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The Xinxing granitic pluton is a large batholith cropping out in southern South China with its long axis parallel to the regional NE–trending faults. We conduct the first comprehensive study of zircon laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) U–Pb chronology and trace element chemistry, rock-forming mineral chemistry and whole-rock element and Sr–Nd isotope geochemistry for this pluton. Our new data indicate that the pluton was emplaced during the interval 234–232 Ma, i.e. early Indosinian rather than late Mesozoic as previously considered. The southern pluton consists of syenogranite and monzogranite, which are composed of K-feldspar, oligoclase, quartz and ferri-biotite. The northern pluton consists of monzogranite and granodiorite, which are composed of andesine, K-feldspar, quartz and magnesio-biotite. The southern granites have high SiO2 contents (72.5–79.2 wt%) and high FeOT/(FeOT + MgO) (T refers to total) ratios with low Mg# [atomic Mg/(Mg + FeT)]. They are enriched in rare earth elements and depleted in Sr and Ba with Zr + Y + Ce + Nb >350 ppm and 10,000 × Ga/Al >2.6. Their initial magma temperatures are unusually high (>886 °C). All those features strongly suggest an affinity with A-type granites. The northern granites have lower SiO2 contents (63.4–72.5 wt%) and lower FeOT/(FeOT + MgO) ratios as well as higher Mg# than the southern granites. They are also enriched in rare earth elements and depleted in Sr and Ba, with high Ga/Al ratios and high Zr + Y + Ce + Nb contents. Geochemical data and major element modeling confirm that the southern A-type granites were generated by the moderate degree (~49%) shallow (ca. 15–20 km depth) dehydration melting of the early Paleozoic granitoids triggered by intraplating of basaltic magmas. Subsequent moderate degree (~57%) fractionation of such crustal melts produced the more felsic granites in the southern pluton, whereas subsequent mixing of such crustal melts with about 8 to 48% intraplated mafic magmas generated the less felsic granites in the northern pluton. Interaction of mafic magmas with A-type crustal melts causes the northern granites to lose some diagnostic geochemical features of A-type granites such as high FeOT/(FeOT + MgO) ratios and to be transitional towards I-type granites. We further suggest their origin to have been related to the transtension of the regional NE–trending strike-slip faults coupled with the early Indosinian continental collisions. [ABSTRACT FROM AUTHOR]

Late Paleozoic granites have rarely been reported in South China. We present the first detailed zircon laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U-Pb dating and in situ Hf isotopic and whole-rock element geochemical and Sr-Nd isotopic data for two late Permian granitic plutons (Napeng and Shicun) recently identified in the Yunkai massif, South China. In addition, we assess their origin and relationship to the geodynamics of late Paleozoic to early Mesozoic magmatism in South China. The Napeng pluton consists of cordierite- and/or garnet-bearing biotite granites, and the Shicun pluton is composed of two-mica granites and muscovite granites. Detailed LA-ICP-MS zircon U-Pb dating shows that both plutons were emplaced in the late Permian and contain abundant inherited zircons with a spread of ages, including Neoarchean-Paleoproterozoic, Neoproterozoic-Cambrian, Ordovician-Silurian, Devonian, Carboniferous, and early Permian. The cordierite- and/or garnet-bearing biotite granites are strongly peraluminous and have higher maficity than experimental melts of metasedimentary rocks. Both the two-mica and muscovite granites are also strongly peraluminous but have similar maficity to experimental melts of metasedimentary rocks. All the granites have high initial 87Sr/86Sr, negative ε Nd(t), and ε Hf(t) (in situ zircon). Detailed petrographic and geochemical characteristics of the studied granites suggest that they are S-type granites and were formed by partial melting of subducted oceanic sediments of the eastern Paleo-Tethys Ocean within the depth of mantle region to normal lower crust in the continental collision zone. Our new data suggest that the origin of the Napeng and Shicun granites might mark the onset of the continental collision between the Indochina and South China Blocks with the initial closure of the eastern Paleo-Tethys Ocean at the beginning of the late Permian. [ABSTRACT FROM AUTHOR]

