited soapstone waste in a sustainable and economically interesting way.

Alkali-activated materials are a low-CO2 alternative for Portland cement in construction. However, one major issue in their use is the poor or varying functionality of the currently available commercial superplasticizers. Especially for one-part (‘just add water’) alkali-activated materials, the number of studies is limited. In this study, one-part alkali-activated mortar was prepared from blast furnace slag by using solid sodium hydroxide as an activator and microsilica as an additional silica source. Comparison of commonly used superplasticizer types revealed that lignosulfonate, melamine, and naphthalene-based superplasticizers are more efficient than the currently most used polyacrylate and polycarboxylate-superplasticizers. Lignosulfonate-based superplasticizer was overall best-performing: it improved significantly the workability (+41% spread, −51% yield stress, −27% viscosity), setting time (+70%), and compressive strength (+19%) at a 0.5 wt% dose. When the amount of water and superplasticizer were optimized, compressive strength of mortar could be doubled (from 19 to 40 MPa at 28 d).

Blast-furnace slag and metakaolin were geopolymerised, modified with barium or treated with a combination of these methods in order to obtain an efficient SO4(2-) sorbent for mine water treatment. Of prepared materials, barium-modified blast-furnace slag geopolymer (Ba-BFS-GP) exhibited the highest SO4(2-) maximum sorption capacity (up to 119mgg(-1)) and it compared also favourably to materials reported in the literature. Therefore, Ba-BFS-GP was selected for further studies and the factors affecting to the sorption efficiency were assessed. Several isotherms were applied to describe the experimental results of Ba-BFS-GP and the Sips model showed the best fit. Kinetic studies showed that the sorption process follows the pseudo-second-order kinetics. In the dynamic removal experiments with columns, total SO4(2-) removal was observed initially when treating mine effluent. The novel modification method of geopolymer material proved to be technically suitable in achieving extremely low concentrations of SO4(2-) (

Geopolymers are aluminosilicate compounds that are amorphous analogues of zeolites, and thus possess similar cation-exchange properties. Geopolymers have been successfully applied to remove toxic metals and organic dyes from aqueous solutions. In this study, geopolymer was synthesized from metakaolin and applied to remove ammonium (NH 4 + ) from model solutions and landfill leachate. Geopolymerization increased the ammonium removal capacity, surface area and average pore width and changed the chemical structure of metakaolin. The maximum NH 4 + removal capacity of the geopolymer was 21.07 mg g − 1 which was 46% higher than the capacity of the reference clinoptilolite–heulandite zeolite (14.42 mg g − 1 ). The adsorption data of the geopolymer and zeolite fitted best to the Langmuir–Freundlich isotherm and the removal kinetics followed the pseudo-second order kinetic equation. The spent geopolymer adsorbent was regenerated efficiently using 0.2 M NaCl and 0.1 M NaOH as a regenerant. A small-scale continuous field experiment with landfill leachate was performed and further indicated that the metakaolin-based geopolymer could be a feasible NH 4 + removal adsorbent.

Alkali-activated materials (AAMs) are one of the alternative low-CO2 binders. One-part AAMs, (that is, mixing a solid precursor with a solid alkali activator and adding water) have recently attracted increasing interest. The purpose of this study is to examine if fast-dissolving solid synthetic sodium metasilicate could be replaced by a combination of sodium hydroxide and slow-dissolving silica derived from rice husk ash or microsilica in the preparation of one-part alkali-activated blast furnace slag mortar. The replacement would improve the carbon footprint and the cost efficiency of the binder. The results demonstrate that silica availability significantly affects compressive strength development as a function of time or mixture composition. The highest compressive strength (107 MPa, 28 d) was obtained with fast-dissolving silica. Furthermore, setting times could be adjusted based on the mix composition, and the durability of mortar remained good after 120 freeze–thaw cycles. The results highlight the overall effect of silica availability on the fresh and hardened properties of one-part AAMs.

Ammonium (NH₄⁺) removal from municipal wastewater poses challenges with the commonly used biological processes. Especially at low wastewater temperatures, the process is frequently ineffective and difficult to control. One alternative is to use ion-exchange. In the present study, a novel NH4+ ion-exchanger, metakaolin geopolymer (MK-GP), was prepared, characterised, and tested. Batch experiments with powdered MK-GP indicated that the maximum exchange capacities were 31.79, 28.77, and 17.75 mg/g in synthetic, screened, and pre-sedimented municipal wastewater, respectively, according to the Sips isotherm (R² ≥ 0.91). Kinetics followed the pseudo-second-order rate equation in all cases (kp₂ = 0.04–0.24 g mg⁻¹ min⁻¹, R² ≥ 0.97) and the equilibrium was reached within 30–90 min. Granulated MK-GP proved to be suitable for a continuous column mode use. Granules were high-strength, porous at the surface and could be regenerated multiple times with NaCl/NaOH. A bench-scale pilot test further confirmed the feasibility of granulated MK-GP in practical conditions at a municipal wastewater treatment plant: consistently

Mineral wools –a general term for stone wool and glass wool– are the most common building insulation materials in the world. The annual amount of mineral wool waste generated in Europe totaled 2.3 Mt in 2010 – including wastes from the mineral wool production and from the construction and demolition industry. Unfortunately, mineral wools are often considered unrecyclable due to their fibrous nature and low density. Thus, the utilisation of post-consumer mineral wool waste in different applications remains low. Mineral wools have a great potential as geopolymer precursors as they have suitable chemical and mineralogical compositions. As geopolymers can provide significant CO2 emission reductions compared to traditional Portland cement concretes, using mineral wool waste as geopolymer precursor would be an attractive utilisation path. Here, we show that mineral wool waste can be geopolymerised to form sustainable cements with good mechanical properties. Geopolymerisation of mineral wool waste therefore offers an attractive route for waste valorisation and production of low-CO2 cements.

The mining industry is a major contributor of various toxic metals and metalloids to the aquatic environment. Efficient and economical water treatment methods are therefore of paramount importance. The application of natural or low-cost sorbents has attracted a great deal of interest due to the simplicity of its process and its potential effectiveness. Geopolymers represent an emerging group of sorbents. In this study, blast-furnace-slag and metakaolin geopolymers and their raw materials were tested for simultaneous removal of Ni(II), As(III) and Sb(III) from spiked mine effluent. Blast-furnace-slag geopolymer proved to be the most efficient of the studied materials: the experimental maximum sorption capacities for Ni, As and, Sb were 3.74 mg/g, 0.52 mg/g, and 0.34 mg/g, respectively. Although the capacities were relatively low due to the difficult water matrix, 90–100% removal of Ni, As, and Sb was achieved when the dose of sorbent was increased appropriately. Removal kinetics fitted well with the pseudo-second-order model. Our results indicate that geopolymer technology could offer a simple and effective way to turn blast-furnace slag to an effective sorbent with a specific utilization prospect in the mining industry.