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Monolithic perovskite/organic tandem solar cells (POTSCs) have significant advantages in next‐generation flexible photovoltaics, owing to their capability to overcome the Shockley–Queisser limit and facile device integration. However, the compromised sub‐cells performance challenges the fabrication of high‐efficiency POTSCs. Especially for all‐inorganic wide‐bandgap perovskite front sub‐cells (AIWPSCs) based n‐i‐p structured POTSCs (AIPOTSCs), for which the power conversion efficiency (PCE) is much lower than organic–inorganic mixed‐halide wide‐bandgap perovskite based POTSCs. Herein, an ionic liquid, methylammonium formate (MAFm), based dual‐interface engineering approach is developed to modify the bottom and top interfaces of wide‐bandgap CsPbI2Br films. In particular, the Fm− group of MAFm can effectively passivate the interface defects, and the top interface modification can facilitate the formation of uniform perovskite films with enlarged grain size, thereby mitigating the defects and perovskite grain boundaries induced carrier recombination. As a result, CsPbI2Br‐based AIWPSCs with a high PCE of 17.0% and open‐circuit voltage (VOC) of 1.347 V are achieved. By integrating these dual‐interface engineered CsPbI2Br‐based front sub‐cells with the narrow‐bandgap PM6:CH1007‐based rear sub‐cells, a record PCE of 23.21% is obtained for AIPOTSCs, illustrating the potential of AIPOTSCs for achieving high‐efficiency tandem solar cells. [ABSTRACT FROM AUTHOR]