The origin of A-type granites is purely circumstantial. Granitic complexes are quite common and generally composed of different type granites. I- and A-type granite association in a granitic complex is often described in the literature. Here we present a granitic complex, i.e. the Pitou complex in southern Jiangxi province, South China that is composed of different varieties of A-type granites. Detailed zircon LA-ICP-MS U Pb chronology and in situ Hf isotope, mineral chemistry and whole-rock element and Sr Nd isotope data of this granitic complex are used to explore their origin and to further constrain the geodynamics of Mesozoic magmatism in South China. Our new data indicate that the Pitou complex was emplaced during the Late Triassic (237 Ma) (central to northern part) and Early Jurassic (188–185 Ma) (southern part), respectively and that both the Late Triassic and Early Jurassic granites belong to A-type but show contrasting origins. The Late Triassic granites show an association of alkali-feldspar granite-syenogranite-monzogranite and the rock type of the Early Jurassic granites is alkali-feldspar granite. All the granites are composed mainly of K-feldspar, quartz, plagioclase and biotite (ferri-biotite or annite) with biotite occurring as anhedral crystal, interstitial to quartz and feldspar. Both the Late Triassic and Early Jurassic granites have high SiO 2 (>70 wt%) and total alkalis (K 2 O + Na 2 O > 8 wt%) with high FeO T /(FeO T + MgO) and low Mg#. They are enriched in rare earth elements (except Eu) and depleted in Sr and Ba. They display Zr + Y + Ce + Nb >350 ppm, 10,000 × Ga/Al >2.6 and have high zircon saturation temperatures (>800 °C). Biotites in the granites are Fe-rich with very low Fe3+/Fe2+, indicating fairly reducing conditions. However, the Late Triassic and Early Jurassic granites also show some geochemical differences. The Late Triassic granites have lower FeO T /(FeO T + MgO) and higher Mg# than the Early Jurassic granites, with the Mg# of the former consistent with pure crustal melts and the Mg# of the latter much lower than pure crustal melts. In addition, the Late Triassic granites have lower zircon saturation temperatures (up to 843 °C, average 823 °C) than the Early Jurassic granites (up to 946 °C, average 875 °C). Furthermore, the Late Triassic granites have high 87Sr/86Sr (t) (0.7132–0.7226) and negative ε Nd (t) (−10.3 to −10.9) and ε Hf (t) (in situ zircon) (−11.5 to −11.6) that are similar to those of the early Paleozoic granitoids in the region whereas the Early Jurassic granites have low 87Sr/86Sr (t) (down to 0.7034) and positive ε Nd (t) (up to +3.0) and ε Hf (t) (in situ zircon) (up to +8.3) that are similar to those of the Early Jurassic gabbroic rocks in the region. Geochemical data and major element modeling suggest that the Late Triassic A-type granites were formed by shallow (ca. 15–20 km depth) dehydration melting of the early Paleozoic granitoids triggered by intraplating of basaltic magmas and the Early Jurassic A-type granites were produced by extensive fractionation (ca. 90% to 95%) from gabbroic magmas by removal of plagioclase, amphibole, K-feldspar, clinopyroxene and magnetite. We further suggest the origin of the Late Triassic A-type granites was related to the transtension of the regional NE–trending strike-slip faults caused by the early Indosinian continental collisions and the Early Jurassic A-type granites were emplaced in a back-arc extensional setting coupled with the slab rollback and subsequent slab break-off of the subducted Palaeo-Pacific plate. Our new data confirm that the early Mesozoic magmatism in South China was controlled by continental collisions during the Late Permian to Triassic amalgamation in Southeast Asia whereas the late Mesozoic magmatism was related to the northwestward subduction of the Palaeo-Pacific plate. A transition in the dominant tectonic regime from the Tethyan to the Pacific tectonic domain most likely took place during the Rhaetian. • The Pitou granitic complex emplaced during the Late Triassic and Early Jurassic. • Both Late Triassic and Early Jurassic granites are A-type but show contrasting origin. • Late Triassic granites formed by shallow dehydration melting of Paleozoic granitoids. • Early Jurassic granites formed by extensive fractionation from gabbroic magmas. • Origin of both A-type granites suggests different geodynamic mechanisms. [ABSTRACT FROM AUTHOR]

Abstract: The western Kunlun orogen, the northwest Tibet Plateau, occupies a key tectonic position at the junction between the Pan-Asia and the Tethyan tectonic domains. It is related to subduction of Proto- and Paleo-Tethys and terrane collision from early Paleozoic to early Mesozoic. This paper presents the first detailed SHRIMP zircon U–Pb chronology, mineral chemistry, major and trace element, and Sr–Nd–Hf isotope geochemistry of three Middle Triassic plutons (Yuqikapa, Muztaga and Taer) and their microgranular enclaves in the western Kunlun orogen. SHRIMP zircon U–Pb dating shows that the Yuqikapa pluton was emplaced in the Anisian (~243Ma) and the Muztaga and Taer plutons that contain microgranular enclaves were emplaced in the Ladinian (234–227Ma). The Yuqikapa pluton is composed of peraluminous high-K calc-alkaline two-mica granites (monzogranite–syenogranite–alkali-feldspar granite), with initial 87Sr/86Sr ratios of 0.7071–0.7077, ε Nd (T) of −4.4 to −6.3 and ε Hf (T) (in-situ zircon) of −3.3. Elemental and isotopic data suggest that they were formed by “wet” anatexis of the Precambrian metasedimentary and metaigneous rocks in the continental collision (overthrust) zone. The Muztaga and Taer plutons consist of metaluminous to weakly peraluminous high-K calc-alkaline granitoids (granodiorite–monzogranite), with initial 87Sr/86Sr ratios of 0.7052−0.7104, ε Nd (T) of −3.6 to −7.3 and ε Hf (T) (in-situ zircon) of −3.1 to −1.0. Elemental and isotopic data suggest that they were formed by partial melting of the Precambrian metasedimentary and metaigneous rocks in the normal lower-crust (<40km) for the Muztaga pluton and in the thickened lower-crust (~40–50km) for the Taer pluton, triggered by underplating of coeval (233–226Ma) mantle-derived enclave-forming magmas. The enclaves are basic (SiO2 48.0–51.6wt.%) to intermediate (SiO2 53.0–54.6wt.%) with high K2O (1.4–4.2wt.%). They generally have lower initial 87Sr/86Sr ratios (0.7034–0.7084) and high initial ε Hf (−1.1 to +1.2) than their respective host granitoids. The enclave magmas are considered to have been derived from the partial melting of subduction-modified mantle in the spinel stability field (<60km) (enclaves in the Muztaga pluton) and the spinel-garnet transition zone (~60–80km) (enclaves in the Taer pluton). Final closure of the Paleo-Tethys occurred in the Middle Triassic Anisian (~243Ma). The Middle Triassic Ladinian (234–227Ma) dates the post-collisional regime caused by Paleo-Tethyan oceanic slab break-off. [Copyright &y& Elsevier]

Abstract: This paper presents detailed SHRIMP zircon U–Pb chronology, mineral chemistry, major and trace element, and Sr–Nd–Hf isotope geochemistry of two Cenozoic plutons (Karibasheng and Kuzigan) in western Tibetan Plateau, China. The Karibasheng pluton is composed of monzogranite, and the Kuzigan pluton consists of syenogranite, diopside-bearing syenite and diopside syenite. SHRIMP zircon U–Pb dating on monzogranite, syenogranite and diopside syenite shows that they were emplaced in Miocene (12–10Ma). These rocks are metaluminous and show the affinities with shoshonitic rocks, i.e., alkali-rich (K2O+Na2O=8.6–13.4wt.%), high K2O contents (4.7–10.6wt.%) with high K2O/Na2O ratios (1.2–4.6), enrichment in large ion lithophile elements (LILE) (e.g., Ba=2200–9100ppm; Sr=840–3100ppm, most >1100ppm) and rare earth elements (REE), especially light REE (LREE) (La/Yb up to 168). The rocks are depleted in high field strength elements (HFSE) but show high Nb/Ta ratios (13.3–30.7). The granites have lower initial 87Sr/86Sr ratios (0.7091–0.7099) and higher εNd (T) values (−7.1 to −9.5) than the syenites that have initial 87Sr/86Sr ratios of 0.7095–0.7117 and εNd (T) values of −8.6 to −12.2. Their zircon εHf (T) values (−7.2 to −9.7) are coupled with their whole-rock εNd (T) values, and plot along the mantle array. The amphibole–plagioclase thermometer and estimation of apatite saturation temperature indicate that the primary magmas had high temperatures (up to 880°C for the granites and up to 1100°C for the syenites). The source depth for the granites and syenites is <70–100km inferred by the metasomatic volatile phase (amphibole–phlogopite) relation, and thus most probably within the upper part of lithospheric mantle. Detailed elemental and isotopic data and major element modeling suggest that the granites and syenites were derived directly by partial melting of the veined lithospheric mantle that had been hybridized by the continental slab-derived melts. Continental slab break-off was most likely the mechanism associated with the generation of these granites and syenites. [Copyright &y& Elsevier]

The origin of microgranitoid enclaves in granitic plutons has long been debated (hybrid magma blobs vs. refractory restites or cognate fragments). This article presents detailed petrography, SHRIMP zircon U–Pb chronology, bulk-rock major and trace element analyses, and Sr–Nd isotope and in situ zircon Hf isotopic geochemistry for microgranitoid enclaves within two Late Triassic granitic plutons in the Qinling orogen. Zircon U–Pb dating shows that the enclaves formed during the Carnian (222.5 ± 2.1 to 220.7 ± 1.9 Ma) coeval with their host granitoids (220.0 ± 2.0 to 218.7 ± 2.4 Ma). Field and petrological observations (e.g. double enclaves, xenocrysts, acicular apatite, and poikilitic K-feldspar or quartz) suggest that the enclaves are globules of a mantle-derived more mafic magma that was injected into and mingled with the host magma. The enclaves are mainly ultrapotassic, distinct from the host granitoids that have high-K calc-alkaline bulk-rock compositions. Although the enclaves have closely similar bulk-rock Sr–Nd isotope [initial 87Sr/86Sr = 0.7046–0.7056, ϵNd (T) = –0.3 to –5.0] and in situ zircon Hf isotope [ϵHf (T) = –1.5 to +2.9] ratios as the granitoids [initial 87Sr/86Sr = 0.7042–0.7059, ϵNd (T) = –0.6 to –6.3, ϵHf (T) = –2.2 to +1.6], chemical relationships including very different bulk-rock compositions at a given SiO2 content lead us to interpret the isotopic similarities as reflecting similar but separate isotopic source rocks. Detailed elemental and isotopic data suggest that the enclaves and the host granitoids were emplaced in a continental arc environment coupled with northward subduction of the Palaeo-Tethyan oceanic crust. Partial melting of subducted sediments triggered by dehydration of the underlying igneous oceanic crust, with melts interacting with the overlying mantle wedge, formed high-K calc-alkaline granitic magmas, whereas partial melting of diapiric phlogopite-pyroxenites, solidified products of the same subducting sediment-derived melts, generated ultrapotassic magmas of the microgranitoid enclaves. Our new data further confirm that in the Late Triassic time the Qinling terrane was an active continental margin rather than a post-collisional regime, giving new insights into the tectonic evolution of this orogen. [ABSTRACT FROM AUTHOR]

Two suites of granitoids, the Late Jurassic (158 ± 3 Ma) Linglong suite and the Early Cretaceous (130-126 Ma) Guojialing suite, crop out in the northwestern Jiaodong Peninsula, eastern China. The Linglong suite is a monzogranite, comprising alkali feldspar, plagioclase, quartz and Ferich biotite. The Guojialing suite includes at least five plutonic bodies of both granodiorite and monzogranite. The rocks are composed of plagioclase, alkali feldspar, quartz, Mg-rich amphibole and Mg-rich biotite. Both the Linglong and Guojialing suites have adakitic affinity. They are enriched in LREE with high La/Yb ratios and show positive Eu anomalies. The rocks are also enriched in LILE and depleted in HFSE with high Sr/Y ratios. The Linglong granite shows very uniform Sr--Nd isotopic compositions with initial 87Sr/86Sr ratios of 0.7119-0.7126 and εNd (T) values of -21.3 to -21.6, which are similar to those of the local Neoarchaean basement. The Guojialing suite has variable initial 87Sr/86Sr ratios (0.7108-0.7120) and εNd (T) values (-10.8 to -17.2), which are distinct both from those of the Neoarchaean basement and from those of the local enriched lithospheric mantle inferred from the coeval mafic dykes in the studied area. Detailed petrological and geochemical data indicate that the Linglong suite was derived by partial melting of Neoarchaean metamorphic lower-crustal rocks at depth of > 50 km with a eclogite residue, whereas the Guojialing suite was formed by the reaction of delaminated eclogitic crust-derived melt with the upwelling asthenospheric mantle. The petrogenesis of these two contrasting adakitic granitoids suggests intensive lower-crustal delamination during Early Cretaceous times, following a crustal thickening process from the late stage of the Early Jurassic to early stage of the Late Jurassic with crustal thickness of < 32 km to > 50 km, respectively. [ABSTRACT FROM AUTHOR]

Mafic microgranular enclaves (MMEs) are common in the monzogranites from the Yangba pluton in the Bikou Terrane of central China. Zircon LA-ICP-MS U–Pb dating yields ages of 208.7 ± 0.7 Ma and 209.3 ± 0.9 Ma for the host monzogranites, and 211.9 ± 0.8 Ma for the MMEs, indicating formation from coeval magmas. The field occurrence and textures including spheroidal shapes, transitional contacts, igneous mineral assemblages, acicular apatites, and oscillatory zoning with repeated resorption surfaces in plagioclase, indicate that the MMEs crystallized from mafic magma that was injected into and mingled with the host felsic magma. The host monzogranites are intermediate-felsic, metaluminous, and lack typical peraluminous minerals or alkaline mafic minerals, suggesting their I-type affinity. The monzogranites display depletion in high field strength elements, with Nb and Ta anomalies, and enrichment in large ion lithophile elements and light rare earth elements (LREE), with slightly negative Eu anomalies (Eu/Eu ∗ = 0.72–0.93). The MMEs from the Yangba pluton are intermediate, metaluminous, and have higher K 2 O, Al 2 O 3 , Fe 2 O 3 T , MgO, Ni, and Cr contents than the pluton. The MMEs also display much higher total rare earth element (REE) concentrations and REE patterns that are sub-parallel to those of the host rocks, enrichments in Rb, Th, U, K, and LREE, and depletions in Ba, Nb, Ta, and Ti. These features are similar to those of the host rocks, indicating crust–mantle interaction during their petrogenesis. Zircons from the MMEs have highly variable ε Hf ( t ) values (−5.5 to +8.7) with corresponding two-stage Hf model ages ( T DM2 ) of 1.14 to 1.42 Ga, indicating they were derived from depleted mantle with crustal contamination. In contrast, zircons from host monzogranite show ε Hf ( t ) values ranging from −1.7 to +2.7, with T DM2 of 1.13 to 1.21 Ga, corresponding to that of the basement rocks in the Bikou Terrane, which indicates that these granitic magmas were probably derived from the Neoproterozoic juvenile lower crust with minor contribution of Mesoproterozoic ancient lower crust. The integrated petrology and elemental and isotopic geochemistry suggest that the MMEs and host monzogranites were generated by the interaction of a granitic magma and a mafic magma in the lower crust. We envisage that Neoproterozoic subcontinental lithosphere mantle-derived mafic magma intruded the lower continental crust during Late Triassic, following the Late Permian to Early Triassic collision between the South China and North China Blocks. [ABSTRACT FROM AUTHOR]

Abstract: The Linglong granite is one of the most important Mesozoic plutons in the Shandong Peninsula, eastern China, and its petrogenesis has long been controversial, particularly with regard to the nature of source region and geodynamic setting. Our new precise zircon U–Pb dating results reveal that the Linglong granite was emplaced in the Late Jurassic (157–160Ma). In addition, abundant inherited zircons are identified in the granite with four groups of age peaked at ~208, ~750, ~1800 and ~2450Ma. Geochemical studies indicate that the Linglong granite is weakly peraluminous I–type granite, and is characterized by high SiO2, Sr and La, but low MgO, Y and Yb contents, strongly fractionated REE pattern and high Sr/Y and La/Yb ratios. It also exhibits high initial 87Sr/86Sr ratios (0.7097 to 0.7125), low εNd(t) (−17.7 to −20.3) and variable zircon εHf(t) (−22.2 to −8.7) values. Calculation of the zircon saturation temperature (TZr) reveals that the magma temperatures are 760±20°C, and the lowest TZr value of 740°C may be close to initial magma temperature of this inheritance-rich rock. Interpretation of the elemental and isotopic data suggests that the Linglong granite has some affinities with the adakite, and was most likely derived from partial melting of thickened lower crust without any significant contribution of mantle components. The presence of a large number of inherited zircons and variable Sr–Nd–Hf isotopic compositions reveal that the Linglong granite probably has multiple sources consisting of the lower crust of both South China Block and North China Block, as well as the collision-related alkaline rocks and UHP metamorphic rocks. The continental arc-rifting related to the Izanagi plate subduction was the most likely geodynamic force for formation of the Jurassic Linglong adakatic granite in the Shandong Peninsula. [Copyright &y& Elsevier]

Abstract: The behavior of boron and its isotopes in fluid-dominant processes and hydrothermal alteration of granites is examined using fresh and altered granite samples from the Qitianling granite and associated hydrothermal tin deposits in South China. Boron concentrations are highest in the fresh granite (37ppm) and depleted as a result of two stages of fluid mobility and fluid–rock interaction within the granite. Constraints provided both by δ 11 B and δ 18 O data suggest that the first stage was related to exsolution of aqueous fluids from the granite magma at a temperature of >450°C. This was followed by further boron depletion in the granite by hydrothermal circulation of meteoric water at lower temperatures (~350°C) and low water/rock ratios. The sensitivity of coupled boron and oxygen isotope systematics to these processes suggests that they can provide valuable constraints on of fluid mobility in granite and associated mineralization. [Copyright &y& Elsevier]