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1. Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex.

Author

Pearson, Tyler J., Fataftah, Majed S., and Freedman, Danna E.

Subjects
*MAGNETIC anisotropy, *HETEROBIMETALLIC complexes, *PARAMAGNETIC materials, *HYPERFINE structure, *HEAVY elements
Abstract

A novel Mn2+…Bi3+ heterobimetallic complex, featuring the closest Mn…Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn2+ to a heavy main group element, namely, bismuth. [ABSTRACT FROM AUTHOR]

Published
2016
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