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Rare information on the seafood safety and the coastal water-food-energy nexus sustainability in terms of seafood safety is available. This study investigated the distribution of heavy metals in 3 kinds of seafood (bivalve molluscs, fish, and crustaceans) collected from coastal areas along the 18,000 km coastline of China. Risk assessment and source apportionment of heavy metals, and the coastal water-food-energy nexus sustainability in terms of heavy metal pollution were also performed. The results showed that total concentrations of 8 heavy metals (Cu, Pb, Zn, Cd, Cr, Hg, As, and Ni) in seafood varied with sampling sites and species by following the order of bivalve molluscs > crustaceans > fish. Estimated daily intake (EDI) analysis indicated that it was safe for humans to consume seafood in all sampling sites. Non-cancer risks posed by heavy metals were acceptable for 99.1% of adult and 97.7% of children. However, Cr and As in 72% of fish samples caused high cancer risks for children. The farmed fish posed relatively low risk in comparison with the wild fish suggested that it might be safer to consume farmed fish than wild fish. Source apportionment demonstrated that the fossil energy consumption (coal combustion and vehicle exhaust), seawater, and metallurgic dust might serve as the possible main sources of heavy metals in seafood. Based on the policy scenario analysis, the fossil-energy-controlling policy and clean coastal water action were beneficial to the seafood safety by reducing target heavy metals in seafood. These findings provided comprehensive information on seafood safety and the water-food-energy nexus sustainability in coastal regions at continental-scale in terms of heavy metal pollution. [ABSTRACT FROM AUTHOR]

Comprehensive information on heavy metals in coastal waters at national scale of China is limited. Therefore, this study investigated the distribution, pollution, and ecological-health risks of heavy metals in coastal waters along 18,000 km coastline of China. Total 13 target heavy metals in coastal waters along coastline of China showed drastic spatial variations with average concentrations ranging from.14 (Cd) to 136.26 (Cu) μg/L. Cu was the dominant heavy metal with the maximal concentration of 1485.92 μg/L. Three methods including heavy metal pollution index (HPI), Nemerow index (NI), and contamination degree (CD) were adopted to explore heavy metal pollution. HPI obtained the worst-case evaluation results to illustrate that heavy pollution occurred at over 50% of sampling sites. Anthropogenic sources were the main sources of heavy metals in the coastal waters. Approximately 28.13% and 9.38% of sampling sites illustrated considerable and very high ecological risks, respectively. Metals including Cu, As, and Hg were the main pollution and risk contributors. Heavy metals in coastal waters posed high cancer risks and unacceptable non-cancer risks to both adults and children. Therefore, effective control of heavy metals is necessary for regional sustainability and well-beings of residents in coastal regions of China. [ABSTRACT FROM AUTHOR]

This paper analyzed the distribution and speciation of seven heavy metals in sediments in Jiaozhou Bay. The ecological risk was assessed using three index approaches (i.e., risk assessment code (RAC), contamination factor (CF), and potential ecological risk index (PERI)) and by a comparison with sediment quality guidelines (Chinese Marine Sediment Quality Standards (CMSQS), and threshold effect level (TEL) and probable effect level (PEL) from the USEPA). Pb, Cr, As, Cu, Zn, and Hg contents at most sites were above the corresponding TEL and Class I criteria (CMSQS) value. Particularly, high contents of Cu, detected at sites S7(124.5 mg kg−1) and S8(118.3 mg kg−1), exceeded the respective PEL value, indicating that harmful biological effects might occur. Speciation analysis, individualCF, andRACcalculations suggested that Cd had the highest bioavailable fraction and thus posed a very high risk to aquatic ecosystem; Cu and Zn showed a medium–high risk. Both globalCFandPERIanalysis indicated a high pollution risk at sites S7, S1, S3, and S2, but the assessments of specific sites were different. The incomplete consistency suggested that it is necessary to consider both total contents and chemical speciation for providing a more realistic appraisal for the risk of heavy metals in sediments. [ABSTRACT FROM AUTHOR]

Scallops are one of the most common bivalves, large-scale farmed in the coastal areas of China. Three species of scallops (Chlamys farreri , Argopecten irradians and Patinopecten yessoensis) from 10 samples sites along the Bohai Sea and the Yellow Sea were collected to investigate species-specific and tissues-specific bioaccumulation, spatial-temporal distribution and health risks for people. Cd must be paid attention since Cd concentrations in 96% of scallop samples exceeded standard with the highest Cd bioaccumulation potentials (BCF) >10,000 while those of the other metals were less than the corresponding limits except Zn with exceeding-limit percentage of 13%. The metal pollution index values showed that A. irradians could accumulate more metals than the other two species, and scallops in the Bohai Sea were polluted more seriously by heavy metals than in the Yellow Sea. The capacities of tissues in scallops to accumulate metals generally followed the order of digestive gland > gill > adductor muscle. However, Zn accumulated in gill was more than that in digestive gland and muscle. Adults and children would face the non-cancer risks because of the accumulation Cd in scallops based on health risk assessment. Cd was the major contributor of health risk to account for 85% of total hazard quotient and 48% of total cancer risk. Scallops could accumulate Cd rapidly from ambient environments to cause health risks according to the transplantation test. Moreover, the recommended maximum edible amounts of whole scallops were 127/63 g/week for adult/children on the basis of the provisional tolerance weekly intake. Humans are recommended to only consume adductor muscles for reducing health risks. ga1 • Cd concentrations in scallop culture area was much less than Class I level of 1.0. • High Cd bioaccumulation (BCF>10,000) caused the over-standard rate beyond 96%. • The Cd, As and Ni were considered as the main cancer risk contributors. • Cd was also the primary limit factor for scallop ingestion among the heavy metals. • The maximum edible amounts of whole scallops were 127/63 g/week for adult/children. [ABSTRACT FROM AUTHOR]

Abstract Coastal groundwater quality significantly affects the regional sustainable development, due to the water resource shortage in coastal zone. Current studies on coastal groundwater have mainly focused on saline water intrusion and over-extraction. Information on the heavy metal pollution of coastal groundwater with salinization trend is limited. This study investigated heavy metals in groundwater from a typical coastal region with intensive anthropogenic activities and saline water intrusion. The southwestern coastal plains of the study area showed significant groundwater salinization trend. Heavy metals in the coastal groundwater mainly originated from anthropogenic activities and groundwater salinization according to principal component analysis. Relative high concentrations of As, Co, Cr, Cu, Fe, Mn, and Ni occurred in the southwestern coast of the study area with high TDS level, indicating that the concentrations of these heavy metals in shallow aquifer of the study area might be influenced by the groundwater salinization. Average concentrations of heavy metals in groundwater of the study area ranged from 0.03 (Cd) to 686.92 (Fe) μg/L. Fe was the dominant heavy metal in groundwater with the maximal concentration of 2333.76 μg/L and exceeding-standard rate reaching 98.23%. Approximately 13.27% of sampling sites showed moderate or higher heavy metal pollution of groundwater based on heavy metal pollution index. Heavy metals in groundwater exerted low ecological risks. Elements Fe, Ni, and As were the main contributors for ecological risks. Cancer risks of heavy metals for both adults and children were high at all sampling sites. Non-cancer risks for adults and children were unacceptable at 4.42% and 17.70% of sampling sites, respectively. The salinization of the coastal groundwater could also lead to the increase in the ecological and health risks of heavy metals in coastal groundwater. These findings provide initial and important information on heavy metals pollution in coastal aquifer with saline water intrusion. Graphical abstract Unlabelled Image Highlights • Southwestern coastal plains of study area showed significant groundwater salinization. • About 13.27% of sampling sites showed moderate or more serious heavy metal pollution. • Heavy metals in groundwater exerted low ecological risks. • Heavy metals in groundwater exerted high cancer risks for adults and children. • Salinization of coastal groundwater caused the increase in pollution and risks. [ABSTRACT FROM AUTHOR]