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Polyaniline (PAni) is a widely studied conductive polymer that has unique properties such as high conductivity and stability. However, poor solubility and mechanical properties limit its prospective applications. To overcome these limitations, different synthesis methods have been developed and studied. One of these methods is to make the composites of PAni which displayed prominent results not only in addressing poor stability but also in achieving high mechanical properties. This review summarizes various synthesis methods, properties, and applications of PAni composites that have been incorporated with different materials such as carbon, carbon nanotube, graphite, graphene oxide, metal and metal oxides, metal–organic framework, bio-molecules, silica, and many more to enhance their potential applications. The most important applications of the PAni composite are briefly revealed at the end of this review and discussed appropriately. [ABSTRACT FROM AUTHOR]