1. Schottky Junctions with Bi@Bi 2 MoO 6 Core-Shell Photocatalysts toward High-Efficiency Solar N 2 -to-Ammonnia Conversion in Aqueous Phase.
- Author
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Wang, Meijiao, Wei, Guosong, Li, Renjie, Yu, Meng, Liu, Guangbo, and Peng, Yanhua
- Subjects
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PHOTOCATALYSTS , *HETEROJUNCTIONS , *RENEWABLE energy sources , *PHOTOREDUCTION , *SURFACE plasmon resonance , *ENERGY consumption - Abstract
The photocatalytic nitrogen reduction reaction (NRR) in aqueous solution is a green and sustainable strategy for ammonia production. Nonetheless, the efficiency of the process still has a wide gap compared to that of the Haber–Bosch one due to the difficulty of N2 activation and the quick recombination of photo-generated carriers. Herein, a core-shell Bi@Bi2MoO6 microsphere through constructing Schottky junctions has been explored as a robust photocatalyst toward N2 reduction to NH3. Metal Bi self-reduced onto Bi2MoO6 not only spurs the photo-generated electron and hole separation owing to the Schottky junction at the interface of Bi and Bi2MoO6 but also promotes N2 adsorption and activation at Bi active sites synchronously. As a result, the yield of the photocatalytic N2-to-ammonia conversion reaches up to 173.40 μmol g−1 on core-shell Bi@Bi2MoO6 photocatalysts, as much as two times of that of bare Bi2MoO6. This work provides a new design for the decarbonization of the nitrogen reduction reaction by the utilization of renewable energy sources. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